ES2728360T3 - Aglutinantes de látex útiles en composiciones de recubrimiento con bajo contenido de VOC o contenido cero - Google Patents
Aglutinantes de látex útiles en composiciones de recubrimiento con bajo contenido de VOC o contenido cero Download PDFInfo
- Publication number
- ES2728360T3 ES2728360T3 ES17175036T ES17175036T ES2728360T3 ES 2728360 T3 ES2728360 T3 ES 2728360T3 ES 17175036 T ES17175036 T ES 17175036T ES 17175036 T ES17175036 T ES 17175036T ES 2728360 T3 ES2728360 T3 ES 2728360T3
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- Spain
- Prior art keywords
- structural formula
- polyalkylene glycol
- polymerizable
- monomer
- glycol monomer
- Prior art date
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- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- ZEYMDLYHRCTNEE-UHFFFAOYSA-N ethenyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OC=C ZEYMDLYHRCTNEE-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002238 fumaric acids Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920001480 hydrophilic copolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- QHFVMEAWBQPKBP-UHFFFAOYSA-N n-[(carbamoylamino)methyl]-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCNC(N)=O QHFVMEAWBQPKBP-UHFFFAOYSA-N 0.000 description 1
- NOEQXGATUUVXRW-UHFFFAOYSA-N n-butan-2-ylprop-2-enamide Chemical compound CCC(C)NC(=O)C=C NOEQXGATUUVXRW-UHFFFAOYSA-N 0.000 description 1
- CZGXZAVXMRSVLV-UHFFFAOYSA-N n-carbamoyl-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NC(N)=O CZGXZAVXMRSVLV-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical group NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- HSYFJDYGOJKZCL-UHFFFAOYSA-L zinc;sulfite Chemical compound [Zn+2].[O-]S([O-])=O HSYFJDYGOJKZCL-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261597452P | 2012-02-10 | 2012-02-10 |
Publications (1)
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|---|---|
| ES2728360T3 true ES2728360T3 (es) | 2019-10-23 |
Family
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| ES13746192.7T Active ES2646778T3 (es) | 2012-02-10 | 2013-02-05 | Aglutinantes de látex útiles en composiciones de recubrimiento con bajo contenido de VOC o contenido cero |
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| CN (2) | CN107099212B (enExample) |
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| CA (1) | CA2863918C (enExample) |
| ES (2) | ES2728360T3 (enExample) |
| MX (1) | MX352167B (enExample) |
| WO (1) | WO2013119521A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112014019655A8 (pt) * | 2012-02-10 | 2017-07-11 | Arkema Inc | Polímeros de emulsão de multifases para composições de revestimento aquoso contendo pouco ou nenhum solvente orgânico |
| FR3030525B1 (fr) * | 2014-12-18 | 2018-05-11 | Arkema France | Polymerisation radicalaire d'alcoxyamines a basse temperature |
| BR112017013392B1 (pt) * | 2014-12-22 | 2022-04-26 | Dow Global Technologies Llc | Composição aquosa para substratos de revestimento, material de revestimento pigmentado, e, método de fazer uma composição para substratos de revestimento |
| BR112017016660B1 (pt) | 2015-02-04 | 2022-01-18 | Ahlstrom-Munksjö Dettingen Gmbh | Papel de base decorativa pré-impregnado para materiais de revestimento decorativo, método para produção do mesmo e material de revestimento decorativo |
| CN105332317A (zh) * | 2015-10-27 | 2016-02-17 | 福建圣莉雅环保壁纸有限公司 | 含衣康酸的浆料及其在壁纸中的应用 |
| CA2948956A1 (en) | 2015-12-15 | 2017-06-15 | Rohm And Haas Company | Phenyl glycidyl ether adduct of maltodextrin |
| CA2948965A1 (en) | 2015-12-17 | 2017-06-17 | Dow Global Technologies Llc | Di- or tristyrylphenol monogycidyl ether adduct of maltodextrin |
| BR112018068289A2 (pt) | 2016-03-11 | 2019-01-15 | Dow Global Technologies Llc | composição de revestimento. |
| US10752793B2 (en) | 2016-03-28 | 2020-08-25 | Dow Global Technologies Llc | Compositions, aqueous coating compositions, and methods for improving the freeze/thaw stability of aqueous coating compositions |
| BR112018075197B1 (pt) | 2016-07-05 | 2022-07-12 | Dow Global Technologies Llc | Composição, e, tinta látex |
| BR112019007744B1 (pt) | 2016-11-11 | 2022-12-06 | Rohm And Haas Company | Composição de revestimento aquosa, e, métodos de preparação da composição de revestimento aquosa e de concessão de estabilidade de congelamento e descongelamento a um polímero de emulsão acrílica |
| KR102351529B1 (ko) | 2017-07-31 | 2022-01-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 수성 중합체 분산액 |
| BR112020001307A2 (pt) | 2017-07-31 | 2020-07-28 | Dow Global Technologies Llc | composição aquosa de revestimento, e, método para melhorar o efeito de perolização de um substrato. |
| BR112020018258A2 (pt) | 2018-04-12 | 2020-12-29 | Dow Global Technologies Llc | Composição aquosa de revestimento, e, processo para preparar uma composição aquosa de revestimento. |
| CN110713572B (zh) * | 2018-07-11 | 2022-07-22 | 广东华润涂料有限公司 | 一种包含丙烯酸类共聚物的高固低粘的树脂组合物 |
| AU2019100711A4 (en) | 2018-12-25 | 2019-08-22 | Ptt Global Chemical Public Company Limited | Solvent as an open time/wet edge time extenders and anti-skinning/freeze thaw stability |
| CA3128263A1 (en) | 2019-01-29 | 2020-08-06 | Dow Global Technologies Llc | Aqueous coating composition |
| US12129399B2 (en) | 2019-04-16 | 2024-10-29 | Dow Global Technologies Llc | Freeze thaw additive composition |
| CN111116838A (zh) * | 2019-12-30 | 2020-05-08 | 广东银洋环保新材料有限公司 | 一种冻融稳定性优异的丙烯酸酯乳液及其制备方法 |
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| US5399617A (en) | 1990-06-13 | 1995-03-21 | National Starch And Chemical Investment Holding Corporation | Thermoplastic, aqueous latex paints having improved wet adhesion and freeze-thaw stability |
| US5064888A (en) | 1990-06-13 | 1991-11-12 | National Starch And Chemical Investment Holding Corporation | Amphoteric surfactants and copolymerizable amphoteric surfactants for use in latex paints |
| JPH05301933A (ja) * | 1992-04-27 | 1993-11-16 | Japan Synthetic Rubber Co Ltd | 共重合体ラテックス |
| US5610225A (en) | 1995-05-03 | 1997-03-11 | National Starch And Chemical Investment Holding Corporation | Latex paints which are free of volatile coalescents and freeze-thaw additives |
| US5530056A (en) | 1995-05-03 | 1996-06-25 | National Starch And Chemical Investment Holding Corporation | latex binders and paints which are free of volatile coalescents and freeze-thaw additives |
| US5618876A (en) | 1995-06-05 | 1997-04-08 | National Starch And Chemical Investment Holding Corporation | Latex binders and coatings containing polymers derived from polymerizable saccharide monomers |
| US6124397A (en) | 1998-02-24 | 2000-09-26 | Air Products And Chemicals, Inc. | Vinyl acetate copolymer emulsions stabilized by poly(ethylene glycol)-diepoxide adducts |
| JP3320698B2 (ja) | 1999-12-09 | 2002-09-03 | 大日本塗料株式会社 | 水性塗料組成物 |
| US6933415B2 (en) | 2002-06-06 | 2005-08-23 | Basf Ag | Low-VOC aqueous coating compositions with excellent freeze-thaw stability |
| US7402627B2 (en) * | 2003-08-18 | 2008-07-22 | Columbia Insurance Company | Precursor colorant composition for latex paint |
| US7612126B2 (en) | 2003-12-04 | 2009-11-03 | Basf Aktiengesellschaft | Low-VOC aqueous coating compositions with excellent freeze-thaw stability |
| US7086187B2 (en) | 2004-11-03 | 2006-08-08 | Husam Yousef Bandak | Advertising display system and method |
| MXPA06011748A (es) | 2005-01-05 | 2007-03-01 | Basf Ag | Composiciones de recubrimiento de polimero en emulsion con bajo contenido de voc. |
| US7705082B2 (en) | 2005-04-22 | 2010-04-27 | Basf Se | Low-VOC emulsion polymer coating compositions |
| WO2008002495A2 (en) | 2006-06-23 | 2008-01-03 | The Sherwin-Williams Company | High solids emulsions |
| WO2009065867A1 (de) | 2007-11-19 | 2009-05-28 | Basf Se | Verwendung hochverzweigter polymere zur herstellung von polymerdispersionen mit verbesserter gefrier-/tau-stabilität |
| US9388323B2 (en) | 2008-01-18 | 2016-07-12 | Rhodia Operations | Latex binders, aqueous coatings and paints having freeze-thaw ability and methods for using same |
| AU2009205657B2 (en) | 2008-01-18 | 2014-05-22 | Rhodia Operations | Latex binders, aqueous coatings and paints having freeze-thaw stability and methods for using same |
| US8980993B2 (en) * | 2008-07-10 | 2015-03-17 | Arkema Inc. | Coating compositions for improved block resistance |
| WO2011095444A1 (de) * | 2010-02-03 | 2011-08-11 | Basf Se | Assoziativverdicker aus säuremonomer, assoziativmonomer und nichtionischem monomer |
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- 2013-02-05 EP EP13746192.7A patent/EP2825575B1/en active Active
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Also Published As
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| MX352167B (es) | 2017-11-13 |
| EP2825575A4 (en) | 2016-04-13 |
| US9834698B2 (en) | 2017-12-05 |
| MX2014009586A (es) | 2014-09-12 |
| EP2825575A1 (en) | 2015-01-21 |
| US20150073080A1 (en) | 2015-03-12 |
| ES2646778T3 (es) | 2017-12-15 |
| BR112014019535A8 (pt) | 2017-07-11 |
| CN104105727B (zh) | 2017-06-06 |
| CA2863918A1 (en) | 2013-08-15 |
| BR112014019535A2 (enExample) | 2017-06-20 |
| EP3231827B1 (en) | 2019-03-27 |
| EP3231827A1 (en) | 2017-10-18 |
| CN104105727A (zh) | 2014-10-15 |
| EP2825575B1 (en) | 2017-08-09 |
| CN107099212B (zh) | 2019-11-22 |
| CA2863918C (en) | 2019-02-26 |
| CN107099212A (zh) | 2017-08-29 |
| WO2013119521A1 (en) | 2013-08-15 |
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