FI942536A - Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi - Google Patents

Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi Download PDF

Info

Publication number
FI942536A
FI942536A FI942536A FI942536A FI942536A FI 942536 A FI942536 A FI 942536A FI 942536 A FI942536 A FI 942536A FI 942536 A FI942536 A FI 942536A FI 942536 A FI942536 A FI 942536A
Authority
FI
Finland
Prior art keywords
product
hydrogen
donor
olefins
compound
Prior art date
Application number
FI942536A
Other languages
English (en)
Swedish (sv)
Other versions
FI96214B (fi
FI96214C (fi
FI942536A0 (fi
Inventor
Paeivi L Pitkaenen
Eero Iiskola
Timo Leinonen
Jukka Tulisalo
Original Assignee
Borealis As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As filed Critical Borealis As
Publication of FI942536A0 publication Critical patent/FI942536A0/fi
Priority to FI942536A priority Critical patent/FI96214C/fi
Priority to AU25684/95A priority patent/AU686813B2/en
Priority to JP8500390A priority patent/JPH10501016A/ja
Priority to CN95193372A priority patent/CN1086393C/zh
Priority to CA002191758A priority patent/CA2191758A1/en
Priority to EP95303675A priority patent/EP0685497B1/en
Priority to AT95303675T priority patent/ATE186308T1/de
Priority to KR1019960706781A priority patent/KR100289321B1/ko
Priority to PCT/FI1995/000298 priority patent/WO1995032994A1/en
Priority to DE69513084T priority patent/DE69513084T2/de
Publication of FI942536A publication Critical patent/FI942536A/fi
Publication of FI96214B publication Critical patent/FI96214B/fi
Application granted granted Critical
Publication of FI96214C publication Critical patent/FI96214C/fi
Priority to US08/745,049 priority patent/US5869418A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FI942536A 1994-05-31 1994-05-31 Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi FI96214C (fi)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FI942536A FI96214C (fi) 1994-05-31 1994-05-31 Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi
AT95303675T ATE186308T1 (de) 1994-05-31 1995-05-30 Stereospezifisches katalysatorsystem für olefinpolymerisation
PCT/FI1995/000298 WO1995032994A1 (en) 1994-05-31 1995-05-30 Stereospecific catalyst system for polymerization of olefins
CN95193372A CN1086393C (zh) 1994-05-31 1995-05-30 用于烯烃聚合的立体有择催化剂体系
CA002191758A CA2191758A1 (en) 1994-05-31 1995-05-30 Stereospecific catalyst system for polymerization of olefins
EP95303675A EP0685497B1 (en) 1994-05-31 1995-05-30 Stereospecific catalyst system for polymerisation of olefins
AU25684/95A AU686813B2 (en) 1994-05-31 1995-05-30 Stereospecific catalyst system for polymerization of olefins
KR1019960706781A KR100289321B1 (ko) 1994-05-31 1995-05-30 올레핀을 중합시키기 위한 입체 특이적 촉매계
JP8500390A JPH10501016A (ja) 1994-05-31 1995-05-30 オレフィン重合用の立体特異性触媒系
DE69513084T DE69513084T2 (de) 1994-05-31 1995-05-30 Stereospezifisches Katalysatorsystem für Olefinpolymerisation
US08/745,049 US5869418A (en) 1994-05-31 1996-11-07 Stereospecific catalyst system for polymerization of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI942536 1994-05-31
FI942536A FI96214C (fi) 1994-05-31 1994-05-31 Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi

Publications (4)

Publication Number Publication Date
FI942536A0 FI942536A0 (fi) 1994-05-31
FI942536A true FI942536A (fi) 1995-12-01
FI96214B FI96214B (fi) 1996-02-15
FI96214C FI96214C (fi) 1996-05-27

Family

ID=8540808

Family Applications (1)

Application Number Title Priority Date Filing Date
FI942536A FI96214C (fi) 1994-05-31 1994-05-31 Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi

Country Status (10)

Country Link
EP (1) EP0685497B1 (fi)
JP (1) JPH10501016A (fi)
KR (1) KR100289321B1 (fi)
CN (1) CN1086393C (fi)
AT (1) ATE186308T1 (fi)
AU (1) AU686813B2 (fi)
CA (1) CA2191758A1 (fi)
DE (1) DE69513084T2 (fi)
FI (1) FI96214C (fi)
WO (1) WO1995032994A1 (fi)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100362026C (zh) * 2000-03-30 2008-01-16 住友化学株式会社 烯烃聚合用催化剂的制备方法和烯烃聚合物的制备方法
SG96207A1 (en) 2000-03-30 2003-05-23 Sumitomo Chemical Co Process for producing catalyst for olefin polymerization and process for producing olefin polymer
EP2067794A1 (en) * 2007-12-06 2009-06-10 Borealis Technology OY Use of a Ziegler-Natta procatalyst containing a trans-esterification product of a lower alcohol and a phthalic ester for the production of reactor grade thermoplastic polyolefins with improved paintability
EP2174965B1 (en) 2008-10-08 2013-05-29 Borealis AG Preparation of propylene copolymer with dynamically operated reactor
EP2174962B1 (en) 2008-10-08 2011-11-30 Borealis AG A method to produce very stiff polypropylene
US8450421B2 (en) 2008-12-29 2013-05-28 Borealis Ag Cable layer of modified soft polypropylene with improved stress whitening resistance
EP2216347A1 (en) 2009-01-30 2010-08-11 Borealis AG A method of catalyst transitions in olefin polymerizations
EP2223943B1 (en) 2009-02-25 2011-10-19 Borealis AG Multimodal polymer of propylene, composition containing the same and a process for manufacturing the same
CN102365325B (zh) 2009-04-09 2015-04-22 北欧化工公司 热塑性聚烯烃组合物
EP2452920A1 (en) 2010-11-12 2012-05-16 Borealis AG A method for recovering transition metal tetrahalide and hydrocarbons from a waste stream
PT2495038T (pt) 2011-03-02 2020-11-06 Borealis Ag Conjunto de reator flexível para polimerização de olefinas
HUE051319T2 (hu) 2011-03-02 2021-03-01 Borealis Ag Nagy átmenõteljesítményû reaktoregység olefinek polimerizálására
US8673448B2 (en) * 2011-03-04 2014-03-18 Outlast Technologies Llc Articles containing precisely branched functional polymeric phase change materials
EP2617741B1 (en) 2012-01-18 2016-01-13 Borealis AG Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process
EP2890490B1 (en) 2012-08-29 2020-05-06 Borealis AG Reactor assembly and method for polymerization of olefins
EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
EP2749580B1 (en) 2012-12-28 2016-09-14 Borealis AG Process for producing copolymers of propylene
ES2628082T3 (es) 2013-04-22 2017-08-01 Borealis Ag Procedimiento con múltiples etapas para producir composiciones de polipropileno resistentes a baja temperatura
EP2796472B1 (en) 2013-04-22 2017-06-28 Borealis AG Two-stage process for producing polypropylene compositions
EP2796474B1 (en) 2013-04-22 2018-01-10 Borealis AG Multistage process for producing polypropylene compositions
EP3033389B1 (en) 2013-08-14 2017-10-11 Borealis AG Propylene composition with improved impact resistance at low temperature
WO2015024891A1 (en) 2013-08-21 2015-02-26 Borealis Ag High flow polyolefin composition with high stiffness and toughness
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
EP2853562A1 (en) 2013-09-27 2015-04-01 Borealis AG Two-stage process for producing polypropylene compositions
EP2853563B1 (en) 2013-09-27 2016-06-15 Borealis AG Films suitable for BOPP processing from polymers with high XS and high Tm
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
US10519259B2 (en) 2013-10-24 2019-12-31 Borealis Ag Low melting PP homopolymer with high content of regioerrors and high molecular weight
ES2574428T3 (es) 2013-10-24 2016-06-17 Borealis Ag Artículo moldeado por soplado basado en copolímero al azar bimodal
