FR2378773A1 - Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic - Google Patents
Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenicInfo
- Publication number
- FR2378773A1 FR2378773A1 FR7702747A FR7702747A FR2378773A1 FR 2378773 A1 FR2378773 A1 FR 2378773A1 FR 7702747 A FR7702747 A FR 7702747A FR 7702747 A FR7702747 A FR 7702747A FR 2378773 A1 FR2378773 A1 FR 2378773A1
- Authority
- FR
- France
- Prior art keywords
- arsenic
- olefins
- based catalysts
- hydrogen peroxide
- epoxidation process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Procédé d'époxydation des oléfines par le peroxyde d'hydrogène à une température comprise entre 0 degrés C et 120 degrés C en phase liquide, caractérisé par l'emploi d'un catalyseur à base d'arsenic, d'un excès d'oléfine par rapport au peroxyde d'hydrogène engagé, et par l'élimination de façon continue par distillation ou entraînement de l'eau introduite avec le peroxyde d'hydrogène ainsi que de l'eau formée au cours de la réaction.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7702747A FR2378773A1 (fr) | 1977-02-01 | 1977-02-01 | Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic |
BE184571A BE863239A (fr) | 1977-02-01 | 1978-01-24 | Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic |
DE2803757A DE2803757C3 (de) | 1977-02-01 | 1978-01-28 | Verfahren zur Epoxidation von Olefinen in Anwesenheit eines Katalysators auf Arsenbasis |
CH105478A CH626614A5 (en) | 1977-02-01 | 1978-01-31 | Process for the epoxidation of olefins in the presence of arsenic-based catalysts |
GB3890/78A GB1585011A (en) | 1977-02-01 | 1978-01-31 | Process for the epoxidation of olefins |
CA296,111A CA1095066A (fr) | 1977-02-01 | 1978-01-31 | Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic |
ES466516A ES466516A0 (es) | 1977-02-01 | 1978-01-31 | Procedimiento de epoxidacion de olefinas mediante peroxido de hidrogeno. |
NL7801122A NL7801122A (nl) | 1977-02-01 | 1978-01-31 | Werkwijze voor het epoxyderen van alkenen bij aanwezigheid van katalysatoren op basis van arsenicum. |
IT67184/78A IT1111604B (it) | 1977-02-01 | 1978-01-31 | Procedimento di epossidazione delle olefine in presenza di catalizzatori a base di aresenico |
JP937478A JPS5395901A (en) | 1977-02-01 | 1978-02-01 | Method of epoxydizing olefin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7702747A FR2378773A1 (fr) | 1977-02-01 | 1977-02-01 | Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2378773A1 true FR2378773A1 (fr) | 1978-08-25 |
FR2378773B1 FR2378773B1 (fr) | 1979-05-11 |
Family
ID=9186133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7702747A Granted FR2378773A1 (fr) | 1977-02-01 | 1977-02-01 | Procede d'epoxydation des olefines en presence de catalyseurs a base d'arsenic |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS5395901A (fr) |
BE (1) | BE863239A (fr) |
CA (1) | CA1095066A (fr) |
CH (1) | CH626614A5 (fr) |
DE (1) | DE2803757C3 (fr) |
ES (1) | ES466516A0 (fr) |
FR (1) | FR2378773A1 (fr) |
GB (1) | GB1585011A (fr) |
IT (1) | IT1111604B (fr) |
NL (1) | NL7801122A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2508451A1 (fr) * | 1981-06-26 | 1982-12-31 | Interox | Procede pour la fabrication d'epoxydes |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7907165A (nl) * | 1979-09-26 | 1981-03-30 | Wavin Bv | Kunststofkrat. |
JPS57203076A (en) * | 1981-06-08 | 1982-12-13 | Mitsubishi Gas Chem Co Inc | Production of olefin oxide |
DE3264774D1 (en) * | 1981-09-04 | 1985-08-22 | Mitsubishi Gas Chemical Co | Catalytic epoxidation of olefins |
US4410715A (en) | 1982-07-14 | 1983-10-18 | Exxon Research & Engineering Co. | Process for the epoxidation of olefins using a group V metal co-catalyst I and a phenolic hydrocarbon co-catalyst II |
US7456313B2 (en) | 2006-01-10 | 2008-11-25 | Rohm And Haas Company | Liquid-phase (AMM)oxidation process |
CN103172486B (zh) * | 2011-12-22 | 2015-07-29 | 中国石油化工股份有限公司 | 一种从直接环氧化反应产物中回收丙烯的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3518285A (en) * | 1967-03-16 | 1970-06-30 | Union Oil Co | Hydrocarbon olefin oxidation |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1093025B (it) * | 1976-11-26 | 1985-07-19 | Ugine Kuhlmann | Procedimento per l epossidazione delle olefine mediante perossido d idrogeno |
-
1977
- 1977-02-01 FR FR7702747A patent/FR2378773A1/fr active Granted
-
1978
- 1978-01-24 BE BE184571A patent/BE863239A/fr not_active IP Right Cessation
- 1978-01-28 DE DE2803757A patent/DE2803757C3/de not_active Expired
- 1978-01-31 IT IT67184/78A patent/IT1111604B/it active
- 1978-01-31 NL NL7801122A patent/NL7801122A/xx not_active Application Discontinuation
- 1978-01-31 CH CH105478A patent/CH626614A5/fr not_active IP Right Cessation
- 1978-01-31 ES ES466516A patent/ES466516A0/es active Granted
- 1978-01-31 CA CA296,111A patent/CA1095066A/fr not_active Expired
- 1978-01-31 GB GB3890/78A patent/GB1585011A/en not_active Expired
- 1978-02-01 JP JP937478A patent/JPS5395901A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3518285A (en) * | 1967-03-16 | 1970-06-30 | Union Oil Co | Hydrocarbon olefin oxidation |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2508451A1 (fr) * | 1981-06-26 | 1982-12-31 | Interox | Procede pour la fabrication d'epoxydes |
EP0068564A1 (fr) * | 1981-06-26 | 1983-01-05 | INTEROX Société Anonyme | Procédé pour la fabrication d'époxydes |
Also Published As
Publication number | Publication date |
---|---|
ES466516A1 (es) | 1978-10-01 |
CH626614A5 (en) | 1981-11-30 |
DE2803757C3 (de) | 1981-01-29 |
JPS5395901A (en) | 1978-08-22 |
DE2803757A1 (de) | 1978-08-03 |
GB1585011A (en) | 1981-02-18 |
ES466516A0 (es) | 1978-10-01 |
IT7867184A0 (it) | 1978-01-31 |
JPS6244549B2 (fr) | 1987-09-21 |
CA1095066A (fr) | 1981-02-03 |
DE2803757B2 (de) | 1980-05-22 |
IT1111604B (it) | 1986-01-13 |
BE863239A (fr) | 1978-07-24 |
NL7801122A (nl) | 1978-08-03 |
FR2378773B1 (fr) | 1979-05-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |