HRP20171637T1 - Postupak za hidroobradu vakuumskog destilata upotrebom niza katalizatora - Google Patents
Postupak za hidroobradu vakuumskog destilata upotrebom niza katalizatora Download PDFInfo
- Publication number
- HRP20171637T1 HRP20171637T1 HRP20171637TT HRP20171637T HRP20171637T1 HR P20171637 T1 HRP20171637 T1 HR P20171637T1 HR P20171637T T HRP20171637T T HR P20171637TT HR P20171637 T HRP20171637 T HR P20171637T HR P20171637 T1 HRP20171637 T1 HR P20171637T1
- Authority
- HR
- Croatia
- Prior art keywords
- catalyst
- metal
- volume
- range
- organic compound
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 20
- 239000003054 catalyst Substances 0.000 title claims 16
- 229910052751 metal Inorganic materials 0.000 claims 13
- 239000002184 metal Substances 0.000 claims 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 10
- 150000002894 organic compounds Chemical class 0.000 claims 7
- 239000000758 substrate Substances 0.000 claims 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 5
- 230000003197 catalytic effect Effects 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 229910052757 nitrogen Inorganic materials 0.000 claims 5
- 229910052698 phosphorus Inorganic materials 0.000 claims 5
- 239000011574 phosphorus Substances 0.000 claims 5
- 239000002243 precursor Substances 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 238000001354 calcination Methods 0.000 claims 3
- 238000004517 catalytic hydrocracking Methods 0.000 claims 3
- 150000002739 metals Chemical class 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 238000004523 catalytic cracking Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000004231 fluid catalytic cracking Methods 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 150000003890 succinate salts Chemical class 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
- 238000005987 sulfurization reaction Methods 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1074—Vacuum distillates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Claims (15)
1. Postupak hidroobrade šarže ugljikovodika koja obuhvaća spojeve koji sadrže spojeve koji sadrže dušik u količini od više od 250 ppm masenih i koja ima ponderiranu prosječnu temperaturu od više od 380°C, naznačen time da sadrži slijedeće korake:
a) dovođenje navedene šarže ugljikovodika u kontakt, u prisutnosti vodika, s barem jednim prvim katalizatorom koji sadrži amorfnu podlogu baziranu na aluminijevom oksidu, fosforu, i aktivnu fazu koju tvori barem jedan metal iz skupine VIB u obliku oksida i barem jedan metal iz skupine VIII u obliku oksida, navedeni prvi katalizator pripremljen je u skladu s postupkom koji obuhvaća barem jedan korak kalcinacije;
b) dovođenje efluenta dobivenog u koraku a) u kontakt, u prisutnosti vodika, s barem jednim drugim katalizatorom koji sadrži amorfnu podlogu baziranu na aluminijevom oksidu, fosfor, aktivnu fazu koju tvori barem jedan metal iz skupine VIB i barem jedan metal iz skupine VIII, te barem jedan organski spoj koji sadrži kisik i/ili dušik, navedeni drugi katalizator se priprema u skladu s postupkom koji obuhvaća slijedeće korake:
i) dovođenje barem jedne komponente metala iz skupine VIB, barem jedne komponente metala iz skupine VIII, fosfora i barem jednog organskog spoja koji sadrži kisik i/ili dušik u kontakt s podlogom, tako da se dobije katalitički prekursor;
ii) sušenje navedenog katalitičkog prekursora dobivenog iz koraka i) kod temperature od manje od 200°C, bez naknadne kalcinacije;
da se dobije hidroobrađeni efluent.
2. Postupak prema zahtjevu 1 naznačen time da, za katalizator iz koraka a) ili b), metal iz skupine VIB je odabran od molibdena, volframa i smjese ta dva elementa, i metal iz skupine VIII je odabran od kobalta, nikla i smjese ta dva elementa.
3. Postupak prema zahtjevu 1 ili zahtjevu 2 naznačen time da, za katalizator iz koraka a) ili b), količina metala iz skupine VIB je u rasponu 5% do 40 masenih % oksida metala iz skupine VIB u odnosu na ukupnu masu katalizatora, količina metala iz skupine VIII je u rasponu 1% do 10 masenih % oksida metala iz skupine VIII u odnosu na ukupnu masu katalizatora, i količina fosfora je u rasponu 0.1% do 10 masenih % P2O5 u odnosu na ukupnu masu katalizatora.
4. Postupak prema jednom od zahtjeva 1 do 3, naznačen time da katalizator iz koraka a) ili b) nadalje sadrži barem jednu primjesu koja se bira od bora i fluora i smjese bora i fluora.
5. Postupak prema jednom od zahtjeva 1 do 4, naznačen time da organski spoj je jedan ili više spojeva koji se biraju od karboksilne kiseline, alkohola, aldehida, estera, amina, aminokarboksilne kiseline, aminoalkohola, nitrila i amida.
6. Postupak prema zahtjevu 5, naznačen time da organski spoj je jedan ili više spojeva koji se biraju od etilen glikola, glicerola, polietilen glikola (s molekularnom masom od 200 do 1500), acetofenona, 2,4-pentanediona, pentanola, octene kiseline, maleinske kiseline, oksalne kiseline, vinske kiseline, mravlje kiseline, limunske kiseline i C1-C4 dialkil sukcinata.
7. Postupak prema zahtjevu 5, naznačen time da organski spoj sadrži barem kombinaciju C1-C4 dialkil sukcinata i octene kiseline ili u kojem organski spoj sadrži barem limunsku kiselinu.
8. Postupak prema jednom od zahtjeva 1 do 7, naznačen time da se katalizator iz koraka a) ili b) također podvrgava koraku sulfurizacije.
9. Postupak prema jednom od zahtjeva 1 do 8, naznačen time da je količina bazičnog dušika u šarži 60 ppm ili više.
10. Postupak prema jednom od zahtjeva 1 do 9, naznačen time da se svaki od koraka a) i b) provodi kod temperature u rasponu od 200°C do 450°C, kod pritiska u rasponu 0.5 do 30 MPa, kod satne prostorne brzine u rasponu 0.1 do 20 h-1 i uz omjer vodik/dovod, izraženo kao volumen vodika mjereno kod uvjeta normalne temperature i tlaka, po volumenu tekuće šarže u rasponu 50 L/L do 2000 L/L.
11. Postupak prema jednom od zahtjeva 1 do 10, naznačen time da se korak a) provodi u prvoj zoni koja sadrži prvi katalizator koji zauzima volumen V1, te se korak b) provodi u drugog zoni koja sadrži drugi katalizator koji zauzima volumen V2, distribucija volumena, V1/V2, je u rasponu 10 volumenskih % /90 volumenskih % do 50 volumenskih % /50 volumenskih % redom za prvu i drugu zonu.
12. Postupak prema jednom od zahtjeva 1 do 11, naznačen time da korak i) iz koraka b) sadrži slijedeće uzastopne korake:
i') impregniranje amorfne podloge bazirane na aluminijevom oksidu s barem jednom otopinom koja sadrži barem jedan metal iz skupine VIB, barem jedan metal iz skupine VIII i navedeni fosfor kako bise dobilo impregniranu podlogu;
i") sušenje impregnirane podloge dobivene u koraku i') kod temperature od manje od 180°C bez naknadne kalcinacije kako bi se dobila osušena impregnirana podloga;
i"') impregniranje osušene impregnirane podloge dobivene u koraku i") s otopinom za impregniranje koja sadrži barem jedan organski spoj koji sadrži kisik i/ili dušik kako bi se dobilo impregnirani katalitički prekursor;
i"") ostavljanje da impregnirani katalitički prekursor dobiven u koraku i"') to mature, kako bi se dobilo navedeni katalitički prekursor.
13. Postupak prema jednom od zahtjeva 1 do 12, naznačen time da se efluent dobiven u koraku a) podvrgava koraku odvajanja kako bi se odvojila teška frakcija i lagana frakcija koje sadrže H2S i NH3 koji nastaje tijekom koraka a), navedena teška frakcija se zatim uvodi u korak b).
14. Postupak hidrokrekiranja koji koristi postupak hidroobrade prema zahtjevima 1 do 13, naznačen time da se navedeni hidroobrađeni efluent dovodi u kontakt, u prisutnosti vodika i pod uvjetima rada hidrokrekiranja, s barem jednim katalizatorom za hidrokrekiranje kako bi se dobio hidrokrekirani efluent.
15. Postupak fluidnog katalitičkog krekiranja koji koristi postupak hidroobrade prema zahtjevima 1 do 13, naznačen time da se navedeni hidroobrađeni efluent dovodi u kontakt, pod uvjetima rada katalitičkog krekiranja, s barem jednim katalizatorom za katalitičko krekiranje kako bi se dobio krekirani efluent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1361800A FR3013720B1 (fr) | 2013-11-28 | 2013-11-28 | Procede d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs |
| EP14306682.7A EP2878651B1 (fr) | 2013-11-28 | 2014-10-23 | Procédé d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20171637T1 true HRP20171637T1 (hr) | 2017-12-15 |
Family
ID=50137831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20171637TT HRP20171637T1 (hr) | 2013-11-28 | 2017-10-25 | Postupak za hidroobradu vakuumskog destilata upotrebom niza katalizatora |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9683180B2 (hr) |
| EP (1) | EP2878651B1 (hr) |
| CN (1) | CN104673373B (hr) |
| CA (1) | CA2872293C (hr) |
| CL (1) | CL2014003244A1 (hr) |
| ES (1) | ES2643987T3 (hr) |
| FR (1) | FR3013720B1 (hr) |
| HR (1) | HRP20171637T1 (hr) |
| HU (1) | HUE035024T2 (hr) |
| PT (1) | PT2878651T (hr) |
| RU (1) | RU2651269C2 (hr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3013721B1 (fr) | 2013-11-28 | 2015-11-13 | Ifp Energies Now | Procede d'hydrotraitement de gazole mettant en oeuvre un enchainement de catalyseurs |
| FR3013720B1 (fr) | 2013-11-28 | 2015-11-13 | IFP Energies Nouvelles | Procede d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs |
| RU2605950C1 (ru) * | 2015-12-25 | 2017-01-10 | Акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" (АО "ВНИИ НП") | Способ переработки вакуумных дистиллатов |
| FR3075220A1 (fr) * | 2017-12-19 | 2019-06-21 | IFP Energies Nouvelles | Procede d'hydrotraitement de distillats sous vide mettant en oeuvre un enchainement specifique de catalyseurs |
| SG11202009693XA (en) | 2018-04-10 | 2020-10-29 | China Petroleum & Chem Corp | Hydrofining catalyst, its preparation and application thereof |
| FR3094985B1 (fr) * | 2019-04-12 | 2021-04-02 | Axens | Procédé d’hydrotraitement d’un naphta |
| CN112717963B (zh) * | 2019-10-28 | 2022-03-04 | 中国石油化工股份有限公司 | 一种加氢预处理催化剂及其制备方法和应用 |
| EP3822332A1 (en) * | 2019-11-13 | 2021-05-19 | Indian Oil Corporation Limited | Catalyst for selective hydrogenation of diolefins and method for preparing catalyst |
| RU2753597C2 (ru) * | 2020-01-24 | 2021-08-18 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ гидрооблагораживания вакуумного газойля (варианты) |
| FR3119624B1 (fr) | 2021-02-09 | 2024-04-26 | Ifp Energies Now | Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene |
| FR3138143A1 (fr) | 2022-07-20 | 2024-01-26 | IFP Energies Nouvelles | Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel et tungstene sur un support silice-alumine |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS526711B1 (hr) | 1971-02-01 | 1977-02-24 | ||
| US4012340A (en) | 1971-02-01 | 1977-03-15 | Chiyoda Kako Kensetsu Kabushiki Kaisha | Process for preparing catalysts for hydrodesulfurization |
| US4392945A (en) | 1982-02-05 | 1983-07-12 | Exxon Research And Engineering Co. | Two-stage hydrorefining process |
| US4574120A (en) * | 1984-10-15 | 1986-03-04 | Shell Oil Company | Method for preparing high activity silica supported hydrotreating catalysts |
| US4534852A (en) | 1984-11-30 | 1985-08-13 | Shell Oil Company | Single-stage hydrotreating process for converting pitch to conversion process feedstock |
| US4902404A (en) | 1988-07-05 | 1990-02-20 | Exxon Research And Engineering Company | Hydrotreating process with catalyst staging |
| FR2664507B1 (fr) | 1990-07-13 | 1995-04-14 | Eurecat Europ Retrait Catalys | Procede de pretraitement d'un catalyseur par un melange d'un agent soufre et d'un agent reducteur organique. |
| JP2900771B2 (ja) | 1992-11-18 | 1999-06-02 | 住友金属鉱山株式会社 | 炭化水素油の水素化処理触媒の製造方法 |
| US5389595A (en) * | 1993-09-30 | 1995-02-14 | Union Oil Company Of California | Hydroprocessing catalyst, its use, and method of preparation |
| DK121993D0 (da) | 1993-10-28 | 1993-10-28 | Haldor Topsoe As | Graded catalyst system |
| JP3802106B2 (ja) | 1995-06-08 | 2006-07-26 | 日本ケッチェン株式会社 | 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法 |
| US6235190B1 (en) | 1998-08-06 | 2001-05-22 | Uop Llc | Distillate product hydrocracking process |
| EP1041133A1 (en) | 1999-04-02 | 2000-10-04 | Akzo Nobel N.V. | Process for effecting ultra-deep HDS of hydrocarbon feedstocks |
| FR2792551B1 (fr) | 1999-04-20 | 2001-06-08 | Atochem Elf Sa | Procede de sulfuration de catalyseurs d'hydrotraitement |
| WO2001076741A1 (en) | 2000-04-11 | 2001-10-18 | Akzo Nobel N.V. | Process for sulphiding an additive-containing catalyst |
| JP2004508453A (ja) | 2000-09-04 | 2004-03-18 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 炭化水素供給原料の超高度な水素化脱硫を達成する方法 |
| BRPI0414865B1 (pt) * | 2003-10-03 | 2014-07-08 | Albemarle Netherlands Bv | Processo para ativação de um catalisador de hidrotratamento |
| US7691257B2 (en) * | 2004-04-22 | 2010-04-06 | Exxonmobil Research And Engineering Company | Process to manufacture low sulfur diesel fuels |
| CA2636156C (en) * | 2006-01-17 | 2015-08-18 | Chuansheng Bai | Selective catalysts for naphtha hydrodesulfurization |
| SG10201610092XA (en) * | 2006-10-11 | 2017-01-27 | Exxonmobil Res & Eng Co | Hydroprocessing methods for bulk group viii/group vib metal catalysts |
| CA2776766A1 (en) | 2009-10-05 | 2011-04-14 | Exxonmobil Research And Engineering Company | Stacking of low activity or regenerated catalyst above higher activity catalyst |
| KR101788700B1 (ko) | 2009-12-16 | 2017-10-20 | 토탈 라피나쥬 프랑스 | Ⅷ 및 ⅵｂ 족 금속을 포함하는, 수소화처리에서 사용될 수 있는 촉매 및 아세트산과 디알킬 숙시네이트 ｃ1-ｃ4 를 이용하는 제조방법 |
