FR3119624B1 - Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene - Google Patents

Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene Download PDF

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Publication number
FR3119624B1
FR3119624B1 FR2101199A FR2101199A FR3119624B1 FR 3119624 B1 FR3119624 B1 FR 3119624B1 FR 2101199 A FR2101199 A FR 2101199A FR 2101199 A FR2101199 A FR 2101199A FR 3119624 B1 FR3119624 B1 FR 3119624B1
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France
Prior art keywords
nickel
tungsten
alumina
silica
vol
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Active
Application number
FR2101199A
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English (en)
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FR3119624A1 (fr
Inventor
Etienne Girard
Anne-Sophie Gay
Isabelle Merdrignac
Antoine Daudin
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR2101199A priority Critical patent/FR3119624B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to PCT/EP2022/052517 priority patent/WO2022171508A1/fr
Priority to KR1020237029110A priority patent/KR20230143151A/ko
Priority to JP2023547596A priority patent/JP2024507480A/ja
Priority to CA3203989A priority patent/CA3203989A1/fr
Priority to EP22702739.8A priority patent/EP4291621A1/fr
Priority to CN202280014020.7A priority patent/CN116917446A/zh
Priority to TW111104227A priority patent/TW202239951A/zh
Publication of FR3119624A1 publication Critical patent/FR3119624A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)

Abstract

L'invention a pour objet un procédé d’hydrotraitement d'une charge hydrocarbonée ayant un intervalle de distillation compris entre 150°C et 600°C, de manière à obtenir un effluent hydrotraité, ledit procédé comportant les étapes suivantes : a) on met en contact en présence d'hydrogène ladite charge hydrocarbonée avec au moins un premier catalyseur occupant un volume V1 et comprenant un support à base d'alumine ou de silice ou de silice-alumine et une phase active constituée de nickel et de molybdène, b) on met en contact en présence d'hydrogène l'effluent obtenu à l'étape a) avec au moins un deuxième catalyseur occupant un volume V2 et comprenant un support à base d'alumine ou de silice ou de silice-alumine et une phase active constituée de nickel, de molybdène et de tungstène, et du phosphore, la répartition des volumes V1/V2 étant comprise entre 50%vol/50%vol et 90%vol/10%vol respectivement.
FR2101199A 2021-02-09 2021-02-09 Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene Active FR3119624B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR2101199A FR3119624B1 (fr) 2021-02-09 2021-02-09 Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene
KR1020237029110A KR20230143151A (ko) 2021-02-09 2022-02-03 니켈, 몰리브덴 및 텅스텐 기반 촉매로 촉매의 시퀀스를 사용하는 수소화처리 공정
JP2023547596A JP2024507480A (ja) 2021-02-09 2022-02-03 ニッケル、モリブデンおよびタングステンをベースとする触媒を有する触媒配列を使用する水素化処理方法
CA3203989A CA3203989A1 (fr) 2021-02-09 2022-02-03 Procede d'hydrotraitement mettant en oeuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene
PCT/EP2022/052517 WO2022171508A1 (fr) 2021-02-09 2022-02-03 Procede d'hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene
EP22702739.8A EP4291621A1 (fr) 2021-02-09 2022-02-03 Procede d'hydrotraitement mettant en ouvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene
CN202280014020.7A CN116917446A (zh) 2021-02-09 2022-02-03 使用具有基于镍、钼和钨的催化剂的催化剂序列的加氢处理方法
TW111104227A TW202239951A (zh) 2021-02-09 2022-02-07 使用具有基於鎳、鉬及鎢之催化劑的催化劑序列之加氫處理方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2101199 2021-02-09
FR2101199A FR3119624B1 (fr) 2021-02-09 2021-02-09 Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene

Publications (2)

Publication Number Publication Date
FR3119624A1 FR3119624A1 (fr) 2022-08-12
FR3119624B1 true FR3119624B1 (fr) 2024-04-26

Family

ID=75339912

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2101199A Active FR3119624B1 (fr) 2021-02-09 2021-02-09 Procede d’hydrotraitement mettant en œuvre un enchainement de catalyseurs avec un catalyseur a base de nickel, molybdene et tungstene

Country Status (8)

Country Link
EP (1) EP4291621A1 (fr)
JP (1) JP2024507480A (fr)
KR (1) KR20230143151A (fr)
CN (1) CN116917446A (fr)
CA (1) CA3203989A1 (fr)
FR (1) FR3119624B1 (fr)
TW (1) TW202239951A (fr)
WO (1) WO2022171508A1 (fr)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5068025A (en) 1990-06-27 1991-11-26 Shell Oil Company Aromatics saturation process for diesel boiling-range hydrocarbons
CN1045099C (zh) 1996-09-11 1999-09-15 中国石油化工总公司 一种润滑油加氢补充精制工艺
WO2001074973A1 (fr) 2000-03-30 2001-10-11 Japan Energy Corporation Procede d'hydrodesulfuration d'une fraction d'huile legere
US7816299B2 (en) 2003-11-10 2010-10-19 Exxonmobil Research And Engineering Company Hydrotreating catalyst system suitable for use in hydrotreating hydrocarbonaceous feedstreams
EP2486109A4 (fr) 2009-10-05 2013-03-27 Exxonmobil Res & Eng Co Empilement d'un catalyseur de faible activité ou régénéré sur un catalyseur d'activité plus élevée
CN102851070B (zh) 2011-06-30 2014-10-29 中国石油化工股份有限公司 一种生产超低硫柴油的方法
FR3013721B1 (fr) 2013-11-28 2015-11-13 Ifp Energies Now Procede d'hydrotraitement de gazole mettant en oeuvre un enchainement de catalyseurs
FR3013720B1 (fr) 2013-11-28 2015-11-13 IFP Energies Nouvelles Procede d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs
CN105435824B (zh) 2014-09-25 2018-05-18 中国石油化工股份有限公司 一种加氢催化剂组合物及其应用
FR3094985B1 (fr) * 2019-04-12 2021-04-02 Axens Procédé d’hydrotraitement d’un naphta

Also Published As

Publication number Publication date
KR20230143151A (ko) 2023-10-11
CN116917446A (zh) 2023-10-20
EP4291621A1 (fr) 2023-12-20
FR3119624A1 (fr) 2022-08-12
JP2024507480A (ja) 2024-02-20
CA3203989A1 (fr) 2022-08-18
TW202239951A (zh) 2022-10-16
WO2022171508A1 (fr) 2022-08-18

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