FR2377995A1 - Procede de preparation de l'acide methacrylique, de son nitrile et de ses esters par reaction respectivement de l'acide propionique, de son nitrile et des esters avec le metrylal - Google Patents
Procede de preparation de l'acide methacrylique, de son nitrile et de ses esters par reaction respectivement de l'acide propionique, de son nitrile et des esters avec le metrylalInfo
- Publication number
- FR2377995A1 FR2377995A1 FR7739472A FR7739472A FR2377995A1 FR 2377995 A1 FR2377995 A1 FR 2377995A1 FR 7739472 A FR7739472 A FR 7739472A FR 7739472 A FR7739472 A FR 7739472A FR 2377995 A1 FR2377995 A1 FR 2377995A1
- Authority
- FR
- France
- Prior art keywords
- nitrile
- esters
- methacrylic acid
- metrylal
- propionic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procédé de préparation de l'acide méthacrylique, de son nitrile et de ses esters par réaction respectivement de l'acide propionique, de son nitrile et de ses esters avec le méthylal. On utilise comme catalyseurs dans la même opération une silice contenant un additif basique et catalyseur à base d'alumine et/ou un catalyseur contenant du bioxyde de titane. L'acide méthacrylique et ses dérivés fonctionnels ont une grosse importance industrielle, par exemple en tant que produits de départ monomères dans des polymérisations.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772702187 DE2702187A1 (de) | 1977-01-20 | 1977-01-20 | Verfahren zur herstellung von methacrylsaeure, dem nitril und estern dieser saeure |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2377995A1 true FR2377995A1 (fr) | 1978-08-18 |
Family
ID=5999098
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7739472A Withdrawn FR2377995A1 (fr) | 1977-01-20 | 1977-12-28 | Procede de preparation de l'acide methacrylique, de son nitrile et de ses esters par reaction respectivement de l'acide propionique, de son nitrile et des esters avec le metrylal |
Country Status (7)
Country | Link |
---|---|
US (1) | US4147718A (fr) |
JP (1) | JPS5390215A (fr) |
BE (1) | BE862417A (fr) |
DE (1) | DE2702187A1 (fr) |
FR (1) | FR2377995A1 (fr) |
IT (1) | IT1093042B (fr) |
NL (1) | NL7800736A (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010058119A1 (fr) | 2008-11-18 | 2010-05-27 | Arkema France | Procede de fabrication d'un methylacrylate de methyle derive de la biomasse |
US8748545B2 (en) | 2008-09-16 | 2014-06-10 | Arkema France | Process for producing bio-resourced polymer-grade acrylic acid from glycerol |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4430252A (en) | 1982-12-10 | 1984-02-07 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition by an organic solution method |
US4444904A (en) * | 1983-05-26 | 1984-04-24 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
US4490476A (en) * | 1983-06-28 | 1984-12-25 | Rohm And Haas Company | Catalyst for the preparation of α,β-unsaturated compounds |
US4801571A (en) * | 1986-07-31 | 1989-01-31 | Amoco Corporation | Catalyst and process for production of an alpha, beta-ethylenically unsaturated monocarboxylic acid |
DE102006048575A1 (de) * | 2006-10-13 | 2008-04-17 | Evonik Degussa Gmbh | Oberflächenmodifizierte Kieselsäuren |
CN104262142A (zh) * | 2014-08-25 | 2015-01-07 | 常州大学 | 一种高效制备α, β-不饱和羧酸或酯的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2457993A1 (de) * | 1974-12-07 | 1976-06-16 | Roehm Gmbh | Verfahren zur herstellung von methacrylsaeure sowie estern und dem nitril dieser saeure |
FR2347330A1 (fr) * | 1976-04-10 | 1977-11-04 | Basf Ag | Procede de preparation d'acide methacrylique et de methacrylate de methyle |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3051747A (en) * | 1958-03-27 | 1962-08-28 | Dow Chemical Co | Synthesis of acrylic acids |
US3089898A (en) * | 1961-06-29 | 1963-05-14 | Air Reduction | Preparation of methyl acrylate |
US3247248A (en) * | 1961-12-26 | 1966-04-19 | Cumberland Chemical Corp | Preparation of unsaturated monocarboxylic acids |
US3578702A (en) * | 1965-12-03 | 1971-05-11 | Eastman Kodak Co | Process for producing alpha,beta-unsaturated organic compounds |
US3440276A (en) * | 1965-12-29 | 1969-04-22 | Commercial Solvents Corp | Process for preparing acrylic esters |
GB1207416A (en) * | 1968-06-17 | 1970-09-30 | British Petroleum Co | Preparation of unsaturated esters |
US3840587A (en) * | 1972-08-03 | 1974-10-08 | Monsanto Co | Process for the condensation of formaldehyde with carboxylic acids |
US3933888A (en) * | 1972-10-06 | 1976-01-20 | Rohm And Haas Company | Production of unsaturated acids, esters and nitriles, and catalyst therefor |
DE2615887C3 (de) | 1976-04-10 | 1980-03-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Methacrylsäure und Methacrylsäuremethylester und Katalysator zur Durchführung des Verfahrens |
-
1977
- 1977-01-20 DE DE19772702187 patent/DE2702187A1/de active Pending
- 1977-12-12 IT IT69773/77A patent/IT1093042B/it active
- 1977-12-28 BE BE183921A patent/BE862417A/fr unknown
- 1977-12-28 FR FR7739472A patent/FR2377995A1/fr not_active Withdrawn
-
1978
- 1978-01-16 US US05/869,605 patent/US4147718A/en not_active Expired - Lifetime
- 1978-01-20 JP JP513078A patent/JPS5390215A/ja active Pending
- 1978-01-20 NL NL7800736A patent/NL7800736A/xx not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2457993A1 (de) * | 1974-12-07 | 1976-06-16 | Roehm Gmbh | Verfahren zur herstellung von methacrylsaeure sowie estern und dem nitril dieser saeure |
FR2347330A1 (fr) * | 1976-04-10 | 1977-11-04 | Basf Ag | Procede de preparation d'acide methacrylique et de methacrylate de methyle |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8748545B2 (en) | 2008-09-16 | 2014-06-10 | Arkema France | Process for producing bio-resourced polymer-grade acrylic acid from glycerol |
WO2010058119A1 (fr) | 2008-11-18 | 2010-05-27 | Arkema France | Procede de fabrication d'un methylacrylate de methyle derive de la biomasse |
Also Published As
Publication number | Publication date |
---|---|
NL7800736A (nl) | 1978-07-24 |
DE2702187A1 (de) | 1978-07-27 |
US4147718A (en) | 1979-04-03 |
BE862417A (fr) | 1978-04-14 |
IT1093042B (it) | 1985-07-19 |
JPS5390215A (en) | 1978-08-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Withdrawal of published application |