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
BR112016009549B1 (pt) 2013-11-22 2021-07-27 Borealis Ag Homopolímero de propileno de baixa emissão com alto índice de fluidez
US9828698B2 (en) 2013-12-04 2017-11-28 Borealis Ag Phthalate-free PP homopolymers for meltblown fibers
EP3083777B1 (en) 2013-12-18 2019-04-24 Borealis AG Bopp film with improved stiffness/toughness balance
WO2015107020A1 (en) 2014-01-17 2015-07-23 Borealis Ag Process for preparing propylene/1-butene copolymers
PL3102634T3 (pl) 2014-02-06 2020-11-16 Borealis Ag Miękkie i przezroczyste kopolimery odporne na uderzenia
US10100185B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft copolymers with high impact strength
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2913345B1 (en) 2014-02-28 2016-11-02 Borealis AG Gas phase polymerization process
EP2913346B1 (en) 2014-02-28 2016-11-02 Borealis AG Process for polymerizing olefins in a fluidized bed
EP2947118B1 (en) 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications
EP2995631A1 (en) 2014-09-12 2016-03-16 Borealis AG Process for producing graft copolymers on polyolefin backbone
EP3018155A1 (en) 2014-11-05 2016-05-11 Borealis AG Branched polypropylene for film applications
EP3023450B1 (en) 2014-11-21 2017-07-19 Borealis AG Process for producing pellets of soft copolymers
EP3103818B1 (en) 2015-06-12 2018-06-06 Borealis AG Method and apparatus for polymerising olefins in gas phase
EP3124567A1 (en) 2015-07-30 2017-02-01 Borealis AG Polypropylene based hot-melt adhesive composition
RU2716077C2 (ru) 2015-07-30 2020-03-05 Бореалис Аг Композиция полипропилена с улучшенной прочностью соединения в горячем состоянии
EP3147324B1 (en) 2015-09-28 2018-09-26 Borealis AG Polypropylene pipes with improved pressure resistance
EP3365388B1 (en) 2015-10-21 2020-12-16 Borealis AG Long-chain branched polypropylene composition with increased melt strength stability
PL3368605T3 (pl) 2015-10-28 2022-08-22 Borealis Ag Kompozycja polipropylenowa dla elementu warstwowego
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
EP3184166A1 (en) 2015-12-22 2017-06-28 Borealis AG A method for withdrawing agglomerates from a fluidised bed reactor
EP3184167B8 (en) 2015-12-22 2022-03-30 Borealis AG A method for returning polymer to a fluidised bed reactor
EP3187512A1 (en) 2015-12-31 2017-07-05 Borealis AG Process for preparing propylene copolymer compositions
MX2018010004A (es) 2016-03-14 2018-12-17 Borealis Ag Composicion de polipropileno que comprende retardante de flama.
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
EP3281973A1 (en) 2016-08-11 2018-02-14 Borealis AG Polypropylene composition with flame retardant activity
TWI696654B (zh) 2016-11-09 2020-06-21 奧地利商柏列利斯股份公司 聚丙烯組成物
WO2018141672A1 (en) 2017-02-01 2018-08-09 Borealis Ag Article comprising a layer element
EP3418309A1 (en) 2017-06-20 2018-12-26 Borealis AG A method, an arrangement and use of an arrangement of preparing polymer
EP3418308B1 (en) 2017-06-20 2020-03-11 Borealis AG A method, an arrangement and use of an arrangement for olefin polymerisation
ES2786567T3 (es) 2017-06-23 2020-10-13 Borealis Ag Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido
EP3473674B1 (en) 2017-10-19 2022-04-20 Abu Dhabi Polymers Co. Ltd (Borouge) Llc. Polypropylene composition
EP3479896A1 (en) 2017-11-03 2019-05-08 Borealis AG Polymerization reactor system comprising at least one withdrawal valve
EP3483189A1 (en) 2017-11-14 2019-05-15 Borealis AG Automated method for terminating an olefin polymerization reaction under emergency conditions
