FR2365590A1 - Catalyseur de polymerisation d'ethylene et son procede de preparation - Google Patents

Catalyseur de polymerisation d'ethylene et son procede de preparation

Info

Publication number
FR2365590A1
FR2365590A1 FR7728407A FR7728407A FR2365590A1 FR 2365590 A1 FR2365590 A1 FR 2365590A1 FR 7728407 A FR7728407 A FR 7728407A FR 7728407 A FR7728407 A FR 7728407A FR 2365590 A1 FR2365590 A1 FR 2365590A1
Authority
FR
France
Prior art keywords
polymerization catalyst
ethylene polymerization
preparation process
relates
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7728407A
Other languages
English (en)
Other versions
FR2365590B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of FR2365590A1 publication Critical patent/FR2365590A1/fr
Application granted granted Critical
Publication of FR2365590B1 publication Critical patent/FR2365590B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne les catalyseurs à base de chrome Elle se rapporte à un catalyseur formé par séchage de silice par exemple, par mise en suspension de la silice dans un hydrocarbure liquide anhydre, par mélange de la suspension avec une solution d'un compose de chromocène et d'un composé du titane, par retrait de l'hydrocarbure, par l'addition au résidu d'un agent éventuel de fluoration, et par chauffage du produit obtenu entre 300 et 1 000 degrés C afin qu'il soit activé. Application à la préparation de catalyseur de polymérisation de l'éthylène.
FR7728407A 1976-09-22 1977-09-21 Catalyseur de polymerisation d'ethylene et son procede de preparation Granted FR2365590A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/725,542 US4101445A (en) 1976-09-22 1976-09-22 Preparation of modified and activated chromocene catalysts for ethylene polymerization

Publications (2)

Publication Number Publication Date
FR2365590A1 true FR2365590A1 (fr) 1978-04-21
FR2365590B1 FR2365590B1 (fr) 1984-06-22

Family

ID=24914969

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7728407A Granted FR2365590A1 (fr) 1976-09-22 1977-09-21 Catalyseur de polymerisation d'ethylene et son procede de preparation

Country Status (27)

Country Link
US (1) US4101445A (fr)
JP (1) JPS5339992A (fr)
AR (1) AR222295A1 (fr)
AU (1) AU519542B2 (fr)
BE (1) BE858910A (fr)
BR (1) BR7706288A (fr)
CA (1) CA1098106A (fr)
CS (2) CS221952B2 (fr)
DE (1) DE2742543C2 (fr)
DK (1) DK149205C (fr)
EG (1) EG13094A (fr)
ES (2) ES462508A1 (fr)
FI (1) FI63246C (fr)
FR (1) FR2365590A1 (fr)
GB (1) GB1574877A (fr)
HK (1) HK38981A (fr)
IN (1) IN147225B (fr)
IT (1) IT1085044B (fr)
MX (1) MX4472E (fr)
MY (1) MY8200080A (fr)
NL (1) NL174723C (fr)
NO (2) NO145680C (fr)
NZ (1) NZ185222A (fr)
PH (1) PH13455A (fr)
RO (1) RO73241A (fr)
SE (2) SE438314B (fr)
ZA (1) ZA775232B (fr)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
EP0166157A2 (fr) * 1984-05-29 1986-01-02 Phillips Petroleum Company Oxyde d'aluminium silicaté et/ou fluoré

