GB916567A - Improvements in or relating to the treatment of cellulosic material - Google Patents

Improvements in or relating to the treatment of cellulosic material

Info

Publication number
GB916567A
GB916567A GB621761A GB621761A GB916567A GB 916567 A GB916567 A GB 916567A GB 621761 A GB621761 A GB 621761A GB 621761 A GB621761 A GB 621761A GB 916567 A GB916567 A GB 916567A
Authority
GB
United Kingdom
Prior art keywords
cellulosic material
cellulose
treatment
irradiation
rays
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB621761A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heberlein and Co AG
Original Assignee
Heberlein and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH308760A external-priority patent/CH407032A/en
Application filed by Heberlein and Co AG filed Critical Heberlein and Co AG
Publication of GB916567A publication Critical patent/GB916567A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/082—Gamma-radiation only
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/008—Treatment with radioactive elements or with neutrons, alpha, beta or gamma rays
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D06M10/10—Macromolecular compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

Cellulosic material, preferably with moisture content at least 20%, is treated with ionising radiation in the substantial absence of oxygen, e.g. on an inert gas or in a vacuum, thereby inducing cross-linking without the need for the heating step required in Specification 895,479. Cellulosic material includes yarns, fibres, threads and fabrics derived wholly or partly from natural cellulose, e.g. cotton; regenerated cellulose, e.g. viscose rayon, cellulose derivatives, e.g. cellulose acetate, regenerated cellulose film and paper. Preferred forms of radiation are g - b - and X-rays or dosages of 5 X 104 to 3 X 106 rads. Prior to irradiation, the material may be topochemically modified by treatment with compounds such as acrylic, methacrylic, crotonic and cinnamic acids, allyl derivatives, acrylonitrile, ethylene imine compounds, or p-isopropylbenzoyl chloride, which promote formation of active groups. The cellulosic material may also be protected against undue degradation during irradiation by treatment with e.g. phenols, cystine, cysteine and methanesulphonyl chloride. Examples describe the irradiation of cotton poplin fabric with g -rays. The tensile strength and resistance to abrasion and creasing is improved.
GB621761A 1959-05-21 1961-02-20 Improvements in or relating to the treatment of cellulosic material Expired GB916567A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH7349659A CH383325A (en) 1959-05-21 1959-05-21 Process for improving the mechanical properties of cellulose-containing textiles
CH308760A CH407032A (en) 1960-03-18 1960-03-18 Process for improving the mechanical properties of cellulose-containing textile material
CH486760A CH400993A (en) 1959-05-21 1960-04-29 Process for improving the mechanical properties of cellulose-containing textiles

Publications (1)

Publication Number Publication Date
GB916567A true GB916567A (en) 1963-01-23

Family

ID=27174117

Family Applications (3)

Application Number Title Priority Date Filing Date
GB929460A Expired GB895479A (en) 1959-05-21 1960-03-16 Improvements in or relating to cellulosic material
GB621761A Expired GB916567A (en) 1959-05-21 1961-02-20 Improvements in or relating to the treatment of cellulosic material
GB1135561A Expired GB925465A (en) 1959-05-21 1961-03-28 Improvements in or relating to the treatment of cellulosic material

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB929460A Expired GB895479A (en) 1959-05-21 1960-03-16 Improvements in or relating to cellulosic material

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1135561A Expired GB925465A (en) 1959-05-21 1961-03-28 Improvements in or relating to the treatment of cellulosic material

Country Status (6)

Country Link
BE (2) BE591044A (en)
CH (2) CH383325A (en)
DE (3) DE1276590B (en)
DK (1) DK102733C (en)
GB (3) GB895479A (en)
NL (3) NL248357A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2475571C1 (en) * 2011-10-21 2013-02-20 Александр Андреевич Клименко Method of producing carbon fibre material
CN116253925A (en) * 2023-03-21 2023-06-13 西南科技大学 Gradient irradiation modification method for cotton waste

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1042521B (en) * 1955-04-07 1958-11-06 Du Pont Process for the modification of fibers or films made from natural or regenerated natural polymers
US2895891A (en) * 1957-05-15 1959-07-21 Gen Electric Cellulosic materials

Also Published As

Publication number Publication date
GB925465A (en) 1963-05-08
NL258641A (en) 1964-04-27
BE591044A (en) 1960-11-21
DK102733C (en) 1965-10-04
DE1294338B (en) 1969-05-08
CH400993A (en) 1965-06-15
CH383325A (en) 1964-06-15
NL248357A (en) 1964-03-10
NL262964A (en) 1964-05-25
DE1419466A1 (en) 1969-02-06
GB895479A (en) 1962-05-02
DE1276590B (en) 1968-09-05
BE603226A (en) 1961-10-30

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