GB491948A - Process for the production of hard resistant surfaces on metals - Google Patents

Process for the production of hard resistant surfaces on metals

Info

Publication number
GB491948A
GB491948A GB33808/36A GB3380836A GB491948A GB 491948 A GB491948 A GB 491948A GB 33808/36 A GB33808/36 A GB 33808/36A GB 3380836 A GB3380836 A GB 3380836A GB 491948 A GB491948 A GB 491948A
Authority
GB
United Kingdom
Prior art keywords
carbonyl
tungsten
carbide
metals
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33808/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB491948A publication Critical patent/GB491948A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32Carbides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

A hard resistant surface consisting of a carbide such as tungsten or boron carbide is formed on metals, e.g. iron, steel, or light metals, by a method involving the decomposition of the corresponding carbonyl. The object to be coated may be placed in a vacuum or an indifferent atmosphere, the carbonyl introduced, and the object heated to a temperature considerably higher than the decomposition temperature of the carbonyl to cause deposition of the carbide. Alternatively the carbonyl can be introduced in solution in an organic solvent, e.g. benzene, which evaporates when the object is heated. The carbonyl decomposes at a comparatively low temperature, e.g. 300 DEG C. in the case of tungsten, and the tungsten is converted into carbide by the benzene vapour at above 800 DEG C. In another method a layer of tungsten is formed on the object by decomposition of the carbonyl, and this is then heated in a reducing carbon-containing atmosphere, e.g. carbon monoxide or a mixture of carbon monoxide and benzene vapour, to a temperature between 970 and 1300 DEG C.
GB33808/36A 1935-12-28 1936-12-09 Process for the production of hard resistant surfaces on metals Expired GB491948A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH491948X 1935-12-28

Publications (1)

Publication Number Publication Date
GB491948A true GB491948A (en) 1938-09-12

Family

ID=4516631

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33808/36A Expired GB491948A (en) 1935-12-28 1936-12-09 Process for the production of hard resistant surfaces on metals

Country Status (1)

Country Link
GB (1) GB491948A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523461A (en) * 1946-03-15 1950-09-26 John T Young Plating with metal carbonyl
US2602033A (en) * 1950-01-18 1952-07-01 Bell Telephone Labor Inc Carbonyl process
US2962388A (en) * 1954-03-12 1960-11-29 Metallgesellschaft Ag Process for the production of titanium carbide coatings
US3368914A (en) * 1964-08-05 1968-02-13 Texas Instruments Inc Process for adherently depositing a metal carbide on a metal substrate

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523461A (en) * 1946-03-15 1950-09-26 John T Young Plating with metal carbonyl
US2602033A (en) * 1950-01-18 1952-07-01 Bell Telephone Labor Inc Carbonyl process
US2962388A (en) * 1954-03-12 1960-11-29 Metallgesellschaft Ag Process for the production of titanium carbide coatings
US3368914A (en) * 1964-08-05 1968-02-13 Texas Instruments Inc Process for adherently depositing a metal carbide on a metal substrate

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