FR2375175A1 - Procede de preparation de dimethyl ether a partir d'oxyde de carbone, d'hydrogene et eventuellement d'anhydride carbonique et catalyseur utile a cet effet - Google Patents

Procede de preparation de dimethyl ether a partir d'oxyde de carbone, d'hydrogene et eventuellement d'anhydride carbonique et catalyseur utile a cet effet

Info

Publication number
FR2375175A1
FR2375175A1 FR7738886A FR7738886A FR2375175A1 FR 2375175 A1 FR2375175 A1 FR 2375175A1 FR 7738886 A FR7738886 A FR 7738886A FR 7738886 A FR7738886 A FR 7738886A FR 2375175 A1 FR2375175 A1 FR 2375175A1
Authority
FR
France
Prior art keywords
carbon
hydrogen
dimethyl ether
anhydride
catalyst useful
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7738886A
Other languages
English (en)
Other versions
FR2375175B1 (fr
Inventor
Giovanni Manara
Bruno Notari
Vittorio Fattore
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of FR2375175A1 publication Critical patent/FR2375175A1/fr
Application granted granted Critical
Publication of FR2375175B1 publication Critical patent/FR2375175B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/506—Method of making inorganic composition utilizing organic compound, except formic, acetic, or oxalic acid or salt thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procédé de production de diméthyl éther par réaction catalytique entre l'oxyde de carbone et l'hydrogene, dans lequel on utilise un système de catalyseur amélioré. Le catalyseur amélioré est composé d'un mélange d'oxydes et/ou de sels de métaux tels que Al, Cr, La, Mn, Cu, Zn et leurs mélanges, qui ont été soumis à un traitement de stabilisation avec un dérivé du silicium contenant des substituants de nature diverse tels que des radicaux hydrocarbonés et des halogènes.
FR7738886A 1976-12-23 1977-12-22 Procede de preparation de dimethyl ether a partir d'oxyde de carbone, d'hydrogene et eventuellement d'anhydride carbonique et catalyseur utile a cet effet Granted FR2375175A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT30800/76A IT1065295B (it) 1976-12-23 1976-12-23 Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo

Publications (2)

Publication Number Publication Date
FR2375175A1 true FR2375175A1 (fr) 1978-07-21
FR2375175B1 FR2375175B1 (fr) 1980-06-06

Family

ID=11232134

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7738886A Granted FR2375175A1 (fr) 1976-12-23 1977-12-22 Procede de preparation de dimethyl ether a partir d'oxyde de carbone, d'hydrogene et eventuellement d'anhydride carbonique et catalyseur utile a cet effet

Country Status (37)

Country Link
US (1) US4177167A (fr)
JP (1) JPS5379811A (fr)
AR (1) AR227123A1 (fr)
AT (1) AT360498B (fr)
AU (1) AU517513B2 (fr)
BE (1) BE862289A (fr)
BR (1) BR7708470A (fr)
CA (1) CA1119147A (fr)
CH (1) CH629682A5 (fr)
CS (1) CS219336B2 (fr)
DD (1) DD133662A5 (fr)
DE (1) DE2757788C3 (fr)
DK (1) DK572277A (fr)
EG (1) EG14145A (fr)
ES (1) ES466012A1 (fr)
FR (1) FR2375175A1 (fr)
GB (2) GB1587630A (fr)
GR (1) GR63609B (fr)
HU (1) HU178729B (fr)
IE (1) IE45952B1 (fr)
IL (1) IL53564A (fr)
IT (1) IT1065295B (fr)
LU (1) LU78753A1 (fr)
MW (1) MW2977A1 (fr)
MX (1) MX147734A (fr)
NL (1) NL7714215A (fr)
NO (1) NO146861C (fr)
PH (1) PH13798A (fr)
PL (2) PL110957B1 (fr)
PT (1) PT67435B (fr)
RO (1) RO81244B (fr)
SE (1) SE427269B (fr)
SU (1) SU913935A3 (fr)
TR (1) TR19408A (fr)
YU (1) YU39229B (fr)
ZA (1) ZA777209B (fr)
ZM (1) ZM9377A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2499553A1 (fr) * 1981-02-06 1982-08-13 Mitsubishi Gas Chemical Co Procede de preparation du methanol a l'aide d'un catalyseur particulier
EP0365181A1 (fr) * 1988-10-18 1990-04-25 The British Petroleum Company p.l.c. Procédé chimique et catalyseur à cet effet

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
US4375424A (en) * 1981-10-21 1983-03-01 Shell Oil Company Catalyst for the preparation of dimethyl ether
US4507401A (en) * 1983-04-01 1985-03-26 At&T Bell Laboratories Intermetallic catalyst preparation
US4521540A (en) * 1984-03-22 1985-06-04 Air Products And Chemicals, Inc. Process for producing dimethyl ether form synthesis gas
US4590176A (en) * 1984-06-05 1986-05-20 Shell Oil Company Catalyst for dimethyl ether synthesis and a process for its preparation
US4885405A (en) * 1987-12-10 1989-12-05 Horst Dornhagen Process for the production of pure dimethylether and a catalyst used in the process
ES2053615T3 (es) * 1988-05-04 1994-08-01 Rwe Dea Ag Procedimiento mejorado para la preparacion de di-metil-eter puro.
US5106810A (en) * 1989-06-29 1992-04-21 E. I. Du Pont De Nemours And Company Methanol dissociation catalysts
DE3938835A1 (de) * 1989-11-23 1991-05-29 Sued Chemie Ag Verfahren zur oxidation von organischen verunreinigungen in abwaessern
US5831116A (en) * 1996-12-18 1998-11-03 Northeastern University Catalytic process for making ethers, aldehydes esters and acids from alcohols using a supercritical fluid mobile
US5753716A (en) * 1997-02-21 1998-05-19 Air Products And Chemicals, Inc. Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process
JP3232326B2 (ja) * 1997-03-11 2001-11-26 経済産業省産業技術総合研究所長 銅系触媒およびその製造法
DK173614B1 (da) 1999-02-02 2001-04-30 Topsoe Haldor As Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas
KR100812099B1 (ko) * 2006-11-28 2008-03-12 한국가스공사 디메틸에테르 제조용 혼합촉매, 이의 제조방법 및 이를 이용한 디메틸에테르 제조방법
FR2909666B1 (fr) * 2006-12-08 2009-03-06 Centre Nat Rech Scient Deshydratation du methanol en dimethyl ether employant des catalyseurs a base d'une zeolithe supportee sur du carbure de silicium
US8961829B2 (en) * 2007-04-27 2015-02-24 Saudi Basic Industries Corporation Catalytic hyrogenation of carbon dioxide into syngas mixture
EP2072491A1 (fr) 2007-12-17 2009-06-24 BP p.l.c. Processus de conversion d'alcool(s) en alcool(s) avec une chaîne de carbone prolongée
EP2072492A1 (fr) 2007-12-17 2009-06-24 BP p.l.c. Processus de conversion d'hydrocarbure en éthanol
EP2072486A1 (fr) 2007-12-17 2009-06-24 BP p.l.c. Processus de conversion d'hydrocarbures en éthanol
BR112020024003B1 (pt) 2018-06-29 2023-12-12 Dow Global Technologies Llc Catalisador híbrido e processo para preparar olefinas c2 a c3
WO2020005701A1 (fr) * 2018-06-29 2020-01-02 Dow Global Technologies Llc Catalyseurs hybrides comprenant une zéolite et un composant d'oxyde métallique mixte pour convertir un gaz de synthèse en oléfines c2 et c3
CN111250098B (zh) * 2020-03-11 2023-03-31 上海兖矿能源科技研发有限公司 一种用于费托合成反应水加氢催化剂及其制备方法和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2852473A (en) * 1955-06-08 1958-09-16 Grace W R & Co Method of preparing alumina and hydroforming catalyst thereon
US3502595A (en) * 1965-10-28 1970-03-24 Sinclair Research Inc Preparation of silica-alumina,titania-alumina,and phosphorous oxide-alumina catalysts
US3770618A (en) * 1967-06-26 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization of residua
US3840477A (en) * 1972-08-03 1974-10-08 Nalco Chemical Co Hydrotreating catalyst
US3944503A (en) * 1972-12-22 1976-03-16 Exxon Research & Engineering Co. Catalyst for conversion of heavy hydrocarbon oils
US3941819A (en) * 1973-12-14 1976-03-02 Exxon Research And Engineering Company Catalytic formation of hydrocarbons from CO hydrogen mixtures

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2499553A1 (fr) * 1981-02-06 1982-08-13 Mitsubishi Gas Chemical Co Procede de preparation du methanol a l'aide d'un catalyseur particulier
EP0365181A1 (fr) * 1988-10-18 1990-04-25 The British Petroleum Company p.l.c. Procédé chimique et catalyseur à cet effet
US5051390A (en) * 1988-10-18 1991-09-24 The British Petroleum Company, P.L.C. Chemical process and catalyst to be used therein

Also Published As

Publication number Publication date
ZM9377A1 (en) 1979-11-21
RO81244B (ro) 1983-02-28
PT67435B (en) 1979-05-23
CH629682A5 (it) 1982-05-14
GB1587630A (en) 1981-04-08
TR19408A (tr) 1979-03-01
IE45952L (en) 1978-06-23
AR227123A1 (es) 1982-09-30
DE2757788C3 (de) 1980-02-14
FR2375175B1 (fr) 1980-06-06
ES466012A1 (es) 1978-10-01
DE2757788B2 (de) 1979-06-21
ATA923177A (de) 1980-06-15
JPS6143332B2 (fr) 1986-09-26
PL110957B1 (en) 1980-08-30
ZA777209B (en) 1978-10-25
GB1587629A (en) 1981-04-08
PH13798A (en) 1980-10-01
BE862289A (fr) 1978-06-23
IT1065295B (it) 1985-02-25
DE2757788A1 (de) 1978-06-29
SE427269B (sv) 1983-03-21
YU306977A (en) 1982-10-31
CS219336B2 (en) 1983-03-25
US4177167A (en) 1979-12-04
IL53564A (en) 1982-07-30
PL110505B1 (en) 1980-07-31
SU913935A3 (en) 1982-03-15
DD133662A5 (de) 1979-01-17
DK572277A (da) 1978-06-24
IL53564A0 (en) 1978-03-10
BR7708470A (pt) 1978-08-08
MX147734A (es) 1983-01-10
JPS5379811A (en) 1978-07-14
AU517513B2 (en) 1981-08-06
YU39229B (en) 1984-08-31
NO146861C (no) 1982-12-22
AT360498B (de) 1981-01-12
NO146861B (no) 1982-09-13
CA1119147A (fr) 1982-03-02
HU178729B (en) 1982-06-28
RO81244A (fr) 1983-02-15
NO774404L (no) 1978-06-26
NL7714215A (nl) 1978-06-27
PL203247A1 (pl) 1978-07-31
GR63609B (en) 1979-11-26
LU78753A1 (fr) 1978-04-17
PT67435A (en) 1978-01-01
EG14145A (en) 1983-09-30
IE45952B1 (en) 1983-01-12
MW2977A1 (en) 1978-08-09
AU3120177A (en) 1979-06-14

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