CN107099212B - 在零或低voc涂料组合物中有用的胶乳粘合剂 - Google Patents
在零或低voc涂料组合物中有用的胶乳粘合剂 Download PDFInfo
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- CN107099212B CN107099212B CN201710338684.XA CN201710338684A CN107099212B CN 107099212 B CN107099212 B CN 107099212B CN 201710338684 A CN201710338684 A CN 201710338684A CN 107099212 B CN107099212 B CN 107099212B
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- structure formula
- latex adhesive
- iii
- polyalkylene glycol
- glycol mono
- Prior art date
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- 239000004816 latex Substances 0.000 title claims abstract description 90
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- 239000000178 monomer Substances 0.000 claims description 95
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- -1 alkyl diester Chemical class 0.000 claims description 32
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 23
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 22
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- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 14
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- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
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- 229940028617 conventional vaccine Drugs 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
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- 239000006260 foam Substances 0.000 description 1
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- 229920000140 heteropolymer Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
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- 230000002427 irreversible effect Effects 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
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- 235000019792 magnesium silicate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- QENDLNJWYIFMIM-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-n-methylprop-2-enamide Chemical compound CN(C)CCCN(C)C(=O)C=C QENDLNJWYIFMIM-UHFFFAOYSA-N 0.000 description 1
- NSSJZLJAIGHPRT-UHFFFAOYSA-N n-carbamoylbut-2-enamide Chemical compound CC=CC(=O)NC(N)=O NSSJZLJAIGHPRT-UHFFFAOYSA-N 0.000 description 1
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- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- VPJDULFXCAQHRC-UHFFFAOYSA-N prop-2-enylurea Chemical compound NC(=O)NCC=C VPJDULFXCAQHRC-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical class [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
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- 125000005504 styryl group Chemical group 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
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|---|---|---|---|
| US201261597452P | 2012-02-10 | 2012-02-10 | |
| US61/597,452 | 2012-02-10 | ||
| CN201380008759.8A CN104105727B (zh) | 2012-02-10 | 2013-02-05 | 在零或低voc涂料组合物中有用的胶乳粘合剂 |
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| CN201380008759.8A Division CN104105727B (zh) | 2012-02-10 | 2013-02-05 | 在零或低voc涂料组合物中有用的胶乳粘合剂 |
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| CN107099212A CN107099212A (zh) | 2017-08-29 |
| CN107099212B true CN107099212B (zh) | 2019-11-22 |
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| CN201380008759.8A Active CN104105727B (zh) | 2012-02-10 | 2013-02-05 | 在零或低voc涂料组合物中有用的胶乳粘合剂 |
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|---|---|
| US (1) | US9834698B2 (enExample) |
| EP (2) | EP3231827B1 (enExample) |
| CN (2) | CN107099212B (enExample) |
| BR (1) | BR112014019535A8 (enExample) |
| CA (1) | CA2863918C (enExample) |
| ES (2) | ES2728360T3 (enExample) |
| MX (1) | MX352167B (enExample) |
| WO (1) | WO2013119521A1 (enExample) |
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| CN104105550B (zh) * | 2012-02-10 | 2017-04-05 | 阿科玛股份有限公司 | 用于包含很少或不含有机溶剂的水性涂料组合物的多相乳液聚合物 |
| FR3030525B1 (fr) * | 2014-12-18 | 2018-05-11 | Arkema France | Polymerisation radicalaire d'alcoxyamines a basse temperature |
| WO2016101105A1 (en) | 2014-12-22 | 2016-06-30 | Dow Global Technologies Llc | Aqueous emulsion paint with improved stain removal and anticlogging properties |
| RU2677150C1 (ru) | 2015-02-04 | 2019-01-15 | Альстром-Мунксьё Деттинген Гмбх | Композиция и способ получения предварительно пропитанной декоративной бумаги-основы, содержащей биополимерные наночастицы |
| CN105332317A (zh) * | 2015-10-27 | 2016-02-17 | 福建圣莉雅环保壁纸有限公司 | 含衣康酸的浆料及其在壁纸中的应用 |
| CA2948956A1 (en) | 2015-12-15 | 2017-06-15 | Rohm And Haas Company | Phenyl glycidyl ether adduct of maltodextrin |
| CA2948965A1 (en) | 2015-12-17 | 2017-06-17 | Dow Global Technologies Llc | Di- or tristyrylphenol monogycidyl ether adduct of maltodextrin |
| WO2017155845A1 (en) | 2016-03-11 | 2017-09-14 | Dow Global Technologies Llc | Coating formulation with an open time additive |
| CA3018968A1 (en) | 2016-03-28 | 2017-10-05 | Dow Global Technologies Llc | Compositions, aqueous coating compositions, and methods for improving the freeze/thaw stability of aqueous coating compositions |
| US10654964B2 (en) | 2016-07-05 | 2020-05-19 | Dow Global Technologies Llc | Compositions comprising polyether-urethane-urea additives for block resistance and open time |
| WO2018086055A1 (en) | 2016-11-11 | 2018-05-17 | Dow Global Technologies Llc | Aqueous coating composition |
| WO2019023844A1 (en) | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | AQUEOUS POLYMERIC DISPERSION |
| AU2017425706B2 (en) | 2017-07-31 | 2023-10-26 | Dow Global Technologies Llc | Aqueous coating composition |
| AU2018418723B2 (en) | 2018-04-12 | 2024-02-29 | Dow Global Technologies Llc | Aqueous coating composition |
| CN110713572B (zh) * | 2018-07-11 | 2022-07-22 | 广东华润涂料有限公司 | 一种包含丙烯酸类共聚物的高固低粘的树脂组合物 |
| AU2019100711A4 (en) | 2018-12-25 | 2019-08-22 | Ptt Global Chemical Public Company Limited | Solvent as an open time/wet edge time extenders and anti-skinning/freeze thaw stability |
| EP3918016B1 (en) | 2019-01-29 | 2023-08-09 | Dow Global Technologies LLC | Aqueous coating composition |
| CA3134861A1 (en) | 2019-04-16 | 2020-10-22 | Dow Global Technologies Llc | Freeze-thaw additive composition |
| CN111116838A (zh) * | 2019-12-30 | 2020-05-08 | 广东银洋环保新材料有限公司 | 一种冻融稳定性优异的丙烯酸酯乳液及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05301933A (ja) * | 1992-04-27 | 1993-11-16 | Japan Synthetic Rubber Co Ltd | 共重合体ラテックス |
| EP0741173A2 (en) * | 1995-05-03 | 1996-11-06 | National Starch and Chemical Investment Holding Corporation | Latex binders and paints which are free of volatile coalescents and freeze-thaw additives |
| CN101977974A (zh) * | 2008-01-18 | 2011-02-16 | 罗地亚管理公司 | 具有冻融稳定性的胶乳粘结剂、水性涂料和漆以及它们的使用方法 |
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| US5399617A (en) | 1990-06-13 | 1995-03-21 | National Starch And Chemical Investment Holding Corporation | Thermoplastic, aqueous latex paints having improved wet adhesion and freeze-thaw stability |
| US5064888A (en) | 1990-06-13 | 1991-11-12 | National Starch And Chemical Investment Holding Corporation | Amphoteric surfactants and copolymerizable amphoteric surfactants for use in latex paints |
| US5610225A (en) | 1995-05-03 | 1997-03-11 | National Starch And Chemical Investment Holding Corporation | Latex paints which are free of volatile coalescents and freeze-thaw additives |
| US5618876A (en) | 1995-06-05 | 1997-04-08 | National Starch And Chemical Investment Holding Corporation | Latex binders and coatings containing polymers derived from polymerizable saccharide monomers |
| US6124397A (en) | 1998-02-24 | 2000-09-26 | Air Products And Chemicals, Inc. | Vinyl acetate copolymer emulsions stabilized by poly(ethylene glycol)-diepoxide adducts |
| JP3320698B2 (ja) | 1999-12-09 | 2002-09-03 | 大日本塗料株式会社 | 水性塗料組成物 |
| US6933415B2 (en) | 2002-06-06 | 2005-08-23 | Basf Ag | Low-VOC aqueous coating compositions with excellent freeze-thaw stability |
| US7402627B2 (en) * | 2003-08-18 | 2008-07-22 | Columbia Insurance Company | Precursor colorant composition for latex paint |
| WO2005054384A1 (en) | 2003-12-04 | 2005-06-16 | Basf Aktiengesellschaft | Low-voc aqueous coating compositions with excellent freeze-thaw stability |
| US7086187B2 (en) | 2004-11-03 | 2006-08-08 | Husam Yousef Bandak | Advertising display system and method |
| MXPA06011748A (es) | 2005-01-05 | 2007-03-01 | Basf Ag | Composiciones de recubrimiento de polimero en emulsion con bajo contenido de voc. |
| US7705082B2 (en) | 2005-04-22 | 2010-04-27 | Basf Se | Low-VOC emulsion polymer coating compositions |
| CA2655641A1 (en) | 2006-06-23 | 2008-01-03 | John A. Joecken | High solids emulsions |
| CN101910207B (zh) | 2007-11-19 | 2013-04-24 | 巴斯夫欧洲公司 | 高度支链化聚合物用于制备具有改进的冻结/融化稳定性的聚合物分散体的用途 |
| US9388323B2 (en) | 2008-01-18 | 2016-07-12 | Rhodia Operations | Latex binders, aqueous coatings and paints having freeze-thaw ability and methods for using same |
| EP2297258B1 (en) * | 2008-07-10 | 2014-03-19 | Arkema, Inc. | Coating compositions having increased block resistance |
| CN102741305B (zh) * | 2010-02-03 | 2015-02-25 | 巴斯夫欧洲公司 | 由酸单体、缔合性单体和非离子性单体制成的缔合性增稠剂 |
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- 2013-02-05 US US14/376,702 patent/US9834698B2/en active Active
- 2013-02-05 WO PCT/US2013/024698 patent/WO2013119521A1/en not_active Ceased
- 2013-02-05 ES ES13746192.7T patent/ES2646778T3/es active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05301933A (ja) * | 1992-04-27 | 1993-11-16 | Japan Synthetic Rubber Co Ltd | 共重合体ラテックス |
| EP0741173A2 (en) * | 1995-05-03 | 1996-11-06 | National Starch and Chemical Investment Holding Corporation | Latex binders and paints which are free of volatile coalescents and freeze-thaw additives |
| CN101977974A (zh) * | 2008-01-18 | 2011-02-16 | 罗地亚管理公司 | 具有冻融稳定性的胶乳粘结剂、水性涂料和漆以及它们的使用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104105727B (zh) | 2017-06-06 |
| EP3231827A1 (en) | 2017-10-18 |
| ES2728360T3 (es) | 2019-10-23 |
| CN104105727A (zh) | 2014-10-15 |
| EP2825575B1 (en) | 2017-08-09 |
| EP2825575A1 (en) | 2015-01-21 |
| BR112014019535A2 (enExample) | 2017-06-20 |
| CN107099212A (zh) | 2017-08-29 |
| EP3231827B1 (en) | 2019-03-27 |
| US20150073080A1 (en) | 2015-03-12 |
| ES2646778T3 (es) | 2017-12-15 |
| CA2863918A1 (en) | 2013-08-15 |
| WO2013119521A1 (en) | 2013-08-15 |
| CA2863918C (en) | 2019-02-26 |
| MX352167B (es) | 2017-11-13 |
| BR112014019535A8 (pt) | 2017-07-11 |
| MX2014009586A (es) | 2014-09-12 |
| US9834698B2 (en) | 2017-12-05 |
| EP2825575A4 (en) | 2016-04-13 |
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