FR2483445A1 - Procede de regulation de la vitesse de durcissement de compositions de caoutchouc de silicone - Google Patents
Procede de regulation de la vitesse de durcissement de compositions de caoutchouc de silicone Download PDFInfo
- Publication number
- FR2483445A1 FR2483445A1 FR8110859A FR8110859A FR2483445A1 FR 2483445 A1 FR2483445 A1 FR 2483445A1 FR 8110859 A FR8110859 A FR 8110859A FR 8110859 A FR8110859 A FR 8110859A FR 2483445 A1 FR2483445 A1 FR 2483445A1
- Authority
- FR
- France
- Prior art keywords
- vinyl
- radicals
- polysiloxane
- parts
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 28
- 239000004945 silicone rubber Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 83
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 40
- 230000000694 effects Effects 0.000 claims abstract description 4
- -1 polysiloxane Polymers 0.000 claims description 107
- 229920000642 polymer Polymers 0.000 claims description 53
- 229920001296 polysiloxane Polymers 0.000 claims description 52
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 51
- 150000001875 compounds Chemical class 0.000 claims description 42
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 229920002554 vinyl polymer Polymers 0.000 claims description 22
- 239000003112 inhibitor Substances 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 18
- 125000005372 silanol group Chemical group 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 230000002401 inhibitory effect Effects 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 7
- 125000001867 hydroperoxy group Chemical group [*]OO[H] 0.000 claims description 6
- 238000007259 addition reaction Methods 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 241001331845 Equus asinus x caballus Species 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000001698 pyrogenic effect Effects 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 17
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 150000004819 silanols Chemical group 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 description 18
- 238000001723 curing Methods 0.000 description 17
- 150000003254 radicals Chemical class 0.000 description 15
- 150000004678 hydrides Chemical class 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 239000000654 additive Substances 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 5
- 229910021485 fumed silica Inorganic materials 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 4
- 125000003709 fluoroalkyl group Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
- 229920002050 silicone resin Polymers 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 238000011067 equilibration Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 150000003058 platinum compounds Chemical class 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical compound O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- KBTYSDMXRXDGGC-UHFFFAOYSA-N 1-hydroperoxycyclohexan-1-ol Chemical compound OOC1(O)CCCCC1 KBTYSDMXRXDGGC-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 description 1
- JGBAASVQPMTVHO-UHFFFAOYSA-N 2,5-dihydroperoxy-2,5-dimethylhexane Chemical compound OOC(C)(C)CCC(C)(C)OO JGBAASVQPMTVHO-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- LIZVXGBYTGTTTI-UHFFFAOYSA-N 2-[(4-methylphenyl)sulfonylamino]-2-phenylacetic acid Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(C(O)=O)C1=CC=CC=C1 LIZVXGBYTGTTTI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 101150103171 DARS1 gene Proteins 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229910019032 PtCl2 Inorganic materials 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013006 addition curing Methods 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- FOEGXSBIOJIQDV-UHFFFAOYSA-N cyclopropane;hydrochloride Chemical compound Cl.C1CC1 FOEGXSBIOJIQDV-UHFFFAOYSA-N 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- LWIGVRDDANOFTD-UHFFFAOYSA-N hydroxy(dimethyl)silane Chemical compound C[SiH](C)O LWIGVRDDANOFTD-UHFFFAOYSA-N 0.000 description 1
- FDTBETCIPGWBHK-UHFFFAOYSA-N hydroxy-dimethyl-phenylsilane Chemical compound C[Si](C)(O)C1=CC=CC=C1 FDTBETCIPGWBHK-UHFFFAOYSA-N 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- DYGOPFFOGFHOIB-UHFFFAOYSA-N methylperoxyethane Chemical compound CCOOC DYGOPFFOGFHOIB-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- NNBZCPXTIHJBJL-UHFFFAOYSA-N trans-decahydronaphthalene Natural products C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15613780A | 1980-06-03 | 1980-06-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2483445A1 true FR2483445A1 (fr) | 1981-12-04 |
| FR2483445B1 FR2483445B1 (enrdf_load_stackoverflow) | 1985-03-08 |
Family
ID=22558265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8110859A Granted FR2483445A1 (fr) | 1980-06-03 | 1981-06-02 | Procede de regulation de la vitesse de durcissement de compositions de caoutchouc de silicone |
Country Status (11)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59176347A (ja) * | 1983-03-25 | 1984-10-05 | Toray Silicone Co Ltd | オルガノポリシロキサン組成物 |
| CA1267750A (en) * | 1985-07-12 | 1990-04-10 | Alexander Miutel | Low density foams |
| JPH07107137B2 (ja) * | 1986-09-19 | 1995-11-15 | 東レ・ダウコ−ニング・シリコ−ン株式会社 | 液状シリコ−ンゴム用オルガノポリシロキサン組成物 |
| US4943601A (en) * | 1989-04-03 | 1990-07-24 | General Electric Company | Coating with improved adhesion |
| CA2055957A1 (en) * | 1990-12-18 | 1992-06-19 | Edwin R. Evans | Vinyl-containing, silanol-terminated silicone compositions for treatment of fillers |
| US5442027A (en) * | 1994-06-23 | 1995-08-15 | Dow Corning Corporation | Moisture curable organosiloxane compositions exhibiting extended workability |
| TWI762649B (zh) * | 2017-06-26 | 2022-05-01 | 日商杜邦東麗特殊材料股份有限公司 | 黏晶用固化性矽組合物 |
| CN108517121A (zh) * | 2018-04-16 | 2018-09-11 | 吉林大学 | 一种搪塑模具硅胶翻印模的制作方法 |
| JP7026575B2 (ja) | 2018-05-22 | 2022-02-28 | 株式会社ニューフレアテクノロジー | 電子ビーム照射方法、電子ビーム照射装置、及びプログラム |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1185814B (de) * | 1959-12-16 | 1965-01-21 | Ici Ltd | Zu unter Waerme und Druck beziehungsweise unter Druck allein selbstabbindenden Elastomeren, vulkanisierbare Organopolysiloxanformmassen |
| DE1904588B2 (de) * | 1968-01-31 | 1970-12-03 | Dow Corning Corp., Midland, Mich. (V.St.A.) | Verzögerung und/oder Verhinderung der Härtung bei Raumtemperatur in Formmassen auf Grundlage von Organosiliciumverbir.dungen |
| US4061609A (en) * | 1976-04-09 | 1977-12-06 | General Electric Company | Inhibitor for platinum catalyzed silicone rubber compositions |
| DE2646726A1 (de) * | 1976-10-15 | 1978-04-20 | Wacker Chemie Gmbh | Verfahren zum regeln der geschwindigkeit der durch platinkatalysator gefoerderten anlagerung von si-gebundenem wasserstoff an aliphatische mehrfachbindungen enthaltendes organopolysiloxan |
| DE2654893A1 (de) * | 1976-12-03 | 1978-06-15 | Wacker Chemie Gmbh | Verfahren zum herstellen von klebrige stoffe abweisenden ueberzuegen |
| DE2502936B2 (de) * | 1974-01-25 | 1979-06-28 | Shinetsu Chemical Co., Tokio | Wärmehärtbare Organopolysiloxanformmassen |
| DE3018079A1 (de) * | 1979-05-16 | 1980-11-27 | Toray Silicone Co | Siliconmasse und ihre verwendung bei einem verfahren zur behandlung von glasfasern |
| GB2051101A (en) * | 1979-06-04 | 1981-01-14 | Dow Corning | Organopolysiloxane composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5146880A (en) * | 1974-10-18 | 1976-04-21 | Matsushita Electronics Corp | Toranjisuta |
-
1981
- 1981-05-20 NZ NZ197154A patent/NZ197154A/en unknown
- 1981-05-20 GB GB8115487A patent/GB2076841B/en not_active Expired
- 1981-05-26 AU AU71008/81A patent/AU7100881A/en not_active Abandoned
- 1981-05-26 ZA ZA00813540A patent/ZA813540B/xx unknown
- 1981-05-29 DE DE19813121260 patent/DE3121260A1/de not_active Withdrawn
- 1981-05-29 ES ES502635A patent/ES502635A0/es active Granted
- 1981-06-01 IT IT22066/81A patent/IT1137173B/it active
- 1981-06-02 NL NL8102666A patent/NL8102666A/nl not_active Application Discontinuation
- 1981-06-02 JP JP8394081A patent/JPS5723657A/ja active Granted
- 1981-06-02 FR FR8110859A patent/FR2483445A1/fr active Granted
- 1981-06-02 BE BE0/204970A patent/BE889056A/fr not_active IP Right Cessation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1185814B (de) * | 1959-12-16 | 1965-01-21 | Ici Ltd | Zu unter Waerme und Druck beziehungsweise unter Druck allein selbstabbindenden Elastomeren, vulkanisierbare Organopolysiloxanformmassen |
| DE1904588B2 (de) * | 1968-01-31 | 1970-12-03 | Dow Corning Corp., Midland, Mich. (V.St.A.) | Verzögerung und/oder Verhinderung der Härtung bei Raumtemperatur in Formmassen auf Grundlage von Organosiliciumverbir.dungen |
| DE2502936B2 (de) * | 1974-01-25 | 1979-06-28 | Shinetsu Chemical Co., Tokio | Wärmehärtbare Organopolysiloxanformmassen |
| US4061609A (en) * | 1976-04-09 | 1977-12-06 | General Electric Company | Inhibitor for platinum catalyzed silicone rubber compositions |
| DE2646726A1 (de) * | 1976-10-15 | 1978-04-20 | Wacker Chemie Gmbh | Verfahren zum regeln der geschwindigkeit der durch platinkatalysator gefoerderten anlagerung von si-gebundenem wasserstoff an aliphatische mehrfachbindungen enthaltendes organopolysiloxan |
| DE2654893A1 (de) * | 1976-12-03 | 1978-06-15 | Wacker Chemie Gmbh | Verfahren zum herstellen von klebrige stoffe abweisenden ueberzuegen |
| DE3018079A1 (de) * | 1979-05-16 | 1980-11-27 | Toray Silicone Co | Siliconmasse und ihre verwendung bei einem verfahren zur behandlung von glasfasern |
| GB2051101A (en) * | 1979-06-04 | 1981-01-14 | Dow Corning | Organopolysiloxane composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6353229B2 (enrdf_load_stackoverflow) | 1988-10-21 |
| NZ197154A (en) | 1984-02-03 |
| BE889056A (fr) | 1981-12-02 |
| FR2483445B1 (enrdf_load_stackoverflow) | 1985-03-08 |
| GB2076841A (en) | 1981-12-09 |
| DE3121260A1 (de) | 1982-05-19 |
| AU7100881A (en) | 1981-12-10 |
| NL8102666A (nl) | 1982-01-04 |
| IT1137173B (it) | 1986-09-03 |
| JPS5723657A (en) | 1982-02-06 |
| ES8300815A1 (es) | 1982-11-01 |
| ES502635A0 (es) | 1982-11-01 |
| ZA813540B (en) | 1982-08-25 |
| IT8122066A0 (it) | 1981-06-01 |
| GB2076841B (en) | 1985-06-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |