FR2354808A1 - Poudre de microspheroides macroporeux et procede pour sa fabrication - Google Patents
Poudre de microspheroides macroporeux et procede pour sa fabricationInfo
- Publication number
- FR2354808A1 FR2354808A1 FR7627560A FR7627560A FR2354808A1 FR 2354808 A1 FR2354808 A1 FR 2354808A1 FR 7627560 A FR7627560 A FR 7627560A FR 7627560 A FR7627560 A FR 7627560A FR 2354808 A1 FR2354808 A1 FR 2354808A1
- Authority
- FR
- France
- Prior art keywords
- microspheroid
- powder
- silica
- macroporous
- manufacture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 5
- 239000002245 particle Substances 0.000 abstract 3
- 239000000843 powder Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004587 chromatography analysis Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000003870 refractory metal Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/282—Porous sorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
- B01J20/28019—Spherical, ellipsoidal or cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/005—Inorganic fillers with a shape other than granular or fibrous
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/07—Reinforcing elements of material other than metal, e.g. of glass, of plastics, or not exclusively made of metal
- E04C5/073—Discrete reinforcing elements, e.g. fibres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
- Silicon Compounds (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
L'invention se rapporte aux poudres de microsphéroïdes. Elle concerne une poudre comprenant une pluralité de microsphéroïdes discrets 11 ayant chacun un diamètre moyen d'environ 2 à 50 microns et comprenant une pluralité de particules colloïdales 12 qui forment une matrice poreuse, les pores 14 des microsphéroïdes étant uniformément distribués, caractérisée en ce que les particules colloïdales sont liées ensemble à leurs points de contact par environ 1 à 10 % en poids de silice amorphe non poreuse 13, chaque particule ayant un diamètre moyen d'environ 0,1 à 1,0 micron et comportant une surface de silice et un coeur d'une matière choisie parmi la silice et les oxydes de métaux réfractaires insolubles dans les acides. Application au garnissage de colonne de chromatographie, aux supports de catalyseurs, aux pigments, etc.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/693,111 US4070286A (en) | 1976-06-15 | 1976-06-15 | Macroporous microspheroids and a process for their manufacture |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2354808A1 true FR2354808A1 (fr) | 1978-01-13 |
FR2354808B1 FR2354808B1 (fr) | 1981-12-11 |
Family
ID=24783352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7627560A Granted FR2354808A1 (fr) | 1976-06-15 | 1976-09-14 | Poudre de microspheroides macroporeux et procede pour sa fabrication |
Country Status (9)
Country | Link |
---|---|
US (2) | US4070286A (fr) |
JP (1) | JPS52152882A (fr) |
CA (1) | CA1087593A (fr) |
CH (1) | CH625973A5 (fr) |
DE (1) | DE2641548C2 (fr) |
FR (1) | FR2354808A1 (fr) |
GB (1) | GB1506114A (fr) |
IT (1) | IT1062546B (fr) |
SE (1) | SE420570B (fr) |
Families Citing this family (56)
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GB2087250B (en) * | 1977-11-01 | 1982-12-08 | Atomic Energy Authority Uk | Catalyst preparation |
US4937394A (en) * | 1984-04-23 | 1990-06-26 | Mallinckrodt, Inc. | Silica catalyst supports for hydration of ethylene to ethanol |
US4617060A (en) * | 1984-04-23 | 1986-10-14 | Mallinckrodt, Inc. | Silica catalyst supports |
US4783435A (en) * | 1984-04-23 | 1988-11-08 | Mallinckrodt, Inc. | Silica catalyst supports |
FR2584698B1 (fr) * | 1985-07-15 | 1990-05-18 | Rhone Poulenc Spec Chim | Procede de preparation de particules de silice spheroidales |
US4810415A (en) * | 1985-09-24 | 1989-03-07 | Dresser Industries, Inc. | Process for manufacturing ultra pure silica and resulting encapsulated products |
US5108595A (en) * | 1985-11-01 | 1992-04-28 | E. I. Du Pont De Nemours And Company | Porous silica microspheres having silanol-enriched and silanized surfaces |
US5032266A (en) * | 1985-11-01 | 1991-07-16 | E. I. Du Pont De Nemours And Company | Porous silica microspheres having silanol-enriched and silanized surfaces |
US4874518A (en) * | 1985-11-01 | 1989-10-17 | E. I. Du Pont De Nemours And Company | Porous silica microspheres having a silanol enriched surface |
GB8529970D0 (en) * | 1985-12-05 | 1986-01-15 | Unilever Plc | Spheroidal silica |
JPH0762674B2 (ja) * | 1986-03-07 | 1995-07-05 | 株式会社高研 | クロマトグラフイ−用吸着剤、及びその製造方法、並びに該吸着剤を使用したクロマトグラフイ−カラム |
EP0239970A3 (fr) * | 1986-03-31 | 1988-04-20 | Toa Nenryo Kogyo Kabushiki Kaisha | Assemblage de particules d'hydroxylapatite et son utilisation dans une colonne de chromatographie en phase liquide |
JPS62198241U (fr) * | 1986-06-09 | 1987-12-17 | ||
DE3628120A1 (de) * | 1986-08-19 | 1988-02-25 | Huels Chemische Werke Ag | Verfahren zur herstellung von rieselfaehigen, mit kieselsaeure gefuellten kautschukpulvern |
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US5256386A (en) * | 1987-06-29 | 1993-10-26 | Eka Nobel Ab | Method for preparation of silica particles |
DE3721481A1 (de) * | 1987-06-30 | 1989-01-12 | Du Pont Deutschland | Mattiertes photographisches aufzeichnungsmaterial |
US5145578A (en) * | 1987-07-03 | 1992-09-08 | Shiseido Company Ltd. | Packing material for liquid chromatography |
US4874667A (en) * | 1987-07-20 | 1989-10-17 | Dow Corning Corporation | Microencapsulated platinum-group metals and compounds thereof |
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CA2127605A1 (fr) * | 1993-12-23 | 1995-06-24 | Peter J. Degen | Methode de separation par affinite |
DE4424044A1 (de) * | 1994-07-11 | 1996-01-18 | Heraeus Quarzglas | Verfahren zur Herstellung von Kieselsäuregranulat und Verwendung des so hergestellten Granulats |
US5540834A (en) * | 1994-08-23 | 1996-07-30 | Regents Of The University Of Minnesota | Synthesis of porous inorganic particles by polymerization-induced colloid aggregation (PICA) |
EP0906349B1 (fr) * | 1996-06-21 | 2002-11-27 | W.R. Grace & Co.-Conn. | Supports d'agregats portant des catalyseurs de polymerisation d'olefines |
US6228340B1 (en) | 1997-08-25 | 2001-05-08 | The Regents Of The University Of California | Method for the production of macroporous ceramics |
US6491976B2 (en) | 1998-08-28 | 2002-12-10 | Sharp Kabushiki Kaisha | Method for adding hydrophilic groups to the surface of particles |
EP1188716B1 (fr) * | 1998-12-21 | 2013-02-20 | JGC Catalysts and Chemicals Ltd. | Particules fines, sol de particules fines dispersees, procede de preparation dudit sol et substrat revetu |
