FR2861726B1 - Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante - Google Patents

Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante

Info

Publication number
FR2861726B1
FR2861726B1 FR0312921A FR0312921A FR2861726B1 FR 2861726 B1 FR2861726 B1 FR 2861726B1 FR 0312921 A FR0312921 A FR 0312921A FR 0312921 A FR0312921 A FR 0312921A FR 2861726 B1 FR2861726 B1 FR 2861726B1
Authority
FR
France
Prior art keywords
diastereoselectivity
wadsworth
horner
olefins
enhances
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0312921A
Other languages
English (en)
Other versions
FR2861726A1 (fr
Inventor
Francois Touchard
Jalmes Laurent Saint
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Solutions UK Ltd
Original Assignee
Rhodia Consumer Specialties Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Consumer Specialties Ltd filed Critical Rhodia Consumer Specialties Ltd
Priority to FR0312921A priority Critical patent/FR2861726B1/fr
Priority to EP04805384A priority patent/EP1680382A1/fr
Priority to PCT/FR2004/002834 priority patent/WO2005044757A1/fr
Priority to CA002543880A priority patent/CA2543880A1/fr
Priority to US10/578,396 priority patent/US20070276153A1/en
Priority to CNA2004800323464A priority patent/CN1874974A/zh
Publication of FR2861726A1 publication Critical patent/FR2861726A1/fr
Application granted granted Critical
Publication of FR2861726B1 publication Critical patent/FR2861726B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4084—Esters with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
FR0312921A 2003-11-04 2003-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante Expired - Fee Related FR2861726B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR0312921A FR2861726B1 (fr) 2003-11-04 2003-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante
EP04805384A EP1680382A1 (fr) 2003-11-04 2004-11-04 Procede diastereoselectif de preparation d olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante
PCT/FR2004/002834 WO2005044757A1 (fr) 2003-11-04 2004-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante
CA002543880A CA2543880A1 (fr) 2003-11-04 2004-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante
US10/578,396 US20070276153A1 (en) 2003-11-04 2004-11-04 Diastereoselective Method of Preparing Olefins by Means of the Horner-Wadsworth-Emmons Reaction Using a Particular Phosphonate Which Improves Diastereoselectivity at all Temperatures Including at Ambient Temperature
CNA2004800323464A CN1874974A (zh) 2003-11-04 2004-11-04 通过使用改进在包括环境温度的所有温度下的非对映选择性的特定膦酸酯的 H o r n e r － W a d s wo r t h －E m m o n s反应来制备烯烃的非对映选择方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0312921A FR2861726B1 (fr) 2003-11-04 2003-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante

Publications (2)

Publication Number Publication Date
FR2861726A1 FR2861726A1 (fr) 2005-05-06
FR2861726B1 true FR2861726B1 (fr) 2006-03-10

Family

ID=34429877

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0312921A Expired - Fee Related FR2861726B1 (fr) 2003-11-04 2003-11-04 Procede diastereoselectif de preparation d'olefines par la reaction d'horner-wadsworth-emmons mettant en oeuvre un phosphonate particulier qui ameliore la diastereoselectivite a toutes temperatures y compris a temperature ambiante

Country Status (6)

Country Link
US (1) US20070276153A1 (fr)
EP (1) EP1680382A1 (fr)
CN (1) CN1874974A (fr)
CA (1) CA2543880A1 (fr)
FR (1) FR2861726B1 (fr)
WO (1) WO2005044757A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011080736A1 (fr) 2009-12-29 2011-07-07 Mapi Pharma Hk Limited Composés intermédiaires et procédés pour la préparation de tapentadol et de composés apparentés
JP5928219B2 (ja) * 2012-07-24 2016-06-01 ダイキン工業株式会社 α−フルオロアクリル酸エステルの製造方法
CN107312039B (zh) 2012-08-30 2019-06-25 江苏豪森药业集团有限公司 一种替诺福韦前药的制备方法
CN105330652B (zh) * 2014-08-07 2019-04-05 天津法莫西医药科技有限公司 一种阿法替尼的制备方法
CN105439879B (zh) * 2014-08-07 2018-08-10 天津法莫西医药科技有限公司 一种反式-4-二甲胺基巴豆酸盐酸盐的制备方法
CN105622458A (zh) * 2015-12-22 2016-06-01 中国药科大学 (s)-4-氨基-2-甲基-5-苯基戊-1-烯-3-酮的制备方法
CN109438357A (zh) * 2018-11-05 2019-03-08 重庆科脉生物化工有限公司 一种咪唑类医药中间体kk-42的制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0734081A (ja) * 1993-07-23 1995-02-03 Tonen Corp 潤滑油組成物

Also Published As

Publication number Publication date
CA2543880A1 (fr) 2005-05-19
US20070276153A1 (en) 2007-11-29
WO2005044757A1 (fr) 2005-05-19
EP1680382A1 (fr) 2006-07-19
CN1874974A (zh) 2006-12-06
FR2861726A1 (fr) 2005-05-06

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Effective date: 20090731