GB825031A - Improvements relating to the electrodeposition of nickel - Google Patents
Improvements relating to the electrodeposition of nickelInfo
- Publication number
- GB825031A GB825031A GB3957/58A GB395758A GB825031A GB 825031 A GB825031 A GB 825031A GB 3957/58 A GB3957/58 A GB 3957/58A GB 395758 A GB395758 A GB 395758A GB 825031 A GB825031 A GB 825031A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- chloride
- black
- bismuth
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 16
- 229910052759 nickel Inorganic materials 0.000 title abstract 8
- 238000004070 electrodeposition Methods 0.000 title 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 abstract 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- 229910001152 Bi alloy Inorganic materials 0.000 abstract 1
- 229910001369 Brass Inorganic materials 0.000 abstract 1
- 229910001018 Cast iron Inorganic materials 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910000881 Cu alloy Inorganic materials 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003929 acidic solution Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- PEEDYJQEMCKDDX-UHFFFAOYSA-N antimony bismuth Chemical compound [Sb].[Bi] PEEDYJQEMCKDDX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- JWVAUCBYEDDGAD-UHFFFAOYSA-N bismuth tin Chemical compound [Sn].[Bi] JWVAUCBYEDDGAD-UHFFFAOYSA-N 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 239000010951 brass Substances 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 150000004687 hexahydrates Chemical class 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- 239000010970 precious metal Substances 0.000 abstract 1
- 239000008262 pumice Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 abstract 1
- 239000010935 stainless steel Substances 0.000 abstract 1
- 229910001220 stainless steel Inorganic materials 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9265—Special properties
- Y10S428/927—Decorative informative
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12944—Ni-base component
Abstract
825,031. Electrodepositing black nickel finish on metals. MOND NICKEL CO. Ltd. Feb. 6, 1958 [Feb. 15, 1957], No. 3957/58. Class 41. A bath for electrodepositing black nickel consists of an aqueous acidic solution containing at least 50 g/l. nickel chloride (calculated as NiCl 2 .6H 2 O), from 7.5 to 45 g/l. ammonium chloride, from 7.5 to 30 g/l. sodium thiocyanate, and from 15 to 60 g/l. zinc chloride. In use the current density is related to the concentration of nickel chloride as shown in the graph, the minimum current density being 0.108 amps/ sq. dm. In practice the nickel chloride concentration does not exceed 165 g/l. of the hexahydrate and the pH is between 2.3 and 5.5 the lower pH values being obtained by addition of hydrochloric or, less desirably, sulphuric acid. Preferably a base of wrought nickel or nickelplated steel is scrubbed with pumice, cathodically cleaned in an alkaline cleaner, and then anodically treated in a chloride nickel electroplating bath, which may contain boric acid and an anti-pitting agent, followed by plating with nickel on reversal of current, whereafter the black nickel finish is deposited using a wrought nickel anode. Other bases referred to are stainless steel, copper alloys, cast iron, and precious metals and their alloys while the undercoat for the black nickel deposit may be copper, silver, cobalt, chromium, lead, cadmium, zinc, tin, antimony, bismuth, gold, cobalt-nickel, tin-bismuth and antimony-bismuth alloys, and brass.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US640373A US2844530A (en) | 1957-02-15 | 1957-02-15 | Black nickel plating |
Publications (1)
Publication Number | Publication Date |
---|---|
GB825031A true GB825031A (en) | 1959-12-09 |
Family
ID=24567985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3957/58A Expired GB825031A (en) | 1957-02-15 | 1958-02-06 | Improvements relating to the electrodeposition of nickel |
Country Status (6)
Country | Link |
---|---|
US (1) | US2844530A (en) |
BE (1) | BE564818A (en) |
CH (1) | CH368679A (en) |
DE (1) | DE1068970B (en) |
FR (1) | FR1191571A (en) |
GB (1) | GB825031A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4282073A (en) | 1979-08-22 | 1981-08-04 | Thomas Steel Strip Corporation | Electro-co-deposition of corrosion resistant nickel/zinc alloys onto steel substrates |
US4351713A (en) * | 1979-08-22 | 1982-09-28 | Thomas Steel Strip Corp. | Electro-co-deposition of corrosion resistant nickel/zinc alloys onto steel substrates |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3064337A (en) * | 1958-05-19 | 1962-11-20 | Rockwell Standard Co | Composite metal article |
DE1254935B (en) * | 1960-12-31 | 1967-11-23 | Bayer Ag | Aqueous bath for chemical deposition of boron-containing metal coatings |