US6313061B1 (en) | 1998-12-22 | 2001-11-06 | W. R. Grace & Co.-Conn. | Method of making frangible spray dried agglomerated supports and olefin polymerization catalysts supported thereon |
GB2355711B (en) | 1999-10-27 | 2003-12-24 | Agilent Technologies Inc | Porous silica microsphere scavengers |
DE60027787T2 (de) * | 1999-11-24 | 2007-04-12 | Pierce Chemical Co., Rockford | Granuliertes chromatographiematerial |
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WO2003104319A1 (fr) * | 2002-06-05 | 2003-12-18 | Showa Denko K. K. | Poudre contenant de l'oxyde de zinc recouvert de silice, composition polymere organique renfermant la poudre et article forme associe |
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AU2009342893B2 (en) * | 2009-03-27 | 2014-03-06 | Australian Nuclear Science And Technology Organisation | Triggered release |
CN102639230A (zh) | 2009-10-08 | 2012-08-15 | 格雷斯公司 | 耐硫的氧化铝催化剂载体 |
KR101852924B1 (ko) * | 2011-11-04 | 2018-04-30 | 삼성전자주식회사 | 혼성 다공성 구조체, 이를 포함하는 분리막 및 혼성 다공성 구조체의 제조 방법 |
US9873622B2 (en) | 2011-11-04 | 2018-01-23 | Samsung Electronics Co., Ltd. | Hybrid porous structured material, membrane including the same, and method of preparing hybrid porous structured material |
US11628381B2 (en) | 2012-09-17 | 2023-04-18 | W.R. Grace & Co. Conn. | Chromatography media and devices |
CN104781199B (zh) * | 2012-11-12 | 2017-12-26 | 旭硝子株式会社 | 熔融玻璃输送设备构件、熔融玻璃输送设备构件的制造方法、包含熔融玻璃输送设备构件的玻璃制造装置、及玻璃物品的制造方法 |
ES2929099T3 (es) | 2014-05-02 | 2022-11-24 | Grace W R & Co | Material de soporte funcionalizado y métodos de fabricación y uso de material de soporte funcionalizado |
CN107418173A (zh) * | 2014-06-27 | 2017-12-01 | 赛史品威奥(唐山)结构复合材料有限公司 | 包括表面改性的微球体的低密度模塑料 |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1928021A (en) * | 1931-03-06 | 1933-09-26 | Albright & Wilson | Process of making porous articles consisting of silica |
GB521213A (en) * | 1938-07-06 | 1940-05-15 | Herbert Hans Greger | Improvements in or relating to bonded granular materials |
GB521214A (en) * | 1938-09-21 | 1940-05-15 | Herbert Hans Greger | Improvements in or relating to bonding fuller's earth or other absorbent granular material |
FR941035A (fr) * | 1940-11-19 | 1948-12-30 | Procédé de fabrication d'une matière absorbante et composition réalisée par ce procédé | |
DE863791C (de) * | 1941-10-16 | 1953-01-19 | Basf Ag | Verfahren zur Herstellung von formfesten Katalysatoren oder Adsorptionsmitteln |
US3505785A (en) * | 1967-06-20 | 1970-04-14 | Du Pont | Superficially porous supports for chromatography |
FR2121002A5 (en) * | 1970-12-29 | 1972-08-18 | Shionogi & Co | Chromatographic disc - consisting of sintered fine glass particles with particles of inorg adsorbent enclosed between glass pa |
US3855172A (en) * | 1972-04-07 | 1974-12-17 | Du Pont | Uniform oxide microspheres and a process for their manufacture |
US3862054A (en) * | 1972-05-26 | 1975-01-21 | Dmitry Vladimirovich Sokolsky | Adsorbent for purifying vegetable oils from phosphorus containing compounds |
US3920578A (en) * | 1968-06-12 | 1975-11-18 | Du Pont | Colloidal silica-based binder vehicles and gels |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3328230A (en) * | 1956-04-03 | 1967-06-27 | Saint Gobain | Fiber glass product and method of making it |
US3274888A (en) * | 1962-01-19 | 1966-09-27 | Minnesota Mining & Mfg | Inorganic reflex-reflective aggregate |
US3420644A (en) * | 1964-10-19 | 1969-01-07 | Howmet Corp | Method for molding of glass and ceramic materials |
US3635824A (en) * | 1969-07-03 | 1972-01-18 | Bell Telephone Labor Inc | Resistance heater and method for preparation thereof |
US3758284A (en) * | 1970-12-17 | 1973-09-11 | W Haller | Porous material and method of making the same |
US3988405A (en) * | 1971-04-07 | 1976-10-26 | Smith Robert D | Process for forming thin walled articles or thin sheets |
US3782075A (en) * | 1972-04-07 | 1974-01-01 | Du Pont | Completely porous microspheres for chromatographic uses |
US3875282A (en) * | 1973-04-30 | 1975-04-01 | Stauffer Chemical Co | Production of high bulk density spray dried hydrous sodium silicate |
-
1976
- 1976-06-15 US US05/693,111 patent/US4070286A/en not_active Expired - Lifetime
- 1976-07-13 GB GB29114/76A patent/GB1506114A/en not_active Expired
- 1976-07-26 IT IT25710/76A patent/IT1062546B/it active
- 1976-09-13 CA CA261,031A patent/CA1087593A/fr not_active Expired
- 1976-09-14 SE SE7610155A patent/SE420570B/xx not_active IP Right Cessation
- 1976-09-14 JP JP10948676A patent/JPS52152882A/ja active Granted
- 1976-09-14 FR FR7627560A patent/FR2354808A1/fr active Granted
- 1976-09-15 DE DE2641548A patent/DE2641548C2/de not_active Expired
- 1976-09-15 CH CH1172076A patent/CH625973A5/de not_active IP Right Cessation
-
1977
- 1977-08-22 US US05/826,900 patent/US4105426A/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1928021A (en) * | 1931-03-06 | 1933-09-26 | Albright & Wilson | Process of making porous articles consisting of silica |
GB521213A (en) * | 1938-07-06 | 1940-05-15 | Herbert Hans Greger | Improvements in or relating to bonded granular materials |
GB521214A (en) * | 1938-09-21 | 1940-05-15 | Herbert Hans Greger | Improvements in or relating to bonding fuller's earth or other absorbent granular material |
FR941035A (fr) * | 1940-11-19 | 1948-12-30 | Procédé de fabrication d'une matière absorbante et composition réalisée par ce procédé | |
DE863791C (de) * | 1941-10-16 | 1953-01-19 | Basf Ag | Verfahren zur Herstellung von formfesten Katalysatoren oder Adsorptionsmitteln |
US3505785A (en) * | 1967-06-20 | 1970-04-14 | Du Pont | Superficially porous supports for chromatography |
US3920578A (en) * | 1968-06-12 | 1975-11-18 | Du Pont | Colloidal silica-based binder vehicles and gels |
FR2121002A5 (en) * | 1970-12-29 | 1972-08-18 | Shionogi & Co | Chromatographic disc - consisting of sintered fine glass particles with particles of inorg adsorbent enclosed between glass pa |
US3855172A (en) * | 1972-04-07 | 1974-12-17 | Du Pont | Uniform oxide microspheres and a process for their manufacture |
US3862054A (en) * | 1972-05-26 | 1975-01-21 | Dmitry Vladimirovich Sokolsky | Adsorbent for purifying vegetable oils from phosphorus containing compounds |
Also Published As
Publication number | Publication date |
---|---|
IT1062546B (it) | 1984-10-20 |
CA1087593A (fr) | 1980-10-14 |
US4105426A (en) | 1978-08-08 |
JPS52152882A (en) | 1977-12-19 |
CH625973A5 (fr) | 1981-10-30 |
JPS617858B2 (fr) | 1986-03-10 |
SE7610155L (sv) | 1977-12-16 |
DE2641548C2 (de) | 1986-02-06 |
DE2641548A1 (de) | 1977-12-29 |
FR2354808B1 (fr) | 1981-12-11 |
SE420570B (sv) | 1981-10-19 |
GB1506114A (en) | 1978-04-05 |
US4070286A (en) | 1978-01-24 |
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