| FR2972648B1 (fr) * | 2011-03-18 | 2013-04-26 | Ifp Energies Now | Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib et preparation avec de l'acide citrique et du succinate de dialkyle c1-c4 |
| FR3013720B1 (fr) | 2013-11-28 | 2015-11-13 | IFP Energies Nouvelles | Procede d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs |
-
2013
- 2013-11-28 FR FR1361800A patent/FR3013720B1/fr active Active
-
2014
- 2014-10-23 EP EP14306682.7A patent/EP2878651B1/fr active Active
- 2014-10-23 ES ES14306682.7T patent/ES2643987T3/es active Active
- 2014-10-23 PT PT143066827T patent/PT2878651T/pt unknown
- 2014-10-23 HU HUE14306682A patent/HUE035024T2/en unknown
- 2014-11-24 CA CA2872293A patent/CA2872293C/fr active Active
- 2014-11-26 US US14/554,242 patent/US9683180B2/en active Active
- 2014-11-27 RU RU2014147969A patent/RU2651269C2/ru active
- 2014-11-28 CL CL2014003244A patent/CL2014003244A1/es unknown
- 2014-11-28 CN CN201410705782.9A patent/CN104673373B/zh active Active
-
2017
- 2017-10-25 HR HRP20171637TT patent/HRP20171637T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2651269C2 (ru) | 2018-04-19 |
| RU2014147969A (ru) | 2016-06-20 |
| CA2872293C (fr) | 2021-07-27 |
| CA2872293A1 (fr) | 2015-05-28 |
| US9683180B2 (en) | 2017-06-20 |
| FR3013720B1 (fr) | 2015-11-13 |
| PT2878651T (pt) | 2017-10-23 |
| EP2878651B1 (fr) | 2017-07-26 |
| EP2878651A1 (fr) | 2015-06-03 |
| HUE035024T2 (en) | 2018-03-28 |
| CL2014003244A1 (es) | 2015-11-20 |
| CN104673373B (zh) | 2018-01-12 |
| ES2643987T3 (es) | 2017-11-27 |
| US20150144529A1 (en) | 2015-05-28 |
| FR3013720A1 (fr) | 2015-05-29 |
| CN104673373A (zh) | 2015-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| HRP20171637T1 (hr) | Postupak za hidroobradu vakuumskog destilata upotrebom niza katalizatora | |
| CN102451722B (zh) | 一种蛋壳型加氢催化剂的制备方法 | |
| JP5060044B2 (ja) | 炭化水素油の水素化処理触媒およびその製造方法、並びに炭化水素油の水素化処理方法 | |
| TW201113360A (en) | Fuel oil base and aviation fuel composition containing same | |
| CN104673374B (zh) | 采用催化剂串联加氢处理柴油的方法 | |
| CN102994142B (zh) | 一种裂解汽油加氢精制的方法 | |
| CN102553567B (zh) | 以氧化铝为载体的含vb金属组分的加氢催化剂、制备及其应用 | |
| CN103702757B (zh) | 用于烃催化加氢处理的具有活性金属或前体、胺组分和不含胺的极性添加剂的组合物及其制备方法 | |
| CN104998668A (zh) | 一种植物油加氢生产高十六烷值柴油的催化剂及其制备使用方法 | |
| CN105745019A (zh) | 制备加氢处理催化剂的方法 | |
| CN104841458A (zh) | 一种负载型硫化态加氢催化剂及其制备方法 | |
| CN103260753A (zh) | 加氢处理催化剂及其制备方法 | |
| CN102652919B (zh) | 以含硼氧化铝为载体的加氢脱金属催化剂、制备及其应用 | |
| CN103703108B (zh) | 用于烃催化加氢处理的醚胺添加剂浸渍的组合物及其制备方法 | |
| CN103386327B (zh) | 一种选择性加氢脱硫催化剂及其制备和应用 | |
| CN103100391A (zh) | 一种蛋壳型加氢催化剂的制备方法 | |
| CN110064405B (zh) | 一种具有脱硫活性的加氢处理催化剂的制备方法 | |
| CN104275191B (zh) | 一种用于fcc汽油预加氢的催化剂及其制备方法 | |
| CN103769221A (zh) | 馏分油加氢处理催化剂的制备方法 | |
| CN103386310A (zh) | 一种二烯烃选择性加氢催化剂及其制备和应用 | |
| CN103801311B (zh) | 一种加氢处理催化剂的制备方法 | |
| CN103934019B (zh) | 一种生产超清洁低凝柴油催化剂的制备及应用方法 | |
| CN103468303B (zh) | 一种汽油选择性加氢脱硫方法 | |
| CN106179522B (zh) | 一种加氢催化剂的器外预硫化方法 | |
| CN105749933A (zh) | 一种加氢催化剂的制备方法 |