DE1243493B (en) * | 1961-02-04 | 1967-06-29 | Bayer Ag | Aqueous bath for chemical deposition of boron-containing metal coatings |
US3223598A (en) * | 1962-11-23 | 1965-12-14 | Germaine F Jacky | Method for determining the adhesion of metal plating |
US3454376A (en) * | 1966-06-06 | 1969-07-08 | Clevite Corp | Metal composite and method of making same |
GB1282373A (en) * | 1969-10-15 | 1972-07-19 | A I C Approvvigionamenti Ind C | Nickel-chromium electroplating |
US3920413A (en) * | 1974-04-05 | 1975-11-18 | Nasa | Panel for selectively absorbing solar thermal energy and the method of producing said panel |
JPS5192739A (en) * | 1975-02-13 | 1976-08-14 | Tairyukaseito taisumatsujiseino suguretadenkiburiki | |
DE2556716C2 (en) * | 1975-12-17 | 1983-11-24 | Philips Patentverwaltung Gmbh, 2000 Hamburg | Electrolytically produced layers with the properties of a black body, which is almost ideal in the solar spectrum |
IT1111112B (en) * | 1978-06-02 | 1986-01-13 | Mahdjuri Sabet Faramarz | SELECTIVE LAYER FOR SOLAR COLLECTOR ABSORBING COMPARTMENTS |
JPS5565389A (en) * | 1978-11-09 | 1980-05-16 | Toshiba Corp | Forming method of black alloy plating film for selective absorption of solar heat |
US4313802A (en) * | 1979-02-15 | 1982-02-02 | Sumitomo Metal Industries, Ltd. | Method of plating steel strip with nickel-zinc alloy |
US4244790A (en) * | 1979-08-31 | 1981-01-13 | Oxy Metal Industries Corporation | Composition and method for electrodeposition of black nickel |
US4350574A (en) * | 1981-03-23 | 1982-09-21 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Method for depositing an oxide coating |
US4422920A (en) * | 1981-07-20 | 1983-12-27 | Occidental Chemical Corporation | Hydrogen cathode |
US4416737A (en) * | 1982-02-11 | 1983-11-22 | National Steel Corporation | Process of electroplating a nickel-zinc alloy on steel strip |
DE3414048A1 (en) * | 1984-04-13 | 1985-10-17 | Nisshin Steel Co., Ltd., Tokio/Tokyo | METHOD FOR PRODUCING STEEL PARTS GALVANIZED WITH A ZINC-NICKEL ALLOY |
JPS60228693A (en) * | 1984-04-25 | 1985-11-13 | Kawasaki Steel Corp | Manufacture of steel plate plated with zn-ni alloy |
US4750976A (en) * | 1984-12-19 | 1988-06-14 | Blasberg Oberflachentechnik Gmbh | Electrically conductive copper layers and process for preparing same |
IL118281A (en) * | 1996-05-15 | 2000-06-29 | Nickel Rainbow Ltd | Articles having a colored metallic coating and process for their manufacture |
US5908542A (en) * | 1997-07-02 | 1999-06-01 | Gould Electronics Inc. | Metal foil with improved bonding to substrates and method for making the foil |
DE19946481A1 (en) * | 1999-09-28 | 2001-03-29 | Surtec Produkte Und Systeme Fu | Electrocatalyst |
US6800190B1 (en) * | 2000-05-16 | 2004-10-05 | Steven F. Wilcox | Method to obtain a variety of surface colors by electroplating zinc nickel and nickel alloy oxides |
US20140076798A1 (en) | 2010-06-30 | 2014-03-20 | Schauenburg Ruhrkunststoff Gmbh | Tribologically Loadable Mixed Noble Metal/Metal Layers |
US20140287208A1 (en) * | 2013-03-22 | 2014-09-25 | Surface Technology, Inc. | Blackened composite electroless nickel coatings |
CN106399683A (en) * | 2016-12-06 | 2017-02-15 | 崔海林 | Method for wet extraction of nickel and copper metal from nickel-copper ore |
CN109576740B (en) * | 2019-01-29 | 2020-12-22 | 深圳奕创表面处理科技有限公司 | Bright black nickel electroplating solution and preparation method thereof, electroplated part and electroplating method of bright black nickel |
CN113445088B (en) * | 2021-06-28 | 2021-12-14 | 沈伟 | Vapor chamber with high heat absorption and preparation method thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR590746A (en) * | 1924-02-16 | 1925-06-22 | Grauer Et Weil | Bath for black nickel plating of all metals by electrolysis |
US2679475A (en) * | 1952-01-21 | 1954-05-25 | Joseph C Singler | Metal blackening composition and method |
-
0
- BE BE564818D patent/BE564818A/xx unknown
- DE DENDAT1068970D patent/DE1068970B/en active Pending
-
1957
- 1957-02-15 US US640373A patent/US2844530A/en not_active Expired - Lifetime
-
1958
- 1958-02-06 GB GB3957/58A patent/GB825031A/en not_active Expired
- 1958-02-14 CH CH5590258A patent/CH368679A/en unknown
- 1958-02-14 FR FR1191571D patent/FR1191571A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4282073A (en) | 1979-08-22 | 1981-08-04 | Thomas Steel Strip Corporation | Electro-co-deposition of corrosion resistant nickel/zinc alloys onto steel substrates |
US4351713A (en) * | 1979-08-22 | 1982-09-28 | Thomas Steel Strip Corp. | Electro-co-deposition of corrosion resistant nickel/zinc alloys onto steel substrates |
Also Published As
Publication number | Publication date |
---|---|
US2844530A (en) | 1958-07-22 |
BE564818A (en) | |
DE1068970B (en) | 1959-11-12 |
CH368679A (en) | 1963-04-15 |
FR1191571A (en) | 1959-10-20 |
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