ES2736852T3 - Sistema de electrólisis para la utilización electroquímica de dióxido de carbono con unidad donadora de protones y procedimiento de reducción - Google Patents
Sistema de electrólisis para la utilización electroquímica de dióxido de carbono con unidad donadora de protones y procedimiento de reducción Download PDFInfo
- Publication number
- ES2736852T3 ES2736852T3 ES16724025T ES16724025T ES2736852T3 ES 2736852 T3 ES2736852 T3 ES 2736852T3 ES 16724025 T ES16724025 T ES 16724025T ES 16724025 T ES16724025 T ES 16724025T ES 2736852 T3 ES2736852 T3 ES 2736852T3
- Authority
- ES
- Spain
- Prior art keywords
- cathode
- carbon dioxide
- proton
- membrane
- space
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 239
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 133
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 131
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims description 22
- 230000009467 reduction Effects 0.000 title claims description 19
- 239000012528 membrane Substances 0.000 claims abstract description 119
- -1 polytetrafluoroethylene Polymers 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- 238000011946 reduction process Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000007848 Bronsted acid Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 230000007423 decrease Effects 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 40
- 238000006243 chemical reaction Methods 0.000 description 28
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 25
- 239000007789 gas Substances 0.000 description 23
- 239000000126 substance Substances 0.000 description 21
- 239000000047 product Substances 0.000 description 18
- 239000000243 solution Substances 0.000 description 15
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 14
- 238000009792 diffusion process Methods 0.000 description 14
- 230000002378 acidificating effect Effects 0.000 description 12
- 239000012071 phase Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 150000001768 cations Chemical class 0.000 description 8
- 239000005518 polymer electrolyte Substances 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 229910001868 water Inorganic materials 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 125000000542 sulfonic acid group Chemical group 0.000 description 5
- 229920000557 Nafion® Polymers 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 239000011736 potassium bicarbonate Substances 0.000 description 4
- 235000015497 potassium bicarbonate Nutrition 0.000 description 4
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 4
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QUWBSOKSBWAQER-UHFFFAOYSA-N [C].O=C=O Chemical compound [C].O=C=O QUWBSOKSBWAQER-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229910052730 francium Inorganic materials 0.000 description 1
- KLMCZVJOEAUDNE-UHFFFAOYSA-N francium atom Chemical compound [Fr] KLMCZVJOEAUDNE-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102015209509.6A DE102015209509A1 (de) | 2015-05-22 | 2015-05-22 | Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung mit Protonenspender-Einheit und Reduktionsverfahren |
| PCT/EP2016/061177 WO2016188829A1 (de) | 2015-05-22 | 2016-05-19 | Elektrolysesystem zur elektrochemischen kohlenstoffdioxid-verwertung mit protonenspender-einheit und reduktionsverfahren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2736852T3 true ES2736852T3 (es) | 2020-01-08 |
Family
ID=56026862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES16724025T Active ES2736852T3 (es) | 2015-05-22 | 2016-05-19 | Sistema de electrólisis para la utilización electroquímica de dióxido de carbono con unidad donadora de protones y procedimiento de reducción |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20180127885A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3280834B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6590951B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN107849714B (cg-RX-API-DMAC7.html) |
| DE (1) | DE102015209509A1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK3280834T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2736852T3 (cg-RX-API-DMAC7.html) |
| PL (1) | PL3280834T3 (cg-RX-API-DMAC7.html) |
| RU (1) | RU2685421C1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2016188829A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6672193B2 (ja) * | 2017-02-02 | 2020-03-25 | 株式会社東芝 | 二酸化炭素の電解セルと電解装置 |
| JP6696696B2 (ja) * | 2017-03-21 | 2020-05-20 | 株式会社東芝 | 電気化学反応装置 |
| DE102017213471A1 (de) * | 2017-08-03 | 2019-02-07 | Siemens Aktiengesellschaft | Vorrichtung und Verfahren zur elektrochemischen Nutzung von Kohlenstoffdioxid |
| JP7273929B2 (ja) * | 2017-09-20 | 2023-05-15 | 株式会社東芝 | 電気化学反応装置および多孔質セパレータ |
| JP2019056136A (ja) * | 2017-09-20 | 2019-04-11 | 株式会社東芝 | 電気化学反応装置 |
| DE102018212409A1 (de) | 2017-11-16 | 2019-05-16 | Siemens Aktiengesellschaft | Kohlenwasserstoff-selektive Elektrode |