EP3486260B1 (en) 2017-11-17 2020-04-01 Borealis AG Method of splitting the return fluidization gas in a gas solids olefin polymerization reactor
EP3486261B1 (en) 2017-11-17 2020-06-24 Borealis AG Method for improving the cooling capacity of a gas solids olefin polymerization reactor
TWI736891B (zh) 2018-05-18 2021-08-21 阿拉伯聯合大公國商阿布達比聚合物股份有限公司（波魯） 熱塑性聚烯烴組成物之改良的流變性質
KR20210005730A (ko) 2018-05-28 2021-01-14 보레알리스 아게 태양 광 (pv) 모듈을 위한 장치
CN112135845B (zh) 2018-06-14 2024-07-09 博里利斯股份公司 用于在具有改善的热均质性的气相反应器中聚合烯烃的方法
CN112638958B (zh) 2018-07-19 2023-06-02 博里利斯股份公司 制备uhmwpe均聚物的方法
WO2020025757A1 (en) 2018-08-02 2020-02-06 Borealis Ag Process for polymerizing ethylene in a multi-stage polymerization process
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
US11897975B2 (en) 2018-09-28 2024-02-13 Borealis Ag Multi-stage process for producing a C2 to C8 olefin polymer composition
US20210317242A1 (en) 2018-09-28 2021-10-14 Borealis Ag Process for producing a prepolymerized solid ziegler-natta catalyst
EP3647645A1 (en) 2018-10-31 2020-05-06 Borealis AG Polyethylene composition for high pressure resistant pipes
EP3873954A1 (en) 2018-10-31 2021-09-08 Borealis AG Polyethylene composition for high pressure resistant pipes with improved homogeneity
WO2020109452A1 (en) 2018-11-30 2020-06-04 Borealis Ag Washing process
US20220177616A1 (en) 2019-06-04 2022-06-09 Borealis Ag Process and reactor assembly for the enhancement of hydrodynamics in a gas-solids fluidized bed reactor
WO2020260021A1 (en) 2019-06-24 2020-12-30 Borealis Ag Process for preparing polypropylene with improved recovery
EP3868793A1 (en) 2020-02-24 2021-08-25 Borealis AG Process for producing alpha-olefin polymers in a multistage polymerization process
JP2023526838A (ja) 2020-05-25 2023-06-23 ボレアリス・アクチェンゲゼルシャフト 両面光起電力モジュール用の一体化バックシートとして適切な層エレメント
EP3915782B1 (en) 2020-05-25 2024-07-17 Borealis AG Layer element suitable as integrated backsheet element of a photovoltaic module
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0197311B1 (en) * 1985-03-08 1991-12-18 Mitsubishi Petrochemical Co., Ltd. Process for polymerizing ethylene
JPH0735410B2 (ja) 1986-01-31 1995-04-19 三菱油化株式会社 オレフィンの立体規則性重合用触媒
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
US4792898A (en) * 1986-09-26 1988-12-20 Mccarthy Donald F Method and apparatus for temporarily storing multiple data records
US4814314A (en) 1986-09-26 1989-03-21 Mitsubishi Petrochemical Company Limited Catalyst for olefin polymerization
JPH0830092B2 (ja) 1986-10-22 1996-03-27 東邦チタニウム株式会社 オレフイン類重合用固体触媒成分
FI83330C (fi) 1988-06-03 1991-06-25 Neste Oy Foerfarande foer aktivering av en polymerisationskatalysatorbaerare och en medelst foerfarandet erhaollen katalysatorkomponent.
DE69019046T2 (de) 1989-03-02 1995-09-07 Mitsui Petrochemical Ind Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation.
FI85710C (fi) 1989-05-16 1992-05-25 Neste Oy Foerfarande foer framstaellning av en olefinpolymerisation aegnad katalysatorkomponent och dess anvaendning.
JP2509767B2 (ja) * 1991-06-28 1996-06-26 出光石油化学株式会社 オレフィン重合体の製造法
IT1241093B (it) * 1990-03-30 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1241094B (it) 1990-03-30 1993-12-29 Himont Inc Polimeri del propilene iperpuri (capacitor grade)
CA2040598A1 (en) 1990-04-20 1991-10-21 Masatoshi Toda Process for producing polyolefins
FI86866C (fi) 1990-12-19 1992-10-26 Neste Oy Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner
FI96615C (fi) 1993-06-04 1996-07-25 Neste Oy Menetelmä C4-C40- -olefiinien polymeroimiseksi tai kopolymeroimiseksi muiden -olefiinien kanssa

