FR2451907A1 - Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine - Google Patents

Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine

Info

Publication number
FR2451907A1
FR2451907A1 FR8006172A FR8006172A FR2451907A1 FR 2451907 A1 FR2451907 A1 FR 2451907A1 FR 8006172 A FR8006172 A FR 8006172A FR 8006172 A FR8006172 A FR 8006172A FR 2451907 A1 FR2451907 A1 FR 2451907A1
Authority
FR
France
Prior art keywords
methacrolein
elements
methacrylic acid
oxygen
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8006172A
Other languages
English (en)
Other versions
FR2451907B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Publication of FR2451907A1 publication Critical patent/FR2451907A1/fr
Application granted granted Critical
Publication of FR2451907B1 publication Critical patent/FR2451907B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

POUR PRODUIRE DE L'ACIDE METHACRYLIQUE, ON OXYDE EN PHASE VAPEUR DE LA METHACROLEINE AVEC DE L'OXYGENE POLECULAIRE OU UN GAZ CONTENANT DE L'OXYGENE MOLECULAIRE EN PRESENCE D'ISOBUTYLENE ETOU D'ALCOOL TERT-BUTYLIQUE ET EN PRESENCE D'UN CATALYSEUR REPRESENTE PAR LA FORMULE GENERALE:MOVPXYOOU MO, V, P ET O REPRESENTENT RESPECTIVEMENT LE MOLYBDENE, LE VANADIUM, LE PHOSPHORE ET L'OXYGENE, X REPRESENTE UN OU PLUSIEURS ELEMENTS CHOISIS PARMI LE CUIVRE, L'ETAIN, LE THORIUM, LE GERMANIUM, LE NICKEL, LE FER, LE COBALT, LE ZINC, LE TITANE, LE PLOMB, LE RHENIUM, LE ZIRCONIUM, LE CERIUM, LE BISMUTH ET L'ARSENIC, Y REPRESENTE UN OU PLUSIEURS ELEMENTS CHOISIS PARMI LE POTASSIUM, LE RUBIDIUM, LE CESIUM ET LE THALLIUM ET A, B, C, D, E ET F REPRESENTENT LE RAPPORT ATOMIQUE DES ELEMENTS OU A EST EGAL A 10, B EST UN NOMBRE EGAL OU INFERIEUR A 6 A L'EXCLUSION DE ZERO, C EST UN NOMBRE DE 0,5 A 6, D EST UN NOMBRE EGAL OU INFERIEUR A 3 A L'EXCLUSION DE ZERO, E EST UN NOMBRE DE 0 A 3 ET F EST UN NOMBRE DETERMINE SELON LA VALENCE ET LE RAPPORT ATOMIQUE DES AUTRES ELEMENTS.
FR8006172A 1979-03-22 1980-03-19 Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine Expired FR2451907B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3232379A JPS55124734A (en) 1979-03-22 1979-03-22 Preparation of methacrylic acid

Publications (2)

Publication Number Publication Date
FR2451907A1 true FR2451907A1 (fr) 1980-10-17
FR2451907B1 FR2451907B1 (fr) 1986-10-24

Family

ID=12355725

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8006172A Expired FR2451907B1 (fr) 1979-03-22 1980-03-19 Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine

Country Status (11)

Country Link
US (1) US4652673A (fr)
JP (1) JPS55124734A (fr)
BE (1) BE882303A (fr)
CS (1) CS215020B2 (fr)
DE (1) DE3010434A1 (fr)
ES (1) ES490544A0 (fr)
FR (1) FR2451907B1 (fr)
GB (1) GB2046252B (fr)
IT (1) IT1195265B (fr)
NL (1) NL8001507A (fr)
SU (1) SU1246889A3 (fr)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4301031A (en) * 1980-08-05 1981-11-17 The Standard Oil Company Methacrolein oxidation catalysts
EP0058046B1 (fr) * 1981-02-05 1984-08-01 Ube Industries, Ltd. Procédé pour la préparation de l'aldéhyde méthacrylique et de l'acide méthacrylique
DE3208572A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
DE3208571A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
CA1199905A (fr) * 1982-06-07 1986-01-28 William J. Kennelly Agents de catalyse, et leur emploi pour la preparation d'acides carboxyliques insatures
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3308625A1 (de) * 1983-03-11 1984-09-13 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
DE3508649A1 (de) * 1985-03-12 1986-09-18 Röhm GmbH, 6100 Darmstadt Heteropolysaeure h(pfeil abwaerts)8(pfeil abwaerts)pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)9(pfeil abwaerts), deren anhydrid pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)und ihre verwendung
JPH0791212B2 (ja) * 1988-07-11 1995-10-04 三菱レイヨン株式会社 メタクリル酸の製造法
DE3844087A1 (de) * 1988-12-28 1990-07-05 Basf Ag Verfahren zur herstellung von methacrylsaeure durch oxidation von methacrolein
EP0415347B2 (fr) * 1989-08-29 2002-06-05 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalyseur pour la fabrication de l'acide méthacrylique
DE4113423A1 (de) * 1991-04-25 1992-10-29 Roehm Gmbh Mit makroporen durchsetzter oxidationskatalysator
DE4240085A1 (de) * 1992-11-28 1994-06-01 Roehm Gmbh Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein
TWI341219B (en) * 2003-02-20 2011-05-01 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
EP1629889B1 (fr) * 2003-05-30 2012-05-02 Nippon Kayaku Kabushiki Kaisha Procede de production d'un catalyseur pour la production d'acide methacrylique
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
KR100807972B1 (ko) * 2005-08-10 2008-02-28 주식회사 엘지화학 아크릴산 선택성이 높은 복합 금속 산화물 촉매
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
EP1995232B1 (fr) * 2007-05-25 2018-01-03 Evonik Röhm GmbH Utilisation de compositions d'alimentation pour la préparation d'acide méthacrylique par oxydation
EP2085376B1 (fr) 2008-01-30 2012-09-05 Evonik Röhm GmbH Procédé pour la préparation d'acide méthacrylique de grande pureté
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP5892826B2 (ja) * 2012-03-27 2016-03-23 住友化学株式会社 メタクリル酸の製造方法
WO2013163806A1 (fr) 2012-05-03 2013-11-07 Evonik Industries Ag Procédé de préparation d'acide méthacrylique de haute pureté, qui ne jaunit pas
JP2016516732A (ja) 2013-03-18 2016-06-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ メタクリル酸及びメタクリル酸エステルの製造方法
JP6078387B2 (ja) * 2013-03-19 2017-02-08 住友化学株式会社 メタクリル酸の製造方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2248261A1 (fr) * 1973-10-23 1975-05-16 Union Carbide Corp
FR2256141A1 (fr) * 1973-12-29 1975-07-25 Nippon Catalytic Chem Ind
FR2275436A1 (fr) * 1974-05-31 1976-01-16 Mitsubishi Rayon Co Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique
FR2306188A1 (fr) * 1975-04-03 1976-10-29 Mitsubishi Rayon Co Procede de preparation d'un acide carboxylique insature
DE2704991A1 (de) * 1976-02-09 1977-08-11 Toyo Soda Mfg Co Ltd Verfahren zur herstellung von methacrylsaeure
GB1498595A (en) * 1975-05-23 1978-01-18 Toyo Soda Mfg Co Ltd Process for producing methacrylic acid and catalyst therefor
FR2369238A1 (fr) * 1976-10-26 1978-05-26 Nippon Zeon Co Procede de preparation de l'acide methacrylique
FR2407022A1 (fr) * 1977-10-31 1979-05-25 Nippon Kayaku Kk Procede et catalyseur pour produire de l'acide methacrylique
GB2016294A (en) * 1978-01-17 1979-09-26 Nippon Zeon Co Catalyst for use in the oxidation of unsaturated aldehydes
EP0006248A1 (fr) * 1978-06-21 1980-01-09 Nippon Kayaku Kabushiki Kaisha Procédé de préparation de l'acide méthacrylique et catalyseur

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5331615A (en) * 1976-09-06 1978-03-25 Nippon Kayaku Co Ltd Production of methacrylic acid and catalyst used thereof
JPS6048496B2 (ja) * 1977-07-22 1985-10-28 東ソー株式会社 メタクリル酸の製造方法
JPS5811416B2 (ja) * 1978-12-13 1983-03-02 日本化薬株式会社 メタクリル酸の製造法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2248261A1 (fr) * 1973-10-23 1975-05-16 Union Carbide Corp
FR2256141A1 (fr) * 1973-12-29 1975-07-25 Nippon Catalytic Chem Ind
FR2275436A1 (fr) * 1974-05-31 1976-01-16 Mitsubishi Rayon Co Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique
FR2306188A1 (fr) * 1975-04-03 1976-10-29 Mitsubishi Rayon Co Procede de preparation d'un acide carboxylique insature
GB1498595A (en) * 1975-05-23 1978-01-18 Toyo Soda Mfg Co Ltd Process for producing methacrylic acid and catalyst therefor
DE2704991A1 (de) * 1976-02-09 1977-08-11 Toyo Soda Mfg Co Ltd Verfahren zur herstellung von methacrylsaeure
FR2369238A1 (fr) * 1976-10-26 1978-05-26 Nippon Zeon Co Procede de preparation de l'acide methacrylique
FR2407022A1 (fr) * 1977-10-31 1979-05-25 Nippon Kayaku Kk Procede et catalyseur pour produire de l'acide methacrylique
GB2016294A (en) * 1978-01-17 1979-09-26 Nippon Zeon Co Catalyst for use in the oxidation of unsaturated aldehydes
EP0006248A1 (fr) * 1978-06-21 1980-01-09 Nippon Kayaku Kabushiki Kaisha Procédé de préparation de l'acide méthacrylique et catalyseur

Also Published As

Publication number Publication date
GB2046252A (en) 1980-11-12
ES8103014A1 (es) 1981-02-16
IT1195265B (it) 1988-10-12
GB2046252B (en) 1983-05-11
IT8020829A0 (it) 1980-03-21
ES490544A0 (es) 1981-02-16
NL8001507A (nl) 1980-09-24
DE3010434A1 (de) 1980-11-20
CS215020B2 (en) 1982-06-25
US4652673A (en) 1987-03-24
FR2451907B1 (fr) 1986-10-24
SU1246889A3 (ru) 1986-07-23
JPS55124734A (en) 1980-09-26
BE882303A (fr) 1980-09-19

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