FR2644934A1 - Procede de fabrication d'un composant tel qu'une eeprom flash, permettant de reduire les effets de la degradation associee aux cycles repetes d'utilisation de ce composant - Google Patents
Procede de fabrication d'un composant tel qu'une eeprom flash, permettant de reduire les effets de la degradation associee aux cycles repetes d'utilisation de ce composant Download PDFInfo
- Publication number
- FR2644934A1 FR2644934A1 FR9003536A FR9003536A FR2644934A1 FR 2644934 A1 FR2644934 A1 FR 2644934A1 FR 9003536 A FR9003536 A FR 9003536A FR 9003536 A FR9003536 A FR 9003536A FR 2644934 A1 FR2644934 A1 FR 2644934A1
- Authority
- FR
- France
- Prior art keywords
- layer
- component
- metal
- titanium
- regions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims description 47
- 230000015556 catabolic process Effects 0.000 title claims description 20
- 238000006731 degradation reaction Methods 0.000 title claims description 20
- 230000000694 effects Effects 0.000 title claims description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 46
- 239000002184 metal Substances 0.000 claims abstract description 46
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 28
- 239000001257 hydrogen Substances 0.000 claims abstract description 28
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000001465 metallisation Methods 0.000 claims abstract description 17
- 238000000151 deposition Methods 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 230000004888 barrier function Effects 0.000 claims description 46
- 230000015654 memory Effects 0.000 claims description 38
- 239000010936 titanium Substances 0.000 claims description 31
- 229910052719 titanium Inorganic materials 0.000 claims description 31
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 28
- 239000002784 hot electron Substances 0.000 claims description 25
- 230000005669 field effect Effects 0.000 claims description 7
- 239000004065 semiconductor Substances 0.000 claims description 6
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 claims description 6
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000002161 passivation Methods 0.000 claims description 4
- 230000000593 degrading effect Effects 0.000 claims description 3
- 101100346656 Drosophila melanogaster strat gene Proteins 0.000 claims 1
- 230000008719 thickening Effects 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000000137 annealing Methods 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 6
- 238000000637 aluminium metallisation Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000000969 carrier Substances 0.000 description 3
- 238000002513 implantation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- 230000005641 tunneling Effects 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- -1 or effect tunnel Substances 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
- H01L29/7881—Programmable transistors with only two possible levels of programmation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53214—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being aluminium
- H01L23/53223—Additional layers associated with aluminium layers, e.g. adhesion, barrier, cladding layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/45—Ohmic electrodes
- H01L29/456—Ohmic electrodes on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Ceramic Engineering (AREA)
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
- Junction Field-Effect Transistors (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32730289A | 1989-03-22 | 1989-03-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2644934A1 true FR2644934A1 (fr) | 1990-09-28 |
Family
ID=23276001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR9003536A Withdrawn FR2644934A1 (fr) | 1989-03-22 | 1990-03-20 | Procede de fabrication d'un composant tel qu'une eeprom flash, permettant de reduire les effets de la degradation associee aux cycles repetes d'utilisation de ce composant |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPH02281663A (ja) |
DE (1) | DE4007895C2 (ja) |
FR (1) | FR2644934A1 (ja) |
GB (1) | GB2229575B (ja) |
HK (1) | HK1000976A1 (ja) |
IT (1) | IT1239459B (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR960015322B1 (ko) * | 1993-07-23 | 1996-11-07 | 현대전자산업 주식회사 | 차폐용 플레이트를 갖는 반도체소자 제조방법 |
JP2003297956A (ja) | 2002-04-04 | 2003-10-17 | Toshiba Corp | 半導体記憶装置及びその製造方法 |
JP4212299B2 (ja) | 2002-05-09 | 2009-01-21 | 株式会社東芝 | 不揮発性半導体記憶装置 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4288256A (en) * | 1977-12-23 | 1981-09-08 | International Business Machines Corporation | Method of making FET containing stacked gates |
GB2156586A (en) * | 1984-02-24 | 1985-10-09 | Hitachi Ltd | A semiconductor device with an insulated gate and an adjacent dense insulation layer |
US4566026A (en) * | 1984-04-25 | 1986-01-21 | Honeywell Inc. | Integrated circuit bimetal layer |
EP0260232A2 (en) * | 1986-08-28 | 1988-03-16 | STMicroelectronics S.r.l. | Process for making metal-semiconductor ohmic contacts |
GB2206234A (en) * | 1987-06-22 | 1988-12-29 | Standard Microsyst Smc | Multilayer metallization method for integrated circuits |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3879746A (en) * | 1972-05-30 | 1975-04-22 | Bell Telephone Labor Inc | Gate metallization structure |
WO1981000487A1 (en) * | 1979-08-13 | 1981-02-19 | Ncr Co | Hydrogen annealing process for silicon gate memory device |
US4743564A (en) * | 1984-12-28 | 1988-05-10 | Kabushiki Kaisha Toshiba | Method for manufacturing a complementary MOS type semiconductor device |
JPS62143476A (ja) * | 1985-12-18 | 1987-06-26 | Fujitsu Ltd | 半導体記憶装置 |
US4707721A (en) * | 1986-02-20 | 1987-11-17 | Texas Instruments Incorporated | Passivated dual dielectric gate system and method for fabricating same |
CA1306072C (en) * | 1987-03-30 | 1992-08-04 | John E. Cronin | Refractory metal - titanium nitride conductive structures and processes for forming the same |
-
1990
- 1990-01-08 GB GB9000360A patent/GB2229575B/en not_active Expired - Lifetime
- 1990-03-13 DE DE4007895A patent/DE4007895C2/de not_active Expired - Lifetime
- 1990-03-19 IT IT19716A patent/IT1239459B/it active IP Right Grant
- 1990-03-20 FR FR9003536A patent/FR2644934A1/fr not_active Withdrawn
- 1990-03-22 JP JP2069896A patent/JPH02281663A/ja active Pending
-
1997
- 1997-12-23 HK HK97102597A patent/HK1000976A1/xx not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4288256A (en) * | 1977-12-23 | 1981-09-08 | International Business Machines Corporation | Method of making FET containing stacked gates |
GB2156586A (en) * | 1984-02-24 | 1985-10-09 | Hitachi Ltd | A semiconductor device with an insulated gate and an adjacent dense insulation layer |
US4566026A (en) * | 1984-04-25 | 1986-01-21 | Honeywell Inc. | Integrated circuit bimetal layer |
EP0260232A2 (en) * | 1986-08-28 | 1988-03-16 | STMicroelectronics S.r.l. | Process for making metal-semiconductor ohmic contacts |
GB2206234A (en) * | 1987-06-22 | 1988-12-29 | Standard Microsyst Smc | Multilayer metallization method for integrated circuits |
Also Published As
Publication number | Publication date |
---|---|
JPH02281663A (ja) | 1990-11-19 |
GB2229575B (en) | 1993-05-12 |
DE4007895C2 (de) | 2000-03-30 |
IT9019716A0 (it) | 1990-03-19 |
IT9019716A1 (it) | 1991-09-19 |
GB9000360D0 (en) | 1990-03-07 |
IT1239459B (it) | 1993-11-02 |
HK1000976A1 (en) | 1998-05-15 |
DE4007895A1 (de) | 1990-09-27 |
GB2229575A (en) | 1990-09-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |