GB925465A - Improvements in or relating to the treatment of cellulosic material - Google Patents

Improvements in or relating to the treatment of cellulosic material

Info

Publication number
GB925465A
GB925465A GB1135561A GB1135561A GB925465A GB 925465 A GB925465 A GB 925465A GB 1135561 A GB1135561 A GB 1135561A GB 1135561 A GB1135561 A GB 1135561A GB 925465 A GB925465 A GB 925465A
Authority
GB
United Kingdom
Prior art keywords
irradiated
cotton
rads
mev
rad
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1135561A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heberlein and Co AG
Original Assignee
Heberlein and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH308760A external-priority patent/CH407032A/en
Application filed by Heberlein and Co AG filed Critical Heberlein and Co AG
Publication of GB925465A publication Critical patent/GB925465A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/082—Gamma-radiation only
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/008—Treatment with radioactive elements or with neutrons, alpha, beta or gamma rays
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D06M10/10—Macromolecular compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

Cellulosic material, particularly cellulosic textile material, is irradiated with accelerated electron beams (b -rays) having a particle energy of less than 1 MeV, and preferably 0,05-0,6 MeV, the material being heated during or after irradiation to induce cross-linking between cellulose molecules with consequent improvement in mechanical properties such as dimensional stability, and resistance to shrinking and abrasion. Suitable radiation is conveniently derived from electron accelerators, or from radio-active sources, e.g. Sr90 or Kr85. The total dosage of radiation, usually 103-107 rad. and preferably 104-106 rad. (1 roentgen=0,83 rads., approx.) is sufficient to effect the desired cross-linking while leaving the mechanical properties of the material unimpaired. The cellulosic material may be topochemically modified, prior to irradiation, by compounds such as isopropylbenzoyl chloride, which promotes the formation of "active" groups as in the parent Specification. The process may be applied to yarns, filaments, threads or woven, non-woven or knitted fabrics composed wholly or partly of natural cellulose, e.g. cotton or of regenerated cellulose, and also regenerated cellulose film and paper. In the examples, bleached poplin, renforc<\>e cotton and bleached cotton voile are irradiated to a total dosage of 105-106 rads. Heating of the irradiated material is effected by steam or warm air.
GB1135561A 1959-05-21 1961-03-28 Improvements in or relating to the treatment of cellulosic material Expired GB925465A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH7349659A CH383325A (en) 1959-05-21 1959-05-21 Process for improving the mechanical properties of cellulose-containing textiles
CH308760A CH407032A (en) 1960-03-18 1960-03-18 Process for improving the mechanical properties of cellulose-containing textile material
CH486760A CH400993A (en) 1959-05-21 1960-04-29 Process for improving the mechanical properties of cellulose-containing textiles

Publications (1)

Publication Number Publication Date
GB925465A true GB925465A (en) 1963-05-08

Family

ID=27174117

Family Applications (3)

Application Number Title Priority Date Filing Date
GB929460A Expired GB895479A (en) 1959-05-21 1960-03-16 Improvements in or relating to cellulosic material
GB621761A Expired GB916567A (en) 1959-05-21 1961-02-20 Improvements in or relating to the treatment of cellulosic material
GB1135561A Expired GB925465A (en) 1959-05-21 1961-03-28 Improvements in or relating to the treatment of cellulosic material

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB929460A Expired GB895479A (en) 1959-05-21 1960-03-16 Improvements in or relating to cellulosic material
GB621761A Expired GB916567A (en) 1959-05-21 1961-02-20 Improvements in or relating to the treatment of cellulosic material

Country Status (6)

Country Link
BE (2) BE591044A (en)
CH (2) CH383325A (en)
DE (3) DE1276590B (en)
DK (1) DK102733C (en)
GB (3) GB895479A (en)
NL (3) NL248357A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2475571C1 (en) * 2011-10-21 2013-02-20 Александр Андреевич Клименко Method of producing carbon fibre material
CN116253925A (en) * 2023-03-21 2023-06-13 西南科技大学 Gradient irradiation modification method for cotton waste

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1042521B (en) * 1955-04-07 1958-11-06 Du Pont Process for the modification of fibers or films made from natural or regenerated natural polymers
US2895891A (en) * 1957-05-15 1959-07-21 Gen Electric Cellulosic materials

Also Published As

Publication number Publication date
NL248357A (en) 1964-03-10
GB916567A (en) 1963-01-23
GB895479A (en) 1962-05-02
NL262964A (en) 1964-05-25
DE1419466A1 (en) 1969-02-06
NL258641A (en) 1964-04-27
BE591044A (en) 1960-11-21
BE603226A (en) 1961-10-30
DE1276590B (en) 1968-09-05
DE1294338B (en) 1969-05-08
CH400993A (en) 1965-06-15
DK102733C (en) 1965-10-04
CH383325A (en) 1964-06-15

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