GB691024A - Improvements in or relating to the production of oximes - Google Patents
Improvements in or relating to the production of oximesInfo
- Publication number
- GB691024A GB691024A GB7062/51A GB706251A GB691024A GB 691024 A GB691024 A GB 691024A GB 7062/51 A GB7062/51 A GB 7062/51A GB 706251 A GB706251 A GB 706251A GB 691024 A GB691024 A GB 691024A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ammonia
- oximes
- cyclic
- sulphides
- relating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cyclic oximes are produced by the reduction of cyclic nitroparaffins with soluble sulphides such as neutral or acid sulphides of alkalies and alkaline earth metals and ammonia, and polysulphides, preferably in solution in an alcohol solvent, or water, at room or raised temperatures, and under non-oxidizing conditions and increased pressure. In examples, nitrocyclohexane is reduced to the corresponding oxime by sodium hydrosulphide, ammonium polysulphide, and the introduction of ammonia and hydrogen sulphide in alcoholic solvents.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL691024X | 1950-03-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB691024A true GB691024A (en) | 1953-05-06 |
Family
ID=19807382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7062/51A Expired GB691024A (en) | 1950-03-31 | 1951-03-27 | Improvements in or relating to the production of oximes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB691024A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE966201C (en) * | 1953-08-14 | 1957-07-18 | Bayer Ag | Process for the preparation of cyclohexanone oxime by catalytic hydrogenation of nitrocyclohexane salts |
DE1022221B (en) * | 1954-10-25 | 1958-01-09 | Du Pont | Process for the preparation of cyclohexanone oxime and its alkyl ethers |
-
1951
- 1951-03-27 GB GB7062/51A patent/GB691024A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE966201C (en) * | 1953-08-14 | 1957-07-18 | Bayer Ag | Process for the preparation of cyclohexanone oxime by catalytic hydrogenation of nitrocyclohexane salts |
DE1022221B (en) * | 1954-10-25 | 1958-01-09 | Du Pont | Process for the preparation of cyclohexanone oxime and its alkyl ethers |
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