Also Published As

Publication number Publication date
CN1086393C (zh) 2002-06-19
DE69513084T2 (de) 2000-02-17
FI96214B (fi) 1996-02-15
FI96214C (fi) 1996-05-27
FI942536A0 (fi) 1994-05-31
AU2568495A (en) 1995-12-21
WO1995032994A1 (en) 1995-12-07
AU686813B2 (en) 1998-02-12
CA2191758A1 (en) 1995-12-07
EP0685497B1 (en) 1999-11-03
CN1149878A (zh) 1997-05-14
KR970703372A (ko) 1997-07-03
DE69513084D1 (de) 1999-12-09
KR100289321B1 (ko) 2001-05-02
ATE186308T1 (de) 1999-11-15
JPH10501016A (ja) 1998-01-27
EP0685497A1 (en) 1995-12-06

Similar Documents

Publication Publication Date Title
FI942536A0 (fi) Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi
FI933806A0 (fi) Katalytkompositioner och foerfarande foer framstaellning av polyolefiner
BR0013223A (pt) Complexos de monociclopentadienila, monoindenila, monofluorenila ou heterociclopentadienila substituìdos de cromo, molebdênio ou tungstênio, processo para a polimeração ou copolimeração de olefinas, polimerizados de olefina, e, fibras, lâminas e corpos moldados
CA2077744A1 (en) Homogeneous-heterogeneous catalyst system for polyolefins
FI931107A (fi) Foerfarande foer polymerisation av olefiner i gasfas
ATE132507T1 (de) Trägerkatalysator für olefinpolymerisation mit monozyklopentadienylkomplexen von übergangsmetallen
DE69017987D1 (de) Katalysator auf Träger für Ethylenpolymerisation.
NO960350A (no) Fremgangsmåte og katalysatorsystem for polymerisering av etylen, eventuelt sammen med <alfa>-olefiner, og fremstilt polymermateriale
NO943642D0 (no) Fremgangsmåte for olefinpolymerisasjon
DK0446989T3 (da) Katalysator på bærer til ethylenpolymerisation og copolymerisationen af ethylen med alfa-olefiner, dens fremstilling og brug
FR2738826B1 (fr) Alcoxysilacycloalcanes, leur procede de preparation et leur utilisation pour la polymerisation des olefines
MY110520A (en) Control of a solution process for polymerization of ethylene.
EP0376348A3 (en) Catalyst for regulating the molecular weight distribution of ethylene polymers
AU1015292A (en) Metallocene (CO)polymers, process for their preparation and their use as catalysts
FR2746672B1 (fr) Composante catalytique et son utilisation en polymerisation des olefines
FI943237A0 (fi) Eteenin (ko)polymerointiin soveltuvia katalyyttejä
FR2729393B1 (fr) Procede de polymerisation d'olefine
NO159285C (no) Fremgangsmaate til fremstilling av et katalysatorsystem, katalysatorsystem og anvendelse av et katalysatorsystem fremstilt iht. fremgangsmaaten.
FR2793799B1 (fr) Polymerisation des olefines en presence de dialcoxysilacyclohexanes
TH42250A3 (th) กระบวนการโพลีเมอไรเซชันของโอลีฟิน
TH42251A3 (fi)

Legal Events

Date Code Title Description
FG Patent granted

Owner name: BOREALIS A/S

GB Transfer or assigment of application

Owner name: BOREALIS A/S

HC Name/ company changed in application

Owner name: BOREALIS A/S

BB Publication of examined application