| JP6822998B2 (ja) * | 2018-03-20 | 2021-01-27 | 株式会社東芝 | 電気化学反応装置 |
| JP6783815B2 (ja) * | 2018-03-22 | 2020-11-11 | 株式会社東芝 | 酸化電極とそれを用いた電気化学反応装置 |
| WO2019204938A1 (en) * | 2018-04-25 | 2019-10-31 | The University Of British Columbia | Systems and methods for electrochemical generation of syngas and other useful chemicals |
| DE102018208624A1 (de) | 2018-05-30 | 2019-12-05 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Verfahren und Vorrichtung zum Bereitstellen von wenigstens einem Produktstrom durch Elektrolyse sowie Verwendung |
| DE102018210303A1 (de) * | 2018-06-25 | 2020-01-02 | Siemens Aktiengesellschaft | Elektrochemische Niedertemperatur Reverse-Watergas-Shift Reaktion |
| CN113795611A (zh) * | 2019-05-05 | 2021-12-14 | 多伦多大学管理委员会 | 在电解池中碳酸盐转化为合成气或c2+产物 |
| CN110760876A (zh) * | 2019-08-19 | 2020-02-07 | 天津大学 | 一种用于高效合成h2o2的三室反应器装置 |
| CN110923736A (zh) * | 2019-10-23 | 2020-03-27 | 安徽中研理工仪器设备有限公司 | 一种光电催化化学反应电解池装置 |
| CN112973398B (zh) * | 2019-12-13 | 2022-05-10 | 中国科学院大连化学物理研究所 | 一种带有剩余离子的电极在co2电化学还原反应中的应用 |
| EP4084889A4 (en) * | 2019-12-30 | 2025-05-14 | USA Fortescue IP, Inc. | ENVIRONMENTAL CONTROL SYSTEM USING AN ANION-CONDUCTING MEMBRANE |
| WO2021222463A1 (en) * | 2020-04-29 | 2021-11-04 | C2Cnt Llc | System, method and composition for making thin-walled carbon nanomaterials |
| JP7356067B2 (ja) * | 2020-05-11 | 2023-10-04 | 日本電信電話株式会社 | 二酸化炭素の気相還元装置、および、二酸化炭素の気相還元方法 |
| JP2023089321A (ja) * | 2020-05-15 | 2023-06-28 | パナソニックＩｐマネジメント株式会社 | レドックスフロー電池 |
| CN114452822A (zh) * | 2020-11-09 | 2022-05-10 | 鼎佳能源股份有限公司 | 二氧化碳回收产生一氧化碳再利用系统 |
| GB2604047B (en) * | 2022-03-24 | 2023-04-05 | Kratos Energy Ltd | Electrolyser |
| CN116072989B (zh) * | 2023-02-13 | 2025-04-04 | 烟台大学 | 一种添加固体酸的锰基氧化物正极水系可充锌锰电池 |
| CN118223052B (zh) * | 2024-03-27 | 2024-11-19 | 清华大学 | 具有多相流直接生成功能的二氧化碳电还原反应装置 |
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| JPH04314881A (ja) * | 1991-03-29 | 1992-11-06 | Mitsubishi Electric Corp | 電解装置 |
| JP2001192875A (ja) * | 2000-01-05 | 2001-07-17 | Kurita Water Ind Ltd | 過酸化水素の製造方法及び装置 |
| CN101250711B (zh) * | 2008-03-27 | 2010-11-10 | 昆明理工大学 | 二氧化碳在离子液体中的电化学还原方法和装置 |
| FR2931168B1 (fr) * | 2008-05-15 | 2010-07-30 | Areva | Procede de production de composes du type cxhyoz par reduction de dioxyde de carbone (co2) et/ou de monoxyde de carbone (co) |
| JP5361325B2 (ja) * | 2008-10-17 | 2013-12-04 | 有限会社スプリング | 溶存水素飲料水の製造装置及びその製造方法 |
| WO2012011209A1 (ja) * | 2010-07-23 | 2012-01-26 | パナソニック株式会社 | 二酸化炭素を還元する方法 |
| CA3048786C (en) * | 2010-09-24 | 2020-11-03 | Dnv Gl As | Method and apparatus for the electrochemical reduction of carbon dioxide |
| US9011650B2 (en) * | 2010-10-08 | 2015-04-21 | Ceramatec, Inc | Electrochemical systems and methods for operating an electrochemical cell with an acidic anolyte |
| WO2012128148A1 (ja) * | 2011-03-18 | 2012-09-27 | 国立大学法人長岡技術科学大学 | 二酸化炭素の還元固定化システム、二酸化炭素の還元固定化方法、及び有用炭素資源の製造方法 |
| CN103160849B (zh) * | 2011-12-12 | 2016-06-08 | 清华大学 | 二氧化碳电化学还原转化利用的方法 |
| WO2013178803A1 (de) * | 2012-05-31 | 2013-12-05 | Hettich Holding Gmbh & Co. Ohg | Verfahren und vorrichtung zur elektrolytischen synthese von methanol und/oder methan |
| US9175407B2 (en) * | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
| US20130105304A1 (en) * | 2012-07-26 | 2013-05-02 | Liquid Light, Inc. | System and High Surface Area Electrodes for the Electrochemical Reduction of Carbon Dioxide |
| WO2014047661A2 (en) * | 2012-09-24 | 2014-03-27 | Dioxide Materials, Inc. | Devices and processes for carbon dioxide conversion into useful fuels and chemicals |
| JP2014227563A (ja) * | 2013-05-21 | 2014-12-08 | パナソニック株式会社 | 二酸化炭素還元用光化学電極、二酸化炭素還元装置、及び二酸化炭素の還元方法 |
| DE102013226357A1 (de) * | 2013-12-18 | 2015-06-18 | Siemens Aktiengesellschaft | Pulsierende Elektrolytzufuhr in den Reaktionsraum einer Elektrolysezelle mit gasentwickelnden Elektroden |
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2015
- 2015-05-22 DE DE102015209509.6A patent/DE102015209509A1/de not_active Withdrawn
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2016
- 2016-05-19 EP EP16724025.8A patent/EP3280834B1/de not_active Not-in-force
- 2016-05-19 CN CN201680042291.8A patent/CN107849714B/zh not_active Expired - Fee Related
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- 2016-05-19 WO PCT/EP2016/061177 patent/WO2016188829A1/de not_active Ceased
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| DE102015209509A1 (de) | 2016-11-24 |
| RU2685421C1 (ru) | 2019-04-18 |
| PL3280834T3 (pl) | 2019-10-31 |
| DK3280834T3 (da) | 2019-07-08 |
| JP2018519418A (ja) | 2018-07-19 |
| CN107849714A (zh) | 2018-03-27 |
| CN107849714B (zh) | 2020-07-10 |
| WO2016188829A1 (de) | 2016-12-01 |
| EP3280834B1 (de) | 2019-04-17 |
| US20180127885A1 (en) | 2018-05-10 |
| JP6590951B2 (ja) | 2019-10-16 |
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