FI895096A0 - Foerfarande foer anvaendning av trietylaluminium foer framstaellning av en alumoxanbaerare foer en aktiv metallocenkatalysator. - Google Patents

Foerfarande foer anvaendning av trietylaluminium foer framstaellning av en alumoxanbaerare foer en aktiv metallocenkatalysator.

Info

Publication number
FI895096A0
FI895096A0 FI895096A FI895096A FI895096A0 FI 895096 A0 FI895096 A0 FI 895096A0 FI 895096 A FI895096 A FI 895096A FI 895096 A FI895096 A FI 895096A FI 895096 A0 FI895096 A0 FI 895096A0
Authority
FI
Finland
Prior art keywords
foer
silica gel
alumoxane
catalyst
trietylaluminium
Prior art date
Application number
FI895096A
Other languages
English (en)
Finnish (fi)
Inventor
Main Chang
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23002330&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FI895096(A0) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of FI895096A0 publication Critical patent/FI895096A0/fi

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Chemically Coating (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Unwinding Webs (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FI895096A 1988-10-27 1989-10-26 Foerfarande foer anvaendning av trietylaluminium foer framstaellning av en alumoxanbaerare foer en aktiv metallocenkatalysator. FI895096A0 (fi)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/263,572 US4937217A (en) 1987-12-17 1988-10-27 Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst

Publications (1)

Publication Number Publication Date
FI895096A0 true FI895096A0 (fi) 1989-10-26

Family

ID=23002330

Family Applications (1)

Application Number Title Priority Date Filing Date
FI895096A FI895096A0 (fi) 1988-10-27 1989-10-26 Foerfarande foer anvaendning av trietylaluminium foer framstaellning av en alumoxanbaerare foer en aktiv metallocenkatalysator.

Country Status (17)

Country Link
US (1) US4937217A (fr)
EP (1) EP0367503B1 (fr)
JP (1) JP2740921B2 (fr)
KR (1) KR900006368A (fr)
AT (1) ATE78043T1 (fr)
AU (1) AU621674B2 (fr)
BR (1) BR8905479A (fr)
CA (1) CA2001249C (fr)
DE (1) DE68902039T2 (fr)
DK (1) DK535889A (fr)
ES (1) ES2052021T3 (fr)
FI (1) FI895096A0 (fr)
HU (1) HUT53384A (fr)
IL (1) IL92093A0 (fr)
NO (1) NO894280L (fr)
PT (1) PT92126A (fr)
YU (1) YU207289A (fr)

