FI112234B - Katalytkompositioner och förfarande för framställning av polyolefiner - Google Patents

Katalytkompositioner och förfarande för framställning av polyolefiner Download PDF

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Publication number
FI112234B
FI112234B FI933805A FI933805A FI112234B FI 112234 B FI112234 B FI 112234B FI 933805 A FI933805 A FI 933805A FI 933805 A FI933805 A FI 933805A FI 112234 B FI112234 B FI 112234B
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Prior art keywords
group
catalytic composition
composition according
metallocene
bis
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FI933805A
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English (en)
Finnish (fi)
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FI933805A (fi
FI933805A0 (fi
Inventor
Ian Raymond Little
John Paul Mcnally
Christine Jacqueline Chabrand
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Bp Chem Int Ltd
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Priority claimed from GB929218805A external-priority patent/GB9218805D0/en
Priority claimed from GB939305963A external-priority patent/GB9305963D0/en
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Publication of FI933805A0 publication Critical patent/FI933805A0/fi
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/68—Vanadium, niobium, tantalum or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Claims (14)

1. Katalytkomposition för användning vid polymerisation av olefiner, kännetecknad av att den innehäller 5 olefinpolymer och ätminstone ett metallocenkomplex med den allmänna formeln I eller II M[XRn]xYp (I) XRn 10. n\ Y„H ZR, p \ / (II) där R är en envärdig eller tvävärdig 1 - 20C-15 hydrokarbylgrupp eller en 1 - 20C-hydrokarbylgrupp som innehäller syre-, kisel-, kväve- eller borsubstituentatomer under förutsättning att ätminstone en grupp R innehäller en polymeriserbar olefingrupp med 3-20 kolatomer och dä ätminstone tvä grupper R är närvarande, kan de vara lika-2 0 dana eller oi ikä, och dä R är tvävärdig, är den fäst di-| rekt tili gruppen M och ersätter en Y-ligand och där ; X är en organisk grupp som innehäller en cyklopen- tadienyl- eller indenylgrupp, :v. M är en metal 1 av grupp IVA, • · • |
25 Y är en envärdig anjonisk ligand och i formeln I • · är • · t ’ n ett heltal 1-10, x är antingen 1 eller 2 och : ·' dä x = 1, p = 0 - 3; 30 däx = 2,p = 0- 2, och • '»it i formeln II är .·*·. n, m och 1 heltal eller 0 sä att n + m + 1 > 1, p =0-2 och • > : Z är en Ci-4-alkylenradikal eller dialkylgermani- ...* 35 um-, eller -kisel- eller alkylfosfin- eller -aminradikal eller bis-dialkylsilyl- eller bis-dialkylgermanylgrupp, 29 112234 som innehaller hydrokarbylgrupper rued 1-4 kolatomer stödda av en oorganisk bärare.
2. Katalytkomposition enligt patentkrav 1, kän-netecknad av att M i den allmänna formeln I eller II är 5 zirkonium.
3. Katalytkomposition enligt patentkrav 1 eller 2, kännetecknad av att den olefiniska gruppen är en vi-nylgrupp.
4. Katalytkomposition enligt patentkrav 1, kän- 10 netecknad av att den oorganiska bäraren är vald bland kiseldioxid, aluminiumoxid och/eller metallhalider av grupp IIA.
5. Katalytkomposition enligt patentkrav 4, kännetecknad av att bäraren är kiseldioxid.
6. Katalytkomposition enligt nägot av föregäende patentkrav, kännetecknad av att den dessutom innehaller en kokatalyt.
7. Katalytkomposition enligt patentkrav 6, kännetecknad av att kokatalyten är en organometallisk fö- 20 rening av grupp IA, IIA, IIB eller IIIB.
8. Katalytkomposition enligt patentkrav 7, kän- . netecknad av att kokatalyten är en organoaluminiumföre- v ning.
: ; 9. Förfarande för framställning av en katalytkom- Γ ; 25 position enligt patentkrav 1, kännetecknat av att ole- finpolymeren och metallocenkomplexet loses i ett inert . ·, lösningsmedel och placeras pä en oorganisk bärare.
10. Katalytkomposition enligt patentkrav 1, kän- . , netecknad av att metallocenkomplexet är bis(3-butenyl- ’ 1 30 cyklopentadienyl)zirkoniumdiklorid.
11. Katalytkomposition enligt patentkrav 1, kännetecknad av att metallocenkomplexet är bis(3-propenyl- : cyklopentadienyl)zirkoniumdiklorid. » 30 112234
12. Förfarande för polymerisation av olefiner, kännetecknat av att atminstone en olefinmonomer bring-as i kontakt med en katalytkomposition enligt nägot av pa-tentkraven. 5
13. Förfarande enligt nägot av patentkraven 12, kännetecknat av att olefinmonomeren är eten.
14. Förfarande enligt nägot av patentkraven 12 el-ler 13, kännetecknat av att polymerisationen utförs i gasfasen. * · a i i · • * • · • · • ♦ • » » » • i * » *
FI933805A 1992-09-04 1993-08-31 Katalytkompositioner och förfarande för framställning av polyolefiner FI112234B (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB929218805A GB9218805D0 (en) 1992-09-04 1992-09-04 Novel metallocene complexes
GB9218805 1992-09-04
GB9305963 1993-03-23
GB939305963A GB9305963D0 (en) 1993-03-23 1993-03-23 Novel metallocene complexes

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FI933805A0 FI933805A0 (fi) 1993-08-31
FI933805A FI933805A (fi) 1994-03-05
FI112234B true FI112234B (sv) 2003-11-14

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US (2) US5714555A (sv)
EP (2) EP0969020A3 (sv)
JP (1) JP3397846B2 (sv)
KR (2) KR100322932B1 (sv)
CN (1) CN1087096A (sv)
AT (1) ATE194630T1 (sv)
CA (1) CA2105015C (sv)
DE (1) DE69328996T2 (sv)
ES (1) ES2148204T3 (sv)
FI (1) FI112234B (sv)
GR (1) GR3034346T3 (sv)
MY (1) MY109833A (sv)
NO (2) NO301332B1 (sv)
PT (1) PT586167E (sv)

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CN1087096A (zh) 1994-05-25
EP0586167A1 (en) 1994-03-09
PT586167E (pt) 2000-12-29
EP0969020A2 (en) 2000-01-05
NO301332B1 (no) 1997-10-13
GR3034346T3 (en) 2000-12-29
CA2105015A1 (en) 1994-03-05
DE69328996D1 (de) 2000-08-17
JP3397846B2 (ja) 2003-04-21
US5714555A (en) 1998-02-03
NO933078D0 (no) 1993-08-30
CA2105015C (en) 2007-04-03
NO972953D0 (no) 1997-06-24
JPH06172415A (ja) 1994-06-21
KR940007063A (ko) 1994-04-26
EP0586167B1 (en) 2000-07-12
KR100322932B1 (ko) 2002-05-13
MY109833A (en) 1997-08-30
EP0969020A3 (en) 2000-01-19
ES2148204T3 (es) 2000-10-16
DE69328996T2 (de) 2000-11-16
FI933805A (fi) 1994-03-05
FI933805A0 (fi) 1993-08-31
NO972953L (no) 1994-03-07
ATE194630T1 (de) 2000-07-15
KR100295941B1 (ko) 2001-07-03
NO933078L (no) 1994-03-07
US5714425A (en) 1998-02-03

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