FR2457848A1 - Catalyseur pour la production d'ethylene a partir d'ethanol - Google Patents
Catalyseur pour la production d'ethylene a partir d'ethanolInfo
- Publication number
- FR2457848A1 FR2457848A1 FR8012052A FR8012052A FR2457848A1 FR 2457848 A1 FR2457848 A1 FR 2457848A1 FR 8012052 A FR8012052 A FR 8012052A FR 8012052 A FR8012052 A FR 8012052A FR 2457848 A1 FR2457848 A1 FR 2457848A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- weight
- ethanol
- ethylene
- selectivity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54068362A JPS5940057B2 (ja) | 1979-05-31 | 1979-05-31 | エタノ−ルからのエチレン製造用触媒 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2457848A1 true FR2457848A1 (fr) | 1980-12-26 |
| FR2457848B1 FR2457848B1 (cg-RX-API-DMAC10.html) | 1983-01-21 |
Family
ID=13371598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8012052A Granted FR2457848A1 (fr) | 1979-05-31 | 1980-05-30 | Catalyseur pour la production d'ethylene a partir d'ethanol |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4302357A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5940057B2 (cg-RX-API-DMAC10.html) |
| BR (1) | BR8003367A (cg-RX-API-DMAC10.html) |
| DE (2) | DE3050706C2 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2457848A1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB2049645B (cg-RX-API-DMAC10.html) |
| IN (1) | IN153076B (cg-RX-API-DMAC10.html) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176734U (ja) * | 1984-04-27 | 1985-11-22 | オルゴ株式会社 | ポツトの提げ手 |
| SG59937A1 (en) * | 1991-02-04 | 1999-02-22 | Mitsui Chemicals Inc | Process for producing lower olefins |
| US20060149109A1 (en) * | 2004-12-30 | 2006-07-06 | Ruziska Philip A | Converting methanol and ethanol to light olefins |
| CN104962586A (zh) | 2006-07-21 | 2015-10-07 | 希乐克公司 | 生物质转化系统 |
| CN101121624B (zh) * | 2006-08-11 | 2010-09-08 | 中国石油化工股份有限公司 | 乙醇脱水制乙烯的方法 |
| CN100582066C (zh) * | 2007-10-16 | 2010-01-20 | 南京工业大学 | 一种乙醇脱水生产乙烯的工艺 |
| EP2090561A1 (en) | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EP2108635A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| EP2108637A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol. |
| EP2108634A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EP2108636A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component. |
| JP5071175B2 (ja) * | 2008-03-11 | 2012-11-14 | 東ソー株式会社 | エチレンの製造法 |
| JP5071174B2 (ja) * | 2008-03-11 | 2012-11-14 | 東ソー株式会社 | エチレンの製法 |
| JP5698142B2 (ja) | 2008-11-28 | 2015-04-08 | トタル リサーチ アンド テクノロジー フエリユイ | 酸触媒存在下で使用前にアルコールを精製する方法 |
| EP2192101A1 (en) | 2008-11-28 | 2010-06-02 | Total Petrochemicals Research Feluy | Purification of alcohols prior to their use in the presence of an acid catalyst |
| RU2438775C1 (ru) * | 2010-04-30 | 2012-01-10 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор, способ его приготовления и способ получения этилена |
| AU2011269098B2 (en) | 2010-06-23 | 2014-08-21 | Total Research & Technology Feluy | Dehydration of alcohols on poisoned acidic catalysts |
| US9968914B2 (en) | 2012-12-26 | 2018-05-15 | Kao Corporation | Method for producing olefin |
| CA2933331C (en) | 2013-12-13 | 2022-01-18 | Dow Global Technologies Llc | Alkanol to alkylene conversion using at least two different catalysts in sequential order |
| RU2609263C1 (ru) * | 2015-09-03 | 2017-01-31 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Катализатор процесса дегидратации этанола в этилен, способ его приготовления и способ получения этилена |
| BR112020004403B1 (pt) | 2017-09-12 | 2023-05-16 | Kao Corporation | Método para produção de olefina |
| US11260367B2 (en) | 2018-12-12 | 2022-03-01 | Instituto Nacional De Tecnologia | Catalytic system and process for the production of light olefins from ethanol |
| BR112022004989A2 (pt) | 2019-09-30 | 2022-06-21 | Gevo Inc | Simultâneas desidratação, dimerização, e metátese de álcoois c2-c5 |
| BR112023021526A2 (pt) | 2021-04-23 | 2023-12-19 | Gevo Inc | Sistemas e processos para conversão catalítica de álcoois c1-c5 em misturas de olefinas c2-c5 |
| WO2024091452A1 (en) | 2022-10-27 | 2024-05-02 | Gevo, Inc. | Processes for catalytic conversion of c1-c5 alcohols to c2-c5 olefin mixtures |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1913938A (en) * | 1929-06-11 | 1933-06-13 | Air Reduction | Catalytic material and method of producing same |
| US2204157A (en) * | 1938-08-16 | 1940-06-11 | Goodrich Co B F | Catalyst and method of producing the same |
| FR2087011A5 (cg-RX-API-DMAC10.html) * | 1970-04-16 | 1971-12-31 | Raffinage Cie Francaise |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA457938A (en) * | 1949-07-05 | Shell Development Company | Process for producing monoolefins | |
| GB586494A (en) * | 1944-10-27 | 1947-03-20 | Frederick Joseph Leigh Bentley | Improvements in or relating to alumina catalysts |
| BE498292A (cg-RX-API-DMAC10.html) * | 1949-09-23 | |||
| DE1142343B (de) * | 1958-01-29 | 1963-01-17 | Pechiney Prod Chimiques Sa | Verfahren zur Herstellung von aus aktiver Tonerde bestehenden Dehydratisierungskatalysatoren aus dem beim Bayerverfahren anfallenden rohen Tonerdealphatrihydrat |
| US3249557A (en) * | 1962-06-25 | 1966-05-03 | Socony Mobil Oil Co Inc | Process for producing an alumina catalyst base |
| US3637406A (en) * | 1970-12-23 | 1972-01-25 | American Lava Corp | Ultrapure alumina ceramics formed by coprecipitation |
| US4207424A (en) * | 1978-08-09 | 1980-06-10 | Halcon Research & Development Corporation | Catalytic process for dehydration of alcohols |
-
1979
- 1979-05-31 JP JP54068362A patent/JPS5940057B2/ja not_active Expired
-
1980
- 1980-04-23 US US06/142,910 patent/US4302357A/en not_active Expired - Lifetime
- 1980-05-01 GB GB8014552A patent/GB2049645B/en not_active Expired
- 1980-05-02 IN IN505/CAL/80A patent/IN153076B/en unknown
- 1980-05-07 DE DE3050706A patent/DE3050706C2/de not_active Expired
- 1980-05-07 DE DE3017501A patent/DE3017501C2/de not_active Expired
- 1980-05-29 BR BR8003367A patent/BR8003367A/pt not_active IP Right Cessation
- 1980-05-30 FR FR8012052A patent/FR2457848A1/fr active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1913938A (en) * | 1929-06-11 | 1933-06-13 | Air Reduction | Catalytic material and method of producing same |
| US2204157A (en) * | 1938-08-16 | 1940-06-11 | Goodrich Co B F | Catalyst and method of producing the same |
| FR2087011A5 (cg-RX-API-DMAC10.html) * | 1970-04-16 | 1971-12-31 | Raffinage Cie Francaise |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5940057B2 (ja) | 1984-09-27 |
| DE3050706C2 (de) | 1987-02-05 |
| US4302357A (en) | 1981-11-24 |
| BR8003367A (pt) | 1980-12-30 |
| GB2049645B (en) | 1983-05-25 |
| IN153076B (cg-RX-API-DMAC10.html) | 1984-05-26 |
| GB2049645A (en) | 1980-12-31 |
| DE3017501A1 (de) | 1980-12-18 |
| DE3017501C2 (de) | 1985-03-28 |
| FR2457848B1 (cg-RX-API-DMAC10.html) | 1983-01-21 |
| JPS55159840A (en) | 1980-12-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |