FR2360541A1 - Procede de telomerisation ou d'oligomerisation de diolefines conjuguees acycliques - Google Patents

Procede de telomerisation ou d'oligomerisation de diolefines conjuguees acycliques

Info

Publication number
FR2360541A1
FR2360541A1 FR7722572A FR7722572A FR2360541A1 FR 2360541 A1 FR2360541 A1 FR 2360541A1 FR 7722572 A FR7722572 A FR 7722572A FR 7722572 A FR7722572 A FR 7722572A FR 2360541 A1 FR2360541 A1 FR 2360541A1
Authority
FR
France
Prior art keywords
telomerization
oligomerization
triphenylphosphine
acyclic
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7722572A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of FR2360541A1 publication Critical patent/FR2360541A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/38—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes
    • C07C2/40—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes of conjugated dienes
    • C07C2/403—Catalytic processes
    • C07C2/406—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

L'invention est relative à un procédé de télomérisation ou d'oligomérisation de dioléfines acycliques contenant de 4 à 6 atomes de carbone. Selon le procédé, par mole de tétrakis-triphénylphosphine palladium, on élimine par oxydation de 1 à 3,5 moles de triphénylphosphine, on utilise le complexe de palladium activé ainsi obtenu dans la télomérisation ou l'oligomérisation, après la fin de la télomérisation ou de l'oligomérisation, on ajoute de la triphénylphosphine à raison de 2 à 6 moles, on traite le mélange par distillation et on récupère le tétrakis-triphénylphosphine-palladium introduit primitivement. Le procédé permet la récupération des coûteux catalyseurs au palladium.
FR7722572A 1976-08-05 1977-07-22 Procede de telomerisation ou d'oligomerisation de diolefines conjuguees acycliques Withdrawn FR2360541A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2635250A DE2635250C3 (de) 1976-08-05 1976-08-05 Verfahren zur Telomerisation bzw. Oligomerisation von acyclischen konjugierten Diolefinen

Publications (1)

Publication Number Publication Date
FR2360541A1 true FR2360541A1 (fr) 1978-03-03

Family

ID=5984801

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7722572A Withdrawn FR2360541A1 (fr) 1976-08-05 1977-07-22 Procede de telomerisation ou d'oligomerisation de diolefines conjuguees acycliques

Country Status (9)

Country Link
US (1) US4146738A (fr)
JP (1) JPS5318689A (fr)
AT (1) ATA573377A (fr)
BE (1) BE857562A (fr)
DE (1) DE2635250C3 (fr)
FI (1) FI772356A (fr)
FR (1) FR2360541A1 (fr)
NL (1) NL7708651A (fr)
SE (1) SE7708817L (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254782A (en) * 1989-12-29 1993-10-19 The Dow Chemical Company Continuous process for the telomerization of conjugated dienes
IT1240737B (it) * 1990-04-02 1993-12-17 Snam Progetti Sistema catalitico e procedimento per la produzione selettiva di isoprenil-alchileteri da isoprene
US5236909A (en) * 1990-07-25 1993-08-17 Henkel Research Corporation Octyl ethers and octadienyl ethers
US5206396A (en) * 1990-07-25 1993-04-27 Henkel Research Corporation Telomerization of 1,3-butadiene
US5198598A (en) * 1991-07-19 1993-03-30 Henkel Kommanditgesellschaft Auf Aktien Telomerization process of a conjugated alkadiene with a polyol
US5169981A (en) * 1991-12-06 1992-12-08 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5243099A (en) * 1991-12-06 1993-09-07 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
DE102005036040A1 (de) 2004-08-28 2006-03-02 Oxeno Olefinchemie Gmbh Verfahren zur Telomerisation von nicht cyclischen Olefinen
CN112473748B (zh) * 2020-12-24 2021-09-17 北京交通大学 一种可控氧化的四三苯基膦钯催化剂及其制备方法和用途

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3530187A (en) * 1967-12-26 1970-09-22 Shell Oil Co Preparation of n-(alkadienyl)amines
GB1248593A (en) * 1968-11-06 1971-10-06 British Petroleum Co Preparation of alkoxy octadienes
US3670032A (en) * 1969-03-19 1972-06-13 Exxon Research Engineering Co Preparation of unsaturated alcohols and ethers
US3992456A (en) * 1969-04-16 1976-11-16 Union Carbide Corporation Synthesis of alkadienols
GB1354507A (en) * 1970-09-29 1974-06-05 Ici Ltd Process for the production of ethers or alcohols
US3691249A (en) * 1970-10-07 1972-09-12 Universal Oil Prod Co Dimerization of diolefinic compounds
US3925497A (en) * 1970-10-09 1975-12-09 Du Pont Substituted 1,3,7-octatrienes and their preparation
US4021383A (en) * 1975-12-22 1977-05-03 Texaco Development Corporation Infused polymer containing monohydric compounds and polyurethane compositions based thereon

Also Published As

Publication number Publication date
DE2635250B2 (de) 1979-01-11
US4146738A (en) 1979-03-27
JPS5318689A (en) 1978-02-21
ATA573377A (de) 1979-07-15
DE2635250C3 (de) 1979-09-13
BE857562A (fr) 1978-02-06
SE7708817L (sv) 1978-02-06
NL7708651A (nl) 1978-02-07
FI772356A (fr) 1978-02-06
DE2635250A1 (de) 1978-02-09

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