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US4690990A (en) * 1982-03-30 1987-09-01 Phillips Petroleum Company Polymerization process using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4803253A (en) * 1982-03-30 1989-02-07 Phillips Petroleum Company Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4424139A (en) 1982-03-30 1984-01-03 Phillips Petroleum Company Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4522987A (en) * 1982-07-09 1985-06-11 Phillips Petroleum Company Low density polyethylene
DE3609828A1 (de) * 1986-03-22 1987-09-24 Basf Ag Verfahren zum herstellen von homo-sowie copolymerisaten des ethens durch phillips-katalyse
DE3618259A1 (de) * 1986-05-30 1987-12-03 Basf Ag Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse
US5064796A (en) * 1991-01-07 1991-11-12 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
US5211746A (en) * 1992-06-22 1993-05-18 Union Carbide Chemicals & Plastics Technology Corporation Flame retardant compositions
US5401816A (en) * 1993-09-27 1995-03-28 Phillips Petroleum Company Transition metal catalyst, method of preparing catalyst, polymerization process employing catalyst, and polymer produced
MX9602866A (es) 1995-07-21 1997-06-28 Union Carbide Chem Plastic Proceso para la extrusion de polietileno.
US5925448A (en) 1995-11-07 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Film extruded from a blend of ethylene copolymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
BR9910611B1 (pt) * 1998-05-18 2009-05-05 processo para produção de uma composição de catalisador.
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
ES2197649T3 (es) 1998-08-26 2004-01-01 Exxonmobil Chemical Patents Inc. Composiciones cataliticas soportadas altamente activas.
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6388051B1 (en) 2000-12-20 2002-05-14 Union Carbide Chemicals & Plastics Technology Corporation Process for selecting a polyethylene having improved processability
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US20060142458A1 (en) 2003-06-09 2006-06-29 Pang Kawai P Strippable semi-conductive insulation shield
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US7629422B2 (en) 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
US7053163B1 (en) 2005-02-22 2006-05-30 Fina Technology, Inc. Controlled comonomer distribution along a reactor for copolymer production
EP2218752B1 (fr) * 2006-04-07 2013-06-12 Dow Global Technologies LLC Compositions de polyoléfines et articles réalisés à partir des ces compositions
US7446167B2 (en) * 2006-04-13 2008-11-04 Fina Technology, Inc. Catalyst deactivation agents and methods for use of same
KR100718022B1 (ko) * 2006-04-25 2007-05-14 한화석유화학 주식회사 트리 내성 가교 폴리올레핀 조성물
US7863522B2 (en) * 2006-12-20 2011-01-04 Dow Global Technologies Inc. Semi-conducting polymer compositions for the preparation of wire and cable
EP2580276A1 (fr) 2010-06-10 2013-04-17 Union Carbide Chemicals & Plastics Technology LLC Mélanges d'antioxydant thiobisphénolique et de polyéthylène glycol
EP2710067B1 (fr) 2011-05-20 2019-10-02 Union Carbide Chemicals & Plastics Technology LLC Procédé pour mélanger des antioxydants thiobisphénoliques avec du polyethylène
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
EP3257892B1 (fr) 2013-09-13 2021-09-01 Dow Global Technologies LLC Compositions réticulables par peroxyde et leurs procédés de production
US9914794B2 (en) 2014-05-27 2018-03-13 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
CN107148442B (zh) 2014-11-28 2019-11-15 陶氏环球技术有限责任公司 使用氟树脂/偶氮二甲酰胺混合物作为晶核生成剂发泡聚烯烃组合物的方法
BR112017010307A2 (pt) 2014-11-28 2017-12-26 Dow Global Technologies Llc processo para formação de espuma de composições de poliolefina usando uma fluororresina como agente de nucleação
EP3237106B1 (fr) 2014-12-22 2018-09-12 SABIC Global Technologies B.V. Récupération d'hydrocarbures à partir d'un recyclage d'hydrocarbures
EA032875B1 (ru) 2014-12-22 2019-07-31 Сабик Глоубл Текнолоджиз Б.В. Способ перехода между несовместимыми катализаторами
KR20170109548A (ko) 2014-12-22 2017-09-29 사빅 글로벌 테크놀러지스 비.브이. 비융화성 촉매 간의 전환 방법
WO2016151098A1 (fr) 2015-03-24 2016-09-29 Sabic Global Technologies B.V. Procédé de transition entre des catalyseurs incompatibles
MX2017013791A (es) 2015-05-08 2018-03-01 Dow Global Technologies Llc Proceso para composiciones de poliolefina espumantes usando una mezcla de azodicarbonamida/citrato como agente nucleante.
CN108699168B (zh) 2015-12-22 2021-04-27 Sabic环球技术有限责任公司 用于不相容催化剂之间转换的方法
CN109937233B (zh) 2016-11-16 2021-11-09 陶氏环球技术有限责任公司 具有损耗因子和添加剂接受性的平衡的组合物
TWI805586B (zh) 2017-06-29 2023-06-21 美商陶氏全球科技有限責任公司 可交聯組合物、製品以及導電方法
CN113631655A (zh) 2018-06-29 2021-11-09 陶氏环球技术有限责任公司 泡沫珠和烧结泡沫结构
CN110878130B (zh) * 2018-09-06 2023-04-07 中国石油化工股份有限公司 负载型铬和茂双金属催化剂、其制备方法及其应用
WO2020056119A1 (fr) 2018-09-14 2020-03-19 Fina Technology, Inc. Mélanges de polymères de polypropylène à rhéologie contrôlée et de polyéthylène et procédés d'utilisation
KR102587649B1 (ko) 2018-09-20 2023-10-13 다우 글로벌 테크놀로지스 엘엘씨 가황 고무에 에틸렌계 중합체 폼을 부착시키기 위한 결합 방법
CA3121960A1 (fr) 2019-02-20 2020-08-27 Fina Technology, Inc. Compositions polymeres a faible gauchissement

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US2882096A (en) * 1956-09-25 1959-04-14 Lyon George Albert Wheel cover
US2879362A (en) * 1956-11-14 1959-03-24 Rauland Corp Photosensitive device
US3622521A (en) * 1967-08-21 1971-11-23 Phillips Petroleum Co Olefin polymerization with chromium and titanium-containing compounds
US3887494A (en) * 1970-11-12 1975-06-03 Phillips Petroleum Co Olefin polymerization catalyst
CA995396A (en) * 1971-03-18 1976-08-17 Robert N. Johnson Catalyst modified with strong reducing agent and silane compounds and use in polymerization of olefins
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
GB1429174A (en) * 1972-06-12 1976-03-24 Bp Chem Int Ltd Polymerisation process and catalyst
US3806500A (en) * 1972-07-21 1974-04-23 Union Carbide Corp Polymerization with thermally aged catalyst
US3950316A (en) * 1974-05-03 1976-04-13 Phillips Petroleum Company Catalyst support formed by adding acidic material to silica containing titanium

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0166157A2 (fr) * 1984-05-29 1986-01-02 Phillips Petroleum Company Oxyde d'aluminium silicaté et/ou fluoré
EP0166157A3 (en) * 1984-05-29 1988-12-28 Phillips Petroleum Company Silicon and/or fluorine treated alumina

Also Published As

Publication number Publication date
ES462508A1 (es) 1978-07-01
NO145680C (no) 1982-05-12
FR2365590B1 (fr) 1984-06-22
JPS5339992A (en) 1978-04-12
DE2742543A1 (de) 1978-03-23
PH13455A (en) 1980-04-23
NL7710349A (nl) 1978-03-28
FI63246C (fi) 1983-05-10
ES464417A1 (es) 1978-09-01
EG13094A (en) 1982-12-31
US4101445A (en) 1978-07-18
FI63246B (fi) 1983-01-31
DE2742543C2 (de) 1983-02-17
NL174723B (nl) 1984-03-01
NO153611B (no) 1986-01-13
BR7706288A (pt) 1978-06-27
NO145680B (no) 1982-02-01
NZ185222A (en) 1980-02-21
SE8300395L (sv) 1983-01-26
HK38981A (en) 1981-08-14
BE858910A (fr) 1978-03-21
AR222295A1 (es) 1981-05-15
CS221952B2 (en) 1983-04-29
CS221951B2 (en) 1983-04-29
SE445460B (sv) 1986-06-23
NO153611C (no) 1986-04-23
AU519542B2 (en) 1981-12-10
IT1085044B (it) 1985-05-28
MX4472E (es) 1982-05-18
AU2890977A (en) 1979-03-29
NO773239L (no) 1978-03-28
FI772791A (fi) 1978-03-23
MY8200080A (en) 1982-12-31
SE8300395D0 (sv) 1983-01-26
ZA775232B (en) 1978-07-26
IN147225B (fr) 1979-12-29
DK149205C (da) 1986-09-08
SE7710593L (sv) 1978-03-23
NO800836L (no) 1978-03-28
DK417277A (da) 1978-03-23
CA1098106A (fr) 1981-03-24
JPS5615807B2 (fr) 1981-04-13
NL174723C (nl) 1984-08-01
DK149205B (da) 1986-03-10
GB1574877A (en) 1980-09-10
RO73241A (fr) 1981-06-26
SE438314B (sv) 1985-04-15

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