AU1015292A - Metallocene (CO)polymers, process for their preparation and their use as catalysts - Google Patents

Metallocene (CO)polymers, process for their preparation and their use as catalysts

Info

Publication number
AU1015292A
AU1015292A AU10152/92A AU1015292A AU1015292A AU 1015292 A AU1015292 A AU 1015292A AU 10152/92 A AU10152/92 A AU 10152/92A AU 1015292 A AU1015292 A AU 1015292A AU 1015292 A AU1015292 A AU 1015292A
Authority
AU
Australia
Prior art keywords
metallocene
catalysts
polymers
preparation
metallocenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU10152/92A
Other versions
AU646537B2 (en
Inventor
Martin Antberg
Hans-Friedrich Herrmann
Jurgen Rohrmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of AU1015292A publication Critical patent/AU1015292A/en
Application granted granted Critical
Publication of AU646537B2 publication Critical patent/AU646537B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

An immobile (heterogeneous) metallocene catalyst component which can advantageously be employed for the polymerisation of olefins is obtained by the homopolymerisation of suitably substituted (vinyl group-containing) metallocenes from the 4th sub-group of the Periodic Table or by copolymerisation of such metallocenes with (di)vinylaromatic compounds.
AU10152/92A 1991-01-12 1992-01-10 Metallocene (CO)polymers, process for their preparation and their use as catalysts Ceased AU646537B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4100761 1991-01-12
DE4100761 1991-01-12

Publications (2)

Publication Number Publication Date
AU1015292A true AU1015292A (en) 1992-07-16
AU646537B2 AU646537B2 (en) 1994-02-24

Family

ID=6422907

Family Applications (1)

Application Number Title Priority Date Filing Date
AU10152/92A Ceased AU646537B2 (en) 1991-01-12 1992-01-10 Metallocene (CO)polymers, process for their preparation and their use as catalysts

Country Status (8)

Country Link
EP (1) EP0496193B1 (en)
JP (1) JP3281636B2 (en)
AT (1) ATE166077T1 (en)
AU (1) AU646537B2 (en)
CA (1) CA2059029A1 (en)
DE (1) DE59209320D1 (en)
ES (1) ES2116299T3 (en)
ZA (1) ZA92182B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69328955T2 (en) * 1992-09-04 2000-11-09 Bp Chem Int Ltd Catalyst compositions and processes for making polyolefins
ES2148204T3 (en) * 1992-09-04 2000-10-16 Bp Chem Int Ltd CATALYTIC COMPOSITIONS AND PROCEDURE FOR THE PREPARATION OF POLYOLEFINS.
US5635573A (en) * 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US6121383A (en) * 1993-01-19 2000-09-19 Advanced Elastomer Systems, L.P. Thermosplastic vulcanizates from blends of a polypropylene and elastic α-olefin/cyclic olefin copolymers
US5837787A (en) * 1993-01-19 1998-11-17 Exxon Chemical Patents, Inc. Process for producing elastic thermoplastic α-olefin/cyclic olefin copolymers
US5763532A (en) * 1993-01-19 1998-06-09 Exxon Chemical Patents, Inc. Blends of polypropylene and elastic alpha-olefin/cyclic olefin copolymers
GB9300934D0 (en) * 1993-01-19 1993-03-10 Bp Chem Int Ltd Metallocene complexes
JP3307704B2 (en) * 1993-02-19 2002-07-24 三菱化学株式会社 Production method of .ALPHA.-olefin polymer
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5635437A (en) * 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
US7176158B2 (en) 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
US7319083B2 (en) 2002-10-25 2008-01-15 Exxonmobil Chemical Patents Inc. Polymerized catalyst composition
US7119155B2 (en) 2002-10-25 2006-10-10 Exxonmobil Chemical Patents Inc. Polymerized catalyst composition II

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4613670A (en) * 1982-05-13 1986-09-23 Wright State University Group IVB metal containing polydyes

Also Published As

Publication number Publication date
JP3281636B2 (en) 2002-05-13
EP0496193B1 (en) 1998-05-13
ES2116299T3 (en) 1998-07-16
DE59209320D1 (en) 1998-06-18
JPH04308598A (en) 1992-10-30
EP0496193A1 (en) 1992-07-29
ATE166077T1 (en) 1998-05-15
CA2059029A1 (en) 1992-07-13
AU646537B2 (en) 1994-02-24
ZA92182B (en) 1992-09-30

Similar Documents

Publication Publication Date Title
AU3559893A (en) Catalyst for the polymerization of olefins, process for its preparation and its use
AU1015292A (en) Metallocene (CO)polymers, process for their preparation and their use as catalysts
ZA932982B (en) Olefin polymerization catalyst, process for its preparation, and its use
HUT51651A (en) Cathalizator for polimerization of olefines
EP0908468A3 (en) Process for the (co)polymerisation of olefins
AU643673B2 (en) Catalysts for the polymerization of olefins
AU589986B2 (en) Polymerisation of olefins using a ziegler-natta catalyst and two organometallic compounds
HUT67821A (en) Polymerization catalyst system, process for producing thereof and polyolefins by using it
AU7899194A (en) Metallocenes, process for their preparation and their use as catalysts
EP0416928A3 (en) New carrier catalyst for the polymerization of ethylene
EP0328348A3 (en) Olefin polymerization catalyst and process for the polymerization of olefins
AU564265B2 (en) Olefin polymerisation catalyst
AU6618294A (en) Catalysts for the (co)polymerization of ethylene
EP0341539A3 (en) Catalyst for ethylene polymerisation, process for its preparation and use of the ethylene polymers in preparing foils with a low tendency to block
EP0587440A3 (en) Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same.
SE9203669D0 (en) UNSATURED FOOD COPY POLYMER AND SET FOR PREPARATION THEREOF
HUT59430A (en) Process fo rpolymerization of olefins
ES2096234T3 (en) OLEPHINE POLYMERIZATION CATALYST, ITS PROCEDURE FOR OBTAINING.
CA2256972A1 (en) Catalyst composition for the polymerization of olefins
AU3194393A (en) Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof
NO905189L (en) PROCEDURE FOR PREPARING A POLYMER CONTAINING STARCH.
EP0941997A3 (en) Bridged zirconocene compounds, process for their preparation, and their use as catalyst components in the polymerization of olefins
ES8802395A1 (en) Polymerisation process for preparing ethylene polymers and copolymers of ethylene and alpha-olefins or diolefins
ES2018115A6 (en) Procedure for polymerization and copolymerization of ethylene with other [alpha]-olefins.
CA2042961A1 (en) Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution

Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired