KR970010729A - 이소보르닐 (메트)아크릴레이트의 제조방법 - Google Patents

이소보르닐 (메트)아크릴레이트의 제조방법 Download PDF

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Publication number
KR970010729A
KR970010729A KR1019960033977A KR19960033977A KR970010729A KR 970010729 A KR970010729 A KR 970010729A KR 1019960033977 A KR1019960033977 A KR 1019960033977A KR 19960033977 A KR19960033977 A KR 19960033977A KR 970010729 A KR970010729 A KR 970010729A
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KR
South Korea
Prior art keywords
meth
acrylate
catalyst
process according
acid
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KR1019960033977A
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English (en)
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KR100217162B1 (ko
Inventor
알랭 리옹델
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미쉘 리외
엘프 아토켐 에스.에이.
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Publication of KR970010729A publication Critical patent/KR970010729A/ko
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Publication of KR100217162B1 publication Critical patent/KR100217162B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 촉매로서 고체 지르코늄-기재 과산의 존재하에 (메트)아크릴산과 캄펜의 반응으로 이루어지는 이소보르닐 (메트)아크릴레이트의 제조방법에 관한 것이다.

Description

이소보르닐 (메트)아크릴레이트의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 하기 식의 (메트)아크릴레이트의 제조방법으로,
    (식중, R은 수소 원자 또는 메틸 라디칼임) 촉매량의 산촉매의 존재하에 하기 식의 아크릴산 또는 메트아크릴산을하기 식의 캄펜
    과 반응시키는 것으로 이루어지며, 촉매로서 고체 지르코늄-기재 과산(superacid)을 사용하는 것을 특징으로 하는 이소보르닐 (메트)아크릴레이트의 제조방법.
  2. 제1항에 있어서, 촉매로서 수산화지르코늄과 황산암모늄의 반응 생성물을 사용하는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 산 대 캄펜의 몰비는 4/1 내지 1/4일 수 있고 바람직하게 2/1 내지 1/2인 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 혼합물을 촉매와 10 내지 60℃ 및 바람직하게는 30 내지 40℃의 온도에서 접촉시키는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960033977A 1995-08-18 1996-08-16 이소보르닐 (메트)아크릴레이트의 제조방법 KR100217162B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9509916A FR2737890B1 (fr) 1995-08-18 1995-08-18 Procede de preparation de (meth)acrylate d'isobornyle
FR9509916 1995-08-18

Publications (2)

Publication Number Publication Date
KR970010729A true KR970010729A (ko) 1997-03-27
KR100217162B1 KR100217162B1 (ko) 1999-09-01

Family

ID=9481993

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960033977A KR100217162B1 (ko) 1995-08-18 1996-08-16 이소보르닐 (메트)아크릴레이트의 제조방법

Country Status (10)

Country Link
US (1) US5719314A (ko)
EP (1) EP0759423A1 (ko)
JP (1) JP2818652B2 (ko)
KR (1) KR100217162B1 (ko)
CN (1) CN1151395A (ko)
CA (1) CA2183399C (ko)
CZ (1) CZ285363B6 (ko)
FR (1) FR2737890B1 (ko)
SG (1) SG77579A1 (ko)
TW (1) TW340112B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100447546B1 (ko) * 2000-12-23 2004-09-04 삼성아토피나주식회사 열가소성 엘라스토머 블렌드

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19920796A1 (de) * 1999-05-06 2000-11-09 Roehm Gmbh Verfahren zur Herstellung von Isobornylmethacrylat
JP4782996B2 (ja) * 2004-09-01 2011-09-28 大阪有機化学工業株式会社 イソボルニル（メタ）アクリレートの製造法
JP5777844B2 (ja) * 2007-12-20 2015-09-09 三菱レイヨン株式会社 イソボルニル（メタ）アクリレートの製造方法
CN101863763A (zh) * 2010-06-04 2010-10-20 南京林业大学 活性炭负载四氯化锡催化合成甲基丙烯酸异冰片酯的方法
WO2012114875A1 (ja) * 2011-02-25 2012-08-30 大阪有機化学工業株式会社 （メタ）アクリル酸ビシクロモノテルペンの製造方法
DE102011089504A1 (de) * 2011-12-22 2013-06-27 Evonik Röhm Gmbh Verfahren zur Herstellung bi- oder trizyklischer (Meth)acrylate
CN104529770A (zh) * 2014-12-16 2015-04-22 上海华谊（集团）公司 丙烯酸异冰片酯或甲基丙烯酸异冰片酯的制备方法
CN104844455B (zh) * 2015-04-13 2016-06-22 徐德良 一种催化合成丙烯酸叔丁酯的工艺
CN108409562A (zh) * 2018-01-22 2018-08-17 安徽联化新材料有限公司 一种甲基丙烯酸异冰片酯的连续生产方法
CN114805061A (zh) * 2022-05-25 2022-07-29 佛山市三水精泽化工有限公司 甲基丙烯酸异冰片酯的制备方法和甲基丙烯酸异冰片酯

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4316004A1 (de) * 1993-05-13 1994-11-17 Roehm Gmbh Verfahren zur Herstellung von Isobornyl(meth)acrylat
FR2718740B1 (fr) * 1994-04-15 1996-05-31 Atochem Elf Sa Procédé de préparation de l'acrylate de butyle secondaire.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100447546B1 (ko) * 2000-12-23 2004-09-04 삼성아토피나주식회사 열가소성 엘라스토머 블렌드

Also Published As

Publication number Publication date
SG77579A1 (en) 2001-01-16
KR100217162B1 (ko) 1999-09-01
EP0759423A1 (fr) 1997-02-26
CA2183399A1 (fr) 1997-02-19
FR2737890A1 (fr) 1997-02-21
CN1151395A (zh) 1997-06-11
US5719314A (en) 1998-02-17
CZ242696A3 (en) 1997-03-12
FR2737890B1 (fr) 1997-10-17
CZ285363B6 (cs) 1999-07-14
CA2183399C (fr) 1999-09-28
JPH0967306A (ja) 1997-03-11
TW340112B (en) 1998-09-11
JP2818652B2 (ja) 1998-10-30

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