GB1394647A - Method to improve zinc electro deposition employing a quaternary compound - Google Patents
Method to improve zinc electro deposition employing a quaternary compoundInfo
- Publication number
- GB1394647A GB1394647A GB1826473A GB1826473A GB1394647A GB 1394647 A GB1394647 A GB 1394647A GB 1826473 A GB1826473 A GB 1826473A GB 1826473 A GB1826473 A GB 1826473A GB 1394647 A GB1394647 A GB 1394647A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- brightener
- acid
- electro
- zincate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011701 zinc Substances 0.000 title abstract 3
- 229910052725 zinc Inorganic materials 0.000 title abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- 238000004070 electrodeposition Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- -1 alkali metal zincate Chemical class 0.000 abstract 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000002466 imines Chemical class 0.000 abstract 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 abstract 2
- RLIPQCDHACHPJW-UHFFFAOYSA-N 2,3,4-trimethylaniline Chemical group CC1=CC=C(N)C(C)=C1C RLIPQCDHACHPJW-UHFFFAOYSA-N 0.000 abstract 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 abstract 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- 239000001828 Gelatine Substances 0.000 abstract 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 abstract 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000001888 Peptone Substances 0.000 abstract 1
- 108010080698 Peptones Proteins 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 abstract 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 1
- 229940073608 benzyl chloride Drugs 0.000 abstract 1
- 229960003237 betaine Drugs 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- MXHTZQSKTCCMFG-UHFFFAOYSA-N n,n-dibenzyl-1-phenylmethanamine Chemical group C=1C=CC=CC=1CN(CC=1C=CC=CC=1)CC1=CC=CC=C1 MXHTZQSKTCCMFG-UHFFFAOYSA-N 0.000 abstract 1
- 235000001968 nicotinic acid Nutrition 0.000 abstract 1
- 239000011664 nicotinic acid Substances 0.000 abstract 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 abstract 1
- 235000019319 peptone Nutrition 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical group CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 abstract 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 abstract 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00321429A US3853718A (en) | 1973-01-05 | 1973-01-05 | Method to improve zinc deposition employing multi-nitrogen quaternaries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1394647A true GB1394647A (en) | 1975-05-21 |
Family
ID=23250574
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1826473A Expired GB1394647A (en) | 1973-01-05 | 1973-04-16 | Method to improve zinc electro deposition employing a quaternary compound |
Country Status (11)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294472A (en) * | 1994-10-25 | 1996-05-01 | Enthone Omi Inc | Cationic quaternary ammonium polymer additive in alkaline zinc and zinc alloy electroplating baths |
| CN102953095A (zh) * | 2012-08-15 | 2013-03-06 | 长江润发(江苏)薄板镀层有限公司 | 一种无铬无氰耐指纹板 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954575A (en) * | 1972-11-10 | 1976-05-04 | Dipsol Chemicals Co., Ltd. | Zinc electroplating |
| US3853718A (en) * | 1973-01-05 | 1974-12-10 | Oxy Metal Finishing Corp | Method to improve zinc deposition employing multi-nitrogen quaternaries |
| JPS5332771B2 (enrdf_load_stackoverflow) * | 1973-12-10 | 1978-09-09 | ||
| US3957595A (en) * | 1975-01-10 | 1976-05-18 | Nalco Chemical Company | Zinc electroplating |
| FR2307060A1 (fr) * | 1975-04-09 | 1976-11-05 | Popescu Francine | Zingage galvanique alcalin brillant |
| US3988219A (en) * | 1975-07-07 | 1976-10-26 | Columbia Chemical Corporation | Baths and additives for the electrodeposition of bright zinc |
| US4046648A (en) * | 1975-09-29 | 1977-09-06 | E. I. Du Pont De Nemours And Company | Polyamine additives in alkaline zinc electroplating |
| DE2658934C3 (de) * | 1976-12-24 | 1980-01-03 | Basf Ag, 6700 Ludwigshafen | Wäßriges cyanidfreies alkalisches Zinkbad zur galvanischen Erzeugung hochglänzender Zinküberzüge |
| CA1119997A (en) * | 1977-05-04 | 1982-03-16 | Bento Dafonte | Electrodeposition of zinc |
| DE2740592C2 (de) * | 1977-09-09 | 1981-11-19 | Basf Ag, 6700 Ludwigshafen | Galvanisches Zinkbad |
| US4169771A (en) * | 1978-04-20 | 1979-10-02 | Oxy Metal Industries Corporation | Ductile bright zinc electroplating bath and process and additive therefor |
| US4229267A (en) * | 1979-06-01 | 1980-10-21 | Richardson Chemical Company | Alkaline bright zinc plating and additive therefor |
| US4366036A (en) * | 1981-09-08 | 1982-12-28 | Occidental Chemical Corporation | Additive and alkaline zinc electroplating bath and process using same |
| US5578187A (en) * | 1995-10-19 | 1996-11-26 | Enthone-Omi, Inc. | Plating process for electroless nickel on zinc die castings |
| US6143160A (en) * | 1998-09-18 | 2000-11-07 | Pavco, Inc. | Method for improving the macro throwing power for chloride zinc electroplating baths |
| JP4570738B2 (ja) * | 1999-08-05 | 2010-10-27 | 日本表面化学株式会社 | 電気亜鉛めっき浴及びめっき方法 |
| US9899695B2 (en) | 2015-05-22 | 2018-02-20 | General Electric Company | Zinc-based electrolyte compositions, and related electrochemical processes and articles |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451426A (en) * | 1943-11-25 | 1948-10-12 | Du Pont | Bright zinc plating |
| US2791554A (en) * | 1954-09-22 | 1957-05-07 | Ann F Hull | Method of electrodepositing zinc |
| US3227638A (en) * | 1961-06-16 | 1966-01-04 | Robert H Burnson | Alkali cyanide bath and process for electroplating therewith |
| US3318787A (en) * | 1964-02-07 | 1967-05-09 | Udylite Corp | Electrodeposition of zinc |
| FR1480997A (fr) * | 1966-05-25 | 1967-05-12 | Schering Ag | Bain de brillantage zincique alcalin, ne contenant pas de cyanures |
| US3393135A (en) * | 1965-08-05 | 1968-07-16 | Enthone | Bright zinc electro-plating |
| US3642589A (en) * | 1969-09-29 | 1972-02-15 | Fred I Nobel | Gold alloy electroplating baths |
| US3655534A (en) * | 1970-02-24 | 1972-04-11 | Enthone | Alkaline bright zinc electroplating |
| US3853718A (en) * | 1973-01-05 | 1974-12-10 | Oxy Metal Finishing Corp | Method to improve zinc deposition employing multi-nitrogen quaternaries |
-
1973
- 1973-01-05 US US00321429A patent/US3853718A/en not_active Expired - Lifetime
- 1973-03-27 NL NLAANVRAGE7304240,A patent/NL175441C/xx not_active IP Right Cessation
- 1973-03-29 FR FR7311418A patent/FR2213349B1/fr not_active Expired
- 1973-04-10 BR BR2573/73A patent/BR7302573D0/pt unknown
- 1973-04-14 DE DE2318985A patent/DE2318985C2/de not_active Expired
- 1973-04-16 GB GB1826473A patent/GB1394647A/en not_active Expired
- 1973-04-16 ES ES413796A patent/ES413796A1/es not_active Expired
- 1973-04-16 CA CA169,010A patent/CA1026263A/en not_active Expired
- 1973-04-16 IT IT49468/73A patent/IT980227B/it active
- 1973-04-17 AR AR247597A patent/AR197893A1/es active
- 1973-04-17 JP JP4355173A patent/JPS5711960B2/ja not_active Expired
-
1981
- 1981-09-16 JP JP56146034A patent/JPS5782490A/ja active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294472A (en) * | 1994-10-25 | 1996-05-01 | Enthone Omi Inc | Cationic quaternary ammonium polymer additive in alkaline zinc and zinc alloy electroplating baths |
| GB2294472B (en) * | 1994-10-25 | 1998-04-29 | Enthone Omi Inc | Alkaline zinc and zinc alloy electroplating baths and processes |
| CN102953095A (zh) * | 2012-08-15 | 2013-03-06 | 长江润发(江苏)薄板镀层有限公司 | 一种无铬无氰耐指纹板 |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7304240A (enrdf_load_stackoverflow) | 1974-07-09 |
| FR2213349A1 (enrdf_load_stackoverflow) | 1974-08-02 |
| NL175441C (nl) | 1984-11-01 |
| IT980227B (it) | 1974-09-30 |
| NL175441B (nl) | 1984-06-01 |
| AR197893A1 (es) | 1974-05-15 |
| BR7302573D0 (pt) | 1974-08-29 |
| DE2318985C2 (de) | 1982-07-22 |
| DE2318985A1 (de) | 1974-07-18 |
| JPS5711960B2 (enrdf_load_stackoverflow) | 1982-03-08 |
| CA1026263A (en) | 1978-02-14 |
| JPS5782490A (en) | 1982-05-22 |
| JPS4998733A (enrdf_load_stackoverflow) | 1974-09-18 |
| US3853718A (en) | 1974-12-10 |
| ES413796A1 (es) | 1976-01-16 |
| FR2213349B1 (enrdf_load_stackoverflow) | 1977-04-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |