FI62116C - Saett att framstaella tvaerbundna formade produkter fraon tvaerbindbara olefin- eller vinylkloridpolymermaterial - Google Patents
Saett att framstaella tvaerbundna formade produkter fraon tvaerbindbara olefin- eller vinylkloridpolymermaterial Download PDFInfo
- Publication number
- FI62116C FI62116C FI2989/74A FI298974A FI62116C FI 62116 C FI62116 C FI 62116C FI 2989/74 A FI2989/74 A FI 2989/74A FI 298974 A FI298974 A FI 298974A FI 62116 C FI62116 C FI 62116C
- Authority
- FI
- Finland
- Prior art keywords
- crosslinking
- peroxide
- product
- polyethylene
- peroxides
- Prior art date
Links
- 239000000463 material Substances 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 55
- 238000004132 cross linking Methods 0.000 claims description 51
- 239000004698 Polyethylene Substances 0.000 claims description 46
- 150000002978 peroxides Chemical class 0.000 claims description 36
- -1 polyethylene Polymers 0.000 claims description 33
- 229920000573 polyethylene Polymers 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000012736 aqueous medium Substances 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 239000002609 medium Substances 0.000 claims description 6
- 150000001451 organic peroxides Chemical class 0.000 claims description 6
- 239000004604 Blowing Agent Substances 0.000 claims description 4
- 238000003856 thermoforming Methods 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 description 27
- 239000000047 product Substances 0.000 description 22
- 239000000126 substance Substances 0.000 description 21
- 239000002245 particle Substances 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000000839 emulsion Substances 0.000 description 13
- 238000000465 moulding Methods 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- 239000000945 filler Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000002861 polymer material Substances 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000546 pharmaceutical excipient Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical group CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 239000011243 crosslinked material Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000720945 Hosta Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004680 hydrogen peroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000011326 mechanical measurement Methods 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB47993/73A GB1489580A (en) | 1973-10-15 | 1973-10-15 | Manufacturing cross-linked moulded articles from cross-linkable polymeric materials |
| GB4799373 | 1973-10-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI298974A7 FI298974A7 (enrdf_load_stackoverflow) | 1975-04-16 |
| FI62116B FI62116B (fi) | 1982-07-30 |
| FI62116C true FI62116C (fi) | 1982-11-10 |
Family
ID=10446990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI2989/74A FI62116C (fi) | 1973-10-15 | 1974-10-14 | Saett att framstaella tvaerbundna formade produkter fraon tvaerbindbara olefin- eller vinylkloridpolymermaterial |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS586736B2 (enrdf_load_stackoverflow) |
| DE (1) | DE2448861C2 (enrdf_load_stackoverflow) |
| DK (1) | DK144513C (enrdf_load_stackoverflow) |
| FI (1) | FI62116C (enrdf_load_stackoverflow) |
| GB (1) | GB1489580A (enrdf_load_stackoverflow) |
| NO (1) | NO139299C (enrdf_load_stackoverflow) |
| SE (1) | SE410194B (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7908964A (nl) * | 1979-12-13 | 1981-07-16 | Akzo Nv | Werkwijze ter bereiding van masterbatches van peroxyden in polymeren. |
| DE3007531A1 (de) * | 1980-02-28 | 1981-10-08 | Dynamit Nobel Ag, 5210 Troisdorf | Formkoerper aus kunststoff mit einer peroxydisch vernetzbaren komponente und verfahren zu seiner herstellung |
| JPS58121202A (ja) * | 1982-01-13 | 1983-07-19 | Nippon Nohyaku Co Ltd | 農園芸用殺菌剤 |
| JPS5959725A (ja) * | 1982-09-30 | 1984-04-05 | Shin Etsu Chem Co Ltd | シリコ−ンゴム成形品の硬化方法 |
| FR2534260B1 (fr) * | 1982-10-08 | 1986-01-10 | Lambert Francois | Procede de polymerisation de resines thermodurcissables |
| GB8517665D0 (en) * | 1985-07-12 | 1985-08-21 | Ass Elect Ind | Extruded products |
| US4873042A (en) * | 1988-03-25 | 1989-10-10 | Union Carbide Chemicals And Plastics Company Inc. | Process for extruding a thermoplastic copolymer |
| JPH0280434A (ja) * | 1988-09-19 | 1990-03-20 | Regurusu:Kk | 樹脂成形物及びその製造方法 |
| WO2005049671A1 (en) * | 2003-11-14 | 2005-06-02 | Exxonmobil Chemical Patents Inc. | High strength propylene-based elastomers and uses thereof |
| EP1857500A4 (en) * | 2005-02-10 | 2011-04-06 | Mitsui Du Pont Polychemical | METHOD FOR PRODUCING SEALING MATERIAL FOR SOLAR CELLS |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1084175B (de) * | 1957-11-13 | 1960-06-23 | Hoechst Ag | Verfahren zum Verbinden von Polyolefinen mit makromolekularen Stoffen |
| IT612464A (enrdf_load_stackoverflow) * | 1959-07-17 | 1900-01-01 | ||
| GB1383924A (en) * | 1971-03-25 | 1974-02-12 | Kanegafuchi Chemical Ind | Method of manufacturing polymer particles having uniform crosslin king and expanded shaped articles formed therefrom |
| JPS5438135B2 (enrdf_load_stackoverflow) * | 1971-09-30 | 1979-11-19 | ||
| US3705257A (en) * | 1972-03-06 | 1972-12-05 | Anaconda Wire & Cable Co | Electric cable and method of making |
-
1973
- 1973-10-15 GB GB47993/73A patent/GB1489580A/en not_active Expired
-
1974
- 1974-10-11 NO NO743669A patent/NO139299C/no unknown
- 1974-10-14 SE SE7412882A patent/SE410194B/xx not_active IP Right Cessation
- 1974-10-14 FI FI2989/74A patent/FI62116C/fi active
- 1974-10-14 DK DK536374A patent/DK144513C/da not_active IP Right Cessation
- 1974-10-14 DE DE2448861A patent/DE2448861C2/de not_active Expired
- 1974-10-15 JP JP49118580A patent/JPS586736B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1489580A (en) | 1977-10-19 |
| SE410194B (sv) | 1979-10-01 |
| DE2448861C2 (de) | 1984-12-20 |
| JPS5083476A (enrdf_load_stackoverflow) | 1975-07-05 |
| NO139299B (no) | 1978-10-30 |
| DK144513C (da) | 1982-10-18 |
| SE7412882L (enrdf_load_stackoverflow) | 1975-04-16 |
| DE2448861A1 (de) | 1975-04-17 |
| DK144513B (da) | 1982-03-22 |
| JPS586736B2 (ja) | 1983-02-05 |
| FI62116B (fi) | 1982-07-30 |
| NO139299C (no) | 1979-02-07 |
| FI298974A7 (enrdf_load_stackoverflow) | 1975-04-16 |
| NO743669L (enrdf_load_stackoverflow) | 1975-05-12 |
| DK536374A (enrdf_load_stackoverflow) | 1975-06-16 |
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