JP6590951B2 - 二酸化炭素の電気化学的有効利用のためのプロトン供与体ユニットを有する電解システム及び還元方法 - Google Patents
二酸化炭素の電気化学的有効利用のためのプロトン供与体ユニットを有する電解システム及び還元方法 Download PDFInfo
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- JP6590951B2 JP6590951B2 JP2017560988A JP2017560988A JP6590951B2 JP 6590951 B2 JP6590951 B2 JP 6590951B2 JP 2017560988 A JP2017560988 A JP 2017560988A JP 2017560988 A JP2017560988 A JP 2017560988A JP 6590951 B2 JP6590951 B2 JP 6590951B2
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- cathode
- proton
- carbon dioxide
- catholyte
- membrane
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 250
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 125
- 239000001569 carbon dioxide Substances 0.000 title claims description 124
- 230000009467 reduction Effects 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 31
- 239000012528 membrane Substances 0.000 claims description 103
- 238000005868 electrolysis reaction Methods 0.000 claims description 45
- -1 polytetrafluoroethylene Polymers 0.000 claims description 28
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 230000005501 phase interface Effects 0.000 claims description 9
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 44
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000007789 gas Substances 0.000 description 23
- 239000000047 product Substances 0.000 description 19
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- 238000009792 diffusion process Methods 0.000 description 14
- 230000002378 acidificating effect Effects 0.000 description 11
- 238000010586 diagram Methods 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 239000005518 polymer electrolyte Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000007848 Bronsted acid Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 5
- 239000011736 potassium bicarbonate Substances 0.000 description 5
- 235000015497 potassium bicarbonate Nutrition 0.000 description 5
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 5
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229920000557 Nafion® Polymers 0.000 description 4
- 229910001413 alkali metal ion Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 229960003975 potassium Drugs 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- 239000006181 electrochemical material Substances 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229910052730 francium Inorganic materials 0.000 description 1
- KLMCZVJOEAUDNE-UHFFFAOYSA-N francium atom Chemical compound [Fr] KLMCZVJOEAUDNE-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- VFWRGKJLLYDFBY-UHFFFAOYSA-N silver;hydrate Chemical compound O.[Ag].[Ag] VFWRGKJLLYDFBY-UHFFFAOYSA-N 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102015209509.6A DE102015209509A1 (de) | 2015-05-22 | 2015-05-22 | Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung mit Protonenspender-Einheit und Reduktionsverfahren |
| DE102015209509.6 | 2015-05-22 | ||
| PCT/EP2016/061177 WO2016188829A1 (de) | 2015-05-22 | 2016-05-19 | Elektrolysesystem zur elektrochemischen kohlenstoffdioxid-verwertung mit protonenspender-einheit und reduktionsverfahren |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018519418A JP2018519418A (ja) | 2018-07-19 |
| JP2018519418A5 JP2018519418A5 (cg-RX-API-DMAC7.html) | 2018-08-30 |
| JP6590951B2 true JP6590951B2 (ja) | 2019-10-16 |
Family
ID=56026862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017560988A Expired - Fee Related JP6590951B2 (ja) | 2015-05-22 | 2016-05-19 | 二酸化炭素の電気化学的有効利用のためのプロトン供与体ユニットを有する電解システム及び還元方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20180127885A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3280834B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6590951B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN107849714B (cg-RX-API-DMAC7.html) |
| DE (1) | DE102015209509A1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK3280834T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2736852T3 (cg-RX-API-DMAC7.html) |
| PL (1) | PL3280834T3 (cg-RX-API-DMAC7.html) |
| RU (1) | RU2685421C1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2016188829A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6672193B2 (ja) * | 2017-02-02 | 2020-03-25 | 株式会社東芝 | 二酸化炭素の電解セルと電解装置 |
| JP6696696B2 (ja) | 2017-03-21 | 2020-05-20 | 株式会社東芝 | 電気化学反応装置 |
| DE102017213471A1 (de) * | 2017-08-03 | 2019-02-07 | Siemens Aktiengesellschaft | Vorrichtung und Verfahren zur elektrochemischen Nutzung von Kohlenstoffdioxid |
| JP2019056136A (ja) * | 2017-09-20 | 2019-04-11 | 株式会社東芝 | 電気化学反応装置 |
| JP7273929B2 (ja) * | 2017-09-20 | 2023-05-15 | 株式会社東芝 | 電気化学反応装置および多孔質セパレータ |
| DE102018212409A1 (de) | 2017-11-16 | 2019-05-16 | Siemens Aktiengesellschaft | Kohlenwasserstoff-selektive Elektrode |
| JP6822998B2 (ja) * | 2018-03-20 | 2021-01-27 | 株式会社東芝 | 電気化学反応装置 |
| JP6783815B2 (ja) * | 2018-03-22 | 2020-11-11 | 株式会社東芝 | 酸化電極とそれを用いた電気化学反応装置 |
| US12006580B2 (en) * | 2018-04-25 | 2024-06-11 | The University Of British Columbia | Systems and methods for electrochemical generation of syngas and other useful chemicals |
| DE102018208624A1 (de) | 2018-05-30 | 2019-12-05 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Verfahren und Vorrichtung zum Bereitstellen von wenigstens einem Produktstrom durch Elektrolyse sowie Verwendung |
| DE102018210303A1 (de) * | 2018-06-25 | 2020-01-02 | Siemens Aktiengesellschaft | Elektrochemische Niedertemperatur Reverse-Watergas-Shift Reaktion |
| WO2020223804A1 (en) * | 2019-05-05 | 2020-11-12 | The Governing Council Of The University Of Toronto | Conversion of carbonate into syngas or c2+ products in electrolysis cell |
| CN110760876A (zh) * | 2019-08-19 | 2020-02-07 | 天津大学 | 一种用于高效合成h2o2的三室反应器装置 |
| CN110923736A (zh) * | 2019-10-23 | 2020-03-27 | 安徽中研理工仪器设备有限公司 | 一种光电催化化学反应电解池装置 |
| CN112973398B (zh) * | 2019-12-13 | 2022-05-10 | 中国科学院大连化学物理研究所 | 一种带有剩余离子的电极在co2电化学还原反应中的应用 |
| WO2021138425A1 (en) * | 2019-12-30 | 2021-07-08 | Xergy Inc. | Environmental control system utilizing an anion conducting mambrane |
| CN115605633B (zh) * | 2020-04-29 | 2023-12-29 | C2Cnt有限责任公司 | 用于制备薄壁碳纳米材料的系统、方法和组合物 |
| JP7356067B2 (ja) * | 2020-05-11 | 2023-10-04 | 日本電信電話株式会社 | 二酸化炭素の気相還元装置、および、二酸化炭素の気相還元方法 |
| JP2023089321A (ja) * | 2020-05-15 | 2023-06-28 | パナソニックＩｐマネジメント株式会社 | レドックスフロー電池 |
| CN114452822A (zh) * | 2020-11-09 | 2022-05-10 | 鼎佳能源股份有限公司 | 二氧化碳回收产生一氧化碳再利用系统 |
| GB2604047B (en) * | 2022-03-24 | 2023-04-05 | Kratos Energy Ltd | Electrolyser |
| CN116072989B (zh) * | 2023-02-13 | 2025-04-04 | 烟台大学 | 一种添加固体酸的锰基氧化物正极水系可充锌锰电池 |
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| JPH04314881A (ja) * | 1991-03-29 | 1992-11-06 | Mitsubishi Electric Corp | 電解装置 |
| JP2001192875A (ja) * | 2000-01-05 | 2001-07-17 | Kurita Water Ind Ltd | 過酸化水素の製造方法及び装置 |
| CN101250711B (zh) * | 2008-03-27 | 2010-11-10 | 昆明理工大学 | 二氧化碳在离子液体中的电化学还原方法和装置 |
| FR2931168B1 (fr) * | 2008-05-15 | 2010-07-30 | Areva | Procede de production de composes du type cxhyoz par reduction de dioxyde de carbone (co2) et/ou de monoxyde de carbone (co) |
| JP5361325B2 (ja) * | 2008-10-17 | 2013-12-04 | 有限会社スプリング | 溶存水素飲料水の製造装置及びその製造方法 |
| CN102686781A (zh) * | 2010-07-23 | 2012-09-19 | 松下电器产业株式会社 | 还原二氧化碳的方法 |
| CA3048786C (en) * | 2010-09-24 | 2020-11-03 | Dnv Gl As | Method and apparatus for the electrochemical reduction of carbon dioxide |
| WO2012048280A2 (en) * | 2010-10-08 | 2012-04-12 | Ceramatec, Inc. | Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte |
| WO2012128148A1 (ja) * | 2011-03-18 | 2012-09-27 | 国立大学法人長岡技術科学大学 | 二酸化炭素の還元固定化システム、二酸化炭素の還元固定化方法、及び有用炭素資源の製造方法 |
| CN103160849B (zh) * | 2011-12-12 | 2016-06-08 | 清华大学 | 二氧化碳电化学还原转化利用的方法 |
| WO2013178803A1 (de) * | 2012-05-31 | 2013-12-05 | Hettich Holding Gmbh & Co. Ohg | Verfahren und vorrichtung zur elektrolytischen synthese von methanol und/oder methan |
| US9175407B2 (en) * | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
| US20130105304A1 (en) * | 2012-07-26 | 2013-05-02 | Liquid Light, Inc. | System and High Surface Area Electrodes for the Electrochemical Reduction of Carbon Dioxide |
| CN104822861B (zh) * | 2012-09-24 | 2017-03-08 | 二氧化碳材料公司 | 用于将二氧化碳转化为有用燃料和化学品的装置和方法 |
| JP2014227563A (ja) * | 2013-05-21 | 2014-12-08 | パナソニック株式会社 | 二酸化炭素還元用光化学電極、二酸化炭素還元装置、及び二酸化炭素の還元方法 |
| DE102013226357A1 (de) * | 2013-12-18 | 2015-06-18 | Siemens Aktiengesellschaft | Pulsierende Elektrolytzufuhr in den Reaktionsraum einer Elektrolysezelle mit gasentwickelnden Elektroden |
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| RU2685421C1 (ru) | 2019-04-18 |
| US20180127885A1 (en) | 2018-05-10 |
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| CN107849714A (zh) | 2018-03-27 |
| DK3280834T3 (da) | 2019-07-08 |
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| JP2018519418A (ja) | 2018-07-19 |
| PL3280834T3 (pl) | 2019-10-31 |
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