GB691024A - Improvements in or relating to the production of oximes - Google Patents

Improvements in or relating to the production of oximes

Info

Publication number
GB691024A
GB691024A GB7062/51A GB706251A GB691024A GB 691024 A GB691024 A GB 691024A GB 7062/51 A GB7062/51 A GB 7062/51A GB 706251 A GB706251 A GB 706251A GB 691024 A GB691024 A GB 691024A
Authority
GB
United Kingdom
Prior art keywords
ammonia
oximes
cyclic
sulphides
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7062/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Directie van de Staatsmijnen in Limburg
Original Assignee
Directie van de Staatsmijnen in Limburg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Directie van de Staatsmijnen in Limburg filed Critical Directie van de Staatsmijnen in Limburg
Publication of GB691024A publication Critical patent/GB691024A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06Preparation of nitro compounds
    • C07C201/08Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Cyclic oximes are produced by the reduction of cyclic nitroparaffins with soluble sulphides such as neutral or acid sulphides of alkalies and alkaline earth metals and ammonia, and polysulphides, preferably in solution in an alcohol solvent, or water, at room or raised temperatures, and under non-oxidizing conditions and increased pressure. In examples, nitrocyclohexane is reduced to the corresponding oxime by sodium hydrosulphide, ammonium polysulphide, and the introduction of ammonia and hydrogen sulphide in alcoholic solvents.
GB7062/51A 1950-03-31 1951-03-27 Improvements in or relating to the production of oximes Expired GB691024A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL691024X 1950-03-31

Publications (1)

Publication Number Publication Date
GB691024A true GB691024A (en) 1953-05-06

Family

ID=19807382

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7062/51A Expired GB691024A (en) 1950-03-31 1951-03-27 Improvements in or relating to the production of oximes

Country Status (1)

Country Link
GB (1) GB691024A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966201C (en) * 1953-08-14 1957-07-18 Bayer Ag Process for the preparation of cyclohexanone oxime by catalytic hydrogenation of nitrocyclohexane salts
DE1022221B (en) * 1954-10-25 1958-01-09 Du Pont Process for the preparation of cyclohexanone oxime and its alkyl ethers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE966201C (en) * 1953-08-14 1957-07-18 Bayer Ag Process for the preparation of cyclohexanone oxime by catalytic hydrogenation of nitrocyclohexane salts
DE1022221B (en) * 1954-10-25 1958-01-09 Du Pont Process for the preparation of cyclohexanone oxime and its alkyl ethers

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