Families Citing this family (141)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5086025A (en) * 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5006500A (en) * 1988-10-27 1991-04-09 Exxon Chemical Patents Inc. Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
US4904631A (en) * 1988-11-08 1990-02-27 Exxon Chemical Patents, Inc. Supported vanadium catalyst for polymerization of olefins and a process of preparing and using the same
DE4032266A1 (de) * 1990-10-11 1992-04-16 Hoechst Ag Verfahren zur herstellung eines polyolefins
TW218884B (fr) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
EP0515132B2 (fr) * 1991-05-20 2003-08-27 Mitsui Chemicals, Inc. Catalyseur et procédé de polymérisation d'oléfine
US5157008A (en) * 1991-08-01 1992-10-20 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
EP0578838A1 (fr) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5391529A (en) * 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
WO1995007939A1 (fr) 1993-09-17 1995-03-23 Exxon Chemical Patents Inc. Systemes catalyseurs de polymerisation, leur production et utilisation
US5455741A (en) * 1993-10-26 1995-10-03 Pulse Engineering, Inc. Wire-lead through hole interconnect device
DE4336659A1 (de) * 1993-10-27 1995-05-04 Witco Gmbh Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5674795A (en) * 1993-12-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US6391817B1 (en) 1993-12-28 2002-05-21 Exxonmobil Chemical Patents Inc. Method for producing a prepolymerized catalyst
JP3223191B2 (ja) * 1994-01-11 2001-10-29 エクソンモービル・ケミカル・パテンツ・インク アルモキサン、アルモキサンを用いる触媒及びその触媒により製造されるポリマー
US5629253A (en) * 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
EP0766700B1 (fr) * 1994-06-24 2000-01-19 Exxon Chemical Patents Inc. Systemes catalyseurs de polymerisation, leur production et leur utilisation
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
US5731253A (en) * 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
CA2225493A1 (fr) 1995-08-10 1997-02-20 Exxon Chemical Patents, Inc. Alumoxane stabilise par des metallocenes
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US5756416A (en) * 1995-11-28 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition having improved comonomer reactivity
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
AU718884B2 (en) 1996-06-17 2000-04-20 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
CA2259999A1 (fr) * 1996-07-15 1998-01-22 Mobil Oil Corporation Catalyseur bimetallique pretraite par comonomere pour le moulage par soufflage et pour des applications en films
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
US5847177A (en) * 1996-10-10 1998-12-08 Albemarle Corporation Production of hydrocarbon-soluble hydrocarbylaluminoxanes
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
ATE189822T1 (de) * 1996-10-30 2000-03-15 Repsol Quimica Sa Organometallische katalysatoren für die polymerisation und die copolymerisation von alpha-olefinen
PT839836E (pt) 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
US6005463A (en) * 1997-01-30 1999-12-21 Pulse Engineering Through-hole interconnect device with isolated wire-leads and component barriers
EP0856524A1 (fr) 1997-02-01 1998-08-05 Repsol Quimica S.A. Composants catalytiques hétérogènes pour la polymérisation des oléfines, procédé pour leur préparation et leur utilisation
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US5990035A (en) * 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
US7148173B2 (en) 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
DE19826743A1 (de) 1998-06-16 1999-12-23 Bayer Ag Verfahren zur Herstellung von geträgerten Polymerisationskatalysatorsystemen und Verwendung dieser zur Homo- und Copolymerisation ungesättigter Monomere
AU4962399A (en) 1998-07-01 2000-01-24 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
KR100430438B1 (ko) 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US7220804B1 (en) 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6914027B2 (en) * 2000-12-01 2005-07-05 Univation Technologies, Llc Polymerization reactor operability using static charge modifier agents
EP1390417B1 (fr) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Procédé de polymérisation de l'éthylène et de propylène en solution
JP2005511804A (ja) * 2001-11-30 2005-04-28 エクソンモービル・ケミカル・パテンツ・インク 非単一部位触媒/単一部位触媒組み合わせを用いて製造されるエチレン/α−オレフィンコポリマー並びにその製造及びその使用
WO2003083003A1 (fr) * 2002-03-22 2003-10-09 Exxonmobil Chemical Patents Inc. Adhesifs
EP1352913B1 (fr) * 2002-04-08 2016-06-01 Tosoh Finechem Corporation Procédé pour la préparation de methylaluminoxane modifié comme composant catalytique pour la polymérisation d'olefins
DE602004027473D1 (de) * 2003-03-21 2010-07-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7803865B2 (en) * 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US8349929B2 (en) * 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US8158711B2 (en) * 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US8357749B2 (en) * 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US7385015B2 (en) * 2004-10-12 2008-06-10 Exxonmobil Chemical Patents Inc. Trialkylaluminum treated supports
WO2006049857A1 (fr) 2004-10-28 2006-05-11 Dow Global Technologies Inc. Procédé de régulation d'un réacteur de polymérisation
EP1803747A1 (fr) 2005-12-30 2007-07-04 Borealis Technology Oy Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films
ES2567141T3 (es) 2006-05-05 2016-04-20 Dow Global Technologies Llc Complejos de hafnio de ligandos de imidazol sustituidos con carbazolilo
BRPI0815807B1 (pt) 2007-08-29 2021-05-11 W.R.Grace & Co.-Conn composição de ativadores de catalisador de aluminoxanos derivados dos agentes precursores do cátion dialquilalumínio, processos para fazer os mesmos, e sua utilização em catalisadores e polimerização de olefinas.
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) * 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
KR101271055B1 (ko) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법
EP2172490A1 (fr) 2008-10-03 2010-04-07 Ineos Europe Limited Procédé de polymérisation
KR101698618B1 (ko) 2009-01-08 2017-01-20 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 중합 방법을 위한 첨가제
WO2010080871A1 (fr) 2009-01-08 2010-07-15 Univation Technologies, Llc Additif pour procédés de polymérisation en phase gazeuse
JP2010189385A (ja) * 2009-01-26 2010-09-02 Koei Chem Co Ltd シクロペンタジエン類の製造方法
US8309749B2 (en) 2009-06-11 2012-11-13 W R Grace & Co-Conn Process of making aluminoxane and catalysts containing thus prepared aluminoxane
WO2011011427A1 (fr) 2009-07-23 2011-01-27 Univation Technologies, Llc Système réactionnel de polymérisation
WO2011078923A1 (fr) 2009-12-23 2011-06-30 Univation Technologies, Llc Procédés pour produire des systèmes de catalyseur
EP2357035A1 (fr) 2010-01-13 2011-08-17 Ineos Europe Limited Stockage et/ou transport de poudre de polymère et/ou récipients de dégazage
RU2554881C2 (ru) 2010-02-18 2015-06-27 Юнивейшн Текнолоджиз, Ллк Способы управления работой реактора для полимеризации
WO2011103402A1 (fr) 2010-02-22 2011-08-25 Univation Technologies, Llc Systèmes catalyseurs et procédés d'utilisation de ces derniers pour produire des produits de polyoléfine
US8722804B2 (en) 2010-04-13 2014-05-13 Univation Technologies, Llc Polymer blends and films made therefrom
EP2383298A1 (fr) 2010-04-30 2011-11-02 Ineos Europe Limited Procédé de polymérisation
EP2383301A1 (fr) 2010-04-30 2011-11-02 Ineos Europe Limited Procédé de polymérisation
US20130115708A1 (en) 2010-07-16 2013-05-09 Univation Technologies, Llc Systems and Methods for Measuring Particle Accumulation on Reactor Surfaces
WO2012009215A1 (fr) 2010-07-16 2012-01-19 Univation Technologies, Llc Systèmes et procédés pour mesurer la charge statique portée par des particules
WO2012015898A1 (fr) 2010-07-28 2012-02-02 Univation Technologies, Llc Systèmes et procédés pour mesurer la vitesse d'un mélange particule/fluide
WO2012072417A1 (fr) 2010-11-29 2012-06-07 Ineos Commercial Services Uk Limited Procédé de contrôle de polymérisation
EP2651982B1 (fr) 2010-12-17 2018-04-11 Univation Technologies, LLC Systèmes et procédés de récupération d'hydrocarbures à partir d'un produit gaz de purge de polyoléfine
RU2577324C2 (ru) 2010-12-22 2016-03-20 Юнивейшн Текнолоджиз, Ллк Добавка для способов полимеризации полиолефина
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
WO2013028283A1 (fr) 2011-08-19 2013-02-28 Univation Technologies, Llc Systèmes de catalyseur et leurs procédés d'utilisation pour la production de produits de polyoléfine
RU2608615C2 (ru) 2011-10-17 2017-01-23 Инеос Юроуп Аг Регулирование процесса дегазации полимеров
BR112014010906B1 (pt) 2011-11-08 2020-12-01 Univation Technologies, Llc método para produzir uma poliolefina
RU2640048C2 (ru) 2012-03-05 2017-12-26 Юнивейшн Текнолоджиз, Ллк Способ получения каталитических композиций и полимерных продуктов, полученных с применением этих каталитических композиций
CA2800056A1 (fr) 2012-12-24 2014-06-24 Nova Chemicals Corporation Compositions de melange de polyethylene
EP4039366A1 (fr) 2012-12-28 2022-08-10 Univation Technologies, LLC Catalyseur supporté ayant un écoulement amélioré
WO2014105464A1 (fr) 2012-12-28 2014-07-03 Dow Global Technologies Llc Compositions de revêtement
BR112015015417B1 (pt) 2012-12-28 2021-08-17 Dow Global Technologies Llc Composição de revestimento
CN105143285B (zh) 2013-02-07 2019-03-08 尤尼威蒂恩技术有限责任公司 聚烯烃的制备
CN105143281B (zh) 2013-03-15 2018-06-01 尤尼威蒂恩技术有限责任公司 用于烯烃聚合催化剂的三齿氮类配体
ES2644669T3 (es) 2013-03-15 2017-11-29 Univation Technologies, Llc Ligandos para catalizadores
CN105308007B (zh) 2013-06-05 2017-07-21 尤尼威蒂恩技术有限责任公司 保护酚基
CN106714967B (zh) 2014-08-19 2020-07-17 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
BR112017003314A2 (pt) 2014-08-19 2018-01-23 Univation Tech Llc suportes de catalisador fluorados e sistemas de catalisador
SG11201701260WA (en) 2014-08-19 2017-03-30 Univation Tech Llc Fluorinated catalyst supports and catalyst systems
SG11201705607QA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for controlling polymer chain scission
SG11201705576YA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for gel reduction in polyolefins
BR112017023386B1 (pt) 2015-05-08 2022-04-05 Exxonmobil Chemical Patents Inc Processo de polimerização em fase gasosa em modo condensado
WO2018063765A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2018063764A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
EP3519466B1 (fr) 2016-09-27 2023-07-05 Univation Technologies, LLC Méthode de contrôle des branchements longs dans la préparation de polyéthylène
WO2018063767A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Processus de polymérisation
WO2018118155A1 (fr) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
EP3580244A1 (fr) 2017-02-07 2019-12-18 ExxonMobil Chemical Patents Inc. Procédés de réduction de perte d'activité catalytique d'un catalyseur ziegler-natta
US11193008B2 (en) 2017-04-10 2021-12-07 Exxonmobil Chemical Patents Inc. Methods for making polyolefin polymer compositions
KR102292947B1 (ko) 2017-05-10 2021-08-25 유니베이션 테크놀로지즈, 엘엘씨 촉매계 및 이의 사용 방법
WO2019089145A1 (fr) 2017-10-31 2019-05-09 Exxonmobil Chemical Patents Inc. Catalyseurs à base d'un métallocène monosite supportés par de la silice sans toluène, obtenus par formation d'un aluminoxane supporté in situ dans des solvants aliphatiques
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
WO2019118073A1 (fr) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Procédés de désactivation pour composants actifs à partir d'un procédé de polymérisation de polyoléfine en phase gazeuse
WO2019173030A1 (fr) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Procédés de préparation et de surveillance d'un lit de germination pour le démarrage d'un réacteur de polymérisation
CN112055719B (zh) 2018-05-02 2022-11-25 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
US20230220136A1 (en) 2020-07-22 2023-07-13 Exxonmobil Chemical Patents Inc. Polyolefin Compositions and Articles Thereof
CN116529253A (zh) 2020-11-23 2023-08-01 埃克森美孚化学专利公司 改进的原位mao衍生的二氧化硅负载的单中心茂金属催化剂
EP4259669A1 (fr) 2020-12-08 2023-10-18 ExxonMobil Chemical Patents Inc. Compositions de polyéthylène haute densité à ramification à longue chaîne
WO2023250240A1 (fr) 2022-06-24 2023-12-28 Exxonmobil Chemical Patents Inc. Procédés à faible coût de support de mao in situ et catalyseurs de polyoléfine finis dérivés

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3240382A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von gefuellten polyolefinen
DE3424697C2 (de) * 1984-07-05 1999-07-08 Targor Gmbh Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst

Also Published As

Publication number Publication date
CA2001249C (fr) 1999-07-13
DE68902039D1 (de) 1992-08-13
YU207289A (en) 1991-02-28
BR8905479A (pt) 1990-05-29
DK535889D0 (da) 1989-10-27
DK535889A (da) 1990-04-28
EP0367503A1 (fr) 1990-05-09
KR900006368A (ko) 1990-05-08
AU621674B2 (en) 1992-03-19
HU895470D0 (en) 1990-01-28
DE68902039T2 (de) 1993-02-11
NO894280L (no) 1990-04-30
JP2740921B2 (ja) 1998-04-15
JPH02170805A (ja) 1990-07-02
NO894280D0 (no) 1989-10-26
HUT53384A (en) 1990-10-28
EP0367503B1 (fr) 1992-07-08
ES2052021T3 (es) 1994-07-01
PT92126A (pt) 1990-04-30
US4937217A (en) 1990-06-26
CA2001249A1 (fr) 1990-04-27
AU4373489A (en) 1990-05-03
ATE78043T1 (de) 1992-07-15
IL92093A0 (en) 1990-07-12

Similar Documents

Publication Publication Date Title
FI895096A0 (fi) Foerfarande foer anvaendning av trietylaluminium foer framstaellning av en alumoxanbaerare foer en aktiv metallocenkatalysator.
FI895646A0 (fi) Foerfarande foer framstaellning av en kiselgelburen metallocenalumoxankatalysator.
FI885570A (fi) Foerfarande foer framstaellning av en buren metallocenalumoxankatalysator foer gasfaspolymerisering.
FI903448A0 (fi) Foerfarande foer anvaendning av trietylaluminium vid framstaellning av alumoxanbaerarematerial foer aktiv metallocenkatalysator.

Legal Events

Date Code Title Description
MM Patent lapsed

Owner name: EXXON CHEMICAL PATENTS INC.