ES2979233T3 - Sistema de catalizador para la formación de copolímero multibloque - Google Patents

Sistema de catalizador para la formación de copolímero multibloque Download PDF

Info

Publication number
ES2979233T3
ES2979233T3 ES18715390T ES18715390T ES2979233T3 ES 2979233 T3 ES2979233 T3 ES 2979233T3 ES 18715390 T ES18715390 T ES 18715390T ES 18715390 T ES18715390 T ES 18715390T ES 2979233 T3 ES2979233 T3 ES 2979233T3
Authority
ES
Spain
Prior art keywords
hydrocarbyl
independently
atoms
group
rc1s
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES18715390T
Other languages
English (en)
Spanish (es)
Inventor
David D Devore
Daniel J Arriola
Arkady L Krasovskiy
Edmund M Carnahan
Curt N Theriault
Gordon R Roof
Timothy T Wenzel
Jerzy Klosin
Ruth Figueroa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of ES2979233T3 publication Critical patent/ES2979233T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168Tetra- or multi-dentate ligand
    • C08F4/64186Dianionic ligand
    • C08F4/64193OOOO
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
ES18715390T 2017-03-15 2018-03-15 Sistema de catalizador para la formación de copolímero multibloque Active ES2979233T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762471518P 2017-03-15 2017-03-15
PCT/US2018/022554 WO2018170208A1 (en) 2017-03-15 2018-03-15 Catalyst system for multi-block copolymer formation

Publications (1)

Publication Number Publication Date
ES2979233T3 true ES2979233T3 (es) 2024-09-25

Family

ID=61873988

Family Applications (1)

Application Number Title Priority Date Filing Date
ES18715390T Active ES2979233T3 (es) 2017-03-15 2018-03-15 Sistema de catalizador para la formación de copolímero multibloque

Country Status (9)

Country Link
US (1) US20200247936A1 (https=)
EP (1) EP3596138B1 (https=)
JP (1) JP7028885B2 (https=)
KR (1) KR102631009B1 (https=)
CN (1) CN110546171B (https=)
BR (1) BR112019019076A2 (https=)
ES (1) ES2979233T3 (https=)
SG (1) SG11201908307XA (https=)
WO (1) WO2018170208A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7713942B2 (ja) 2019-12-26 2025-07-28 ダウ グローバル テクノロジーズ エルエルシー 優れた加工性を有するポリマー組成物の製造のための方法
WO2021128126A1 (en) * 2019-12-26 2021-07-01 Dow Global Technologies Llc Alpha-olefin interpolymers with improved molecular design for photovoltaic encapsulants
EP4097152B1 (en) * 2020-01-31 2025-09-03 Dow Global Technologies LLC Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents
CA3180275A1 (en) * 2020-05-29 2021-12-02 Rhett A. BAILLIE Catalyst systems and processes for producing polyethylene using the same
CN113880977B (zh) * 2021-10-18 2023-07-11 万华化学集团股份有限公司 一种烯烃聚合催化剂、制备方法与应用
KR20260040442A (ko) 2023-07-20 2026-03-24 다우 글로벌 테크놀로지스 엘엘씨 섬유 혼합물을 포함하는 스펀본드 부직포

Family Cites Families (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
DZ520A1 (fr) 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
US4798081A (en) 1985-11-27 1989-01-17 The Dow Chemical Company High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5608019A (en) 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
FR2705252B1 (fr) 1993-05-19 1995-07-21 Bp Chemicals Snc Procédé d'introduction d'un solide dans un réacteur et appareillage.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5672669A (en) 1993-12-23 1997-09-30 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5543458A (en) 1995-01-31 1996-08-06 Shell Oil Company Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
JP2000517349A (ja) 1996-03-27 2000-12-26 ザ ダウ ケミカル カンパニー 分散した触媒活性剤による溶液重合法
RU2178422C2 (ru) 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
CZ42399A3 (cs) 1996-08-08 1999-07-14 The Dow Chemical Company Kovové komplexy obsahující 3-heteroatom-substituovaný cyklopentadienyl, katalytický systém obsahující tento kovový komplex, způsob polymerace, cyklopentadienylový ligand a použití tohoto ligandu
US6015868A (en) 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
AU726123B2 (en) 1996-12-19 2000-11-02 Dow Chemical Company, The 3-aryl substituted indenyl containing metal complexes and polymerization process
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
CA2204803C (en) 1997-05-08 2005-11-15 Nova Chemicals Ltd. Process to prepare bridged phosphole-cyclopentadienyl compounds
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6319989B1 (en) 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
AR012518A1 (es) 1997-09-19 2000-10-18 Dow Global Technologies Inc Composicion de polimeros que comprende etileno interpolimerizado con al menos un comonomero insaturado, proceso para prepararla y articulo fabricado que la comprende
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
US6827976B2 (en) 1998-04-29 2004-12-07 Unaxis Trading Ag Method to increase wear resistance of a tool or other machine component
EP1178997B1 (en) 1999-05-13 2003-03-05 Dow Global Technologies Inc. Di-and tri-heteroatom substituted indenyl metal complexes
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
ES2379243T3 (es) 1999-12-10 2012-04-24 Dow Global Technologies Llc Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas
CA2411712C (en) 2000-06-30 2011-01-25 Dow Global Technologies Inc. Polycyclic, fused ring compounds, metal complexes and polymerization process
EP1334139A2 (en) 2000-11-07 2003-08-13 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom. processes for producing polyolefins therewith
US6825147B2 (en) 2001-05-14 2004-11-30 Dow Global Technologies Inc. 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US20050010039A1 (en) 2002-03-14 2005-01-13 Graf David D Polycyclic fused heteroring compounds metal complexes and polymerization process
CA2477776C (en) 2002-03-14 2011-11-15 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6897276B2 (en) 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
EP1543014B1 (en) 2002-09-12 2006-10-04 Dow Global Technologies Inc. Preparation of metal complexes
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7858706B2 (en) * 2004-03-17 2010-12-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
NZ549262A (en) * 2004-03-17 2010-08-27 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
SG151310A1 (en) * 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene copolymer formation
US7355089B2 (en) 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
MY148607A (en) 2005-03-17 2013-05-15 Dow Global Technologies Inc Ethylene/?-olefins block interpolymers
MX2007011337A (es) * 2005-03-17 2007-10-02 Dow Global Technologies Inc Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples tactico/atactico.
TWI426089B (zh) 2005-09-15 2014-02-11 Dow Global Technologies Llc 具受控嵌段序列分布之催化烯烴嵌段共聚物
ES2534469T3 (es) 2006-05-17 2015-04-23 Dow Global Technologies Llc Procedimiento de polimerización de polietileno en disolución a alta temperatura
CN101855078B (zh) 2007-07-13 2014-08-27 陶氏环球技术有限责任公司 含有低结晶度硬嵌段的乙烯/α-烯烃互聚物
KR101720353B1 (ko) 2008-08-21 2017-03-27 다우 글로벌 테크놀로지스 엘엘씨 금속-리간드 착체 및 촉매
CN102215952B (zh) 2008-10-06 2014-10-22 陶氏环球技术有限责任公司 聚烯烃聚合物的色谱分析
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
EP3489264B1 (en) 2009-07-29 2021-08-25 Dow Global Technologies LLC Chain shuttling agents and their use for the preparation of block copolymers
US8318896B2 (en) 2009-12-21 2012-11-27 Dow Global Technologies Llc Chromatography of polyolefin polymers
US8822599B2 (en) 2010-06-21 2014-09-02 Dow Global Technologies Llc Crystalline block composites as compatibilizers
US8907034B2 (en) * 2010-09-30 2014-12-09 Dow Global Technologies Llc Comb architecture olefin block copolymers
JP5992036B2 (ja) 2011-06-03 2016-09-14 ダウ グローバル テクノロジーズ エルエルシー ポリマーのクロマトグラフィー
EP2938643B1 (en) 2012-12-27 2018-01-31 Dow Global Technologies LLC Catalyst systems for olefin polymerization
WO2014105413A1 (en) * 2012-12-27 2014-07-03 Dow Global Technologies Llc An ethylene based polymer
CN105339327B (zh) * 2013-06-28 2020-01-21 陶氏环球技术有限责任公司 基于乙烯的超支化寡聚物
CN113201084A (zh) * 2013-06-28 2021-08-03 陶氏环球技术有限责任公司 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量

Also Published As

Publication number Publication date
SG11201908307XA (en) 2019-10-30
BR112019019076A2 (pt) 2020-06-30
JP7028885B2 (ja) 2022-03-02
JP2020511573A (ja) 2020-04-16
US20200247936A1 (en) 2020-08-06
EP3596138B1 (en) 2024-04-03
EP3596138A1 (en) 2020-01-22
CN110546171A (zh) 2019-12-06
WO2018170208A1 (en) 2018-09-20
KR20190126131A (ko) 2019-11-08
KR102631009B1 (ko) 2024-01-30
CN110546171B (zh) 2023-02-28

Similar Documents

Publication Publication Date Title
EP3596141B1 (en) Catalyst system for multi-block copolymer formation
ES2979233T3 (es) Sistema de catalizador para la formación de copolímero multibloque
ES2946762T3 (es) Sistema de catalizador para la formación de copolímero multibloque
ES2558316T3 (es) Control de la arquitectura polimérica y distribución de pesos moleculares por medio de un agente de transporte multicentrado
ES2954446T3 (es) Sistema de catalizador parala formación de copolímero multibloque
JP2023103240A (ja) マルチブロックコポリマー形成用触媒系
ES2951157T3 (es) Catalizadores de bis-fenil fenoxi poliolefina que tienen un ligando alcoxi o amido en el metal para obtener una solubilidad mejorada
BR112019018888B1 (pt) Sistema catalisador de polimerização de olefina e processo para a preparação de um copolímero de múltiplos blocos
BR112019019129B1 (pt) Sistema catalisador de polimerização de olefina e processo para preparar um copolímero de múltiplos blocos
BR112019019065B1 (pt) Sistema catalisador de polimerização de olefina