ES2622299T3 - Polímero de polipropileno heterofásico - Google Patents

Polímero de polipropileno heterofásico Download PDF

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Publication number
ES2622299T3
ES2622299T3 ES14150318.5T ES14150318T ES2622299T3 ES 2622299 T3 ES2622299 T3 ES 2622299T3 ES 14150318 T ES14150318 T ES 14150318T ES 2622299 T3 ES2622299 T3 ES 2622299T3
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Spain
Prior art keywords
propylene
ethylene
heterophasic
catalyst
weight
Prior art date
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Active
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ES14150318.5T
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English (en)
Spanish (es)
Inventor
Jingbo Wang
Petar Doshev
Luigi Resconi
Wilfried Töltsch
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Borealis GmbH
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Borealis GmbH
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/20—Activation energy or enthalpy
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/16—Ethene-propene or ethene-propene-diene copolymers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ES14150318.5T 2014-01-07 2014-01-07 Polímero de polipropileno heterofásico Active ES2622299T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14150318.5A EP2891667B1 (en) 2014-01-07 2014-01-07 Heterophasic polypropylene polymer

Publications (1)

Publication Number Publication Date
ES2622299T3 true ES2622299T3 (es) 2017-07-06

Family

ID=49883039

Family Applications (1)

Application Number Title Priority Date Filing Date
ES14150318.5T Active ES2622299T3 (es) 2014-01-07 2014-01-07 Polímero de polipropileno heterofásico

Country Status (9)

Country Link
US (1) US9932469B2 (enExample)
EP (1) EP2891667B1 (enExample)
JP (1) JP6545703B2 (enExample)
KR (1) KR20160106690A (enExample)
CN (1) CN105899553B (enExample)
ES (1) ES2622299T3 (enExample)
PL (1) PL2891667T3 (enExample)
RU (1) RU2677463C2 (enExample)
WO (1) WO2015104266A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2891667T3 (pl) 2014-01-07 2017-07-31 Borealis Ag Heterofazowy polimer polipropylenu
WO2017085195A1 (en) * 2015-11-17 2017-05-26 Borealis Ag High flow tpo composition with excellent low temperature impact
ES2897714T3 (es) * 2016-12-01 2022-03-02 Borealis Ag Composición de polipropileno expandido
ES2952512T3 (es) * 2016-12-15 2023-10-31 Borealis Ag Composición de polipropileno con excelente adhesión de la pintura
CN110392700B (zh) * 2017-03-27 2022-01-11 巴塞尔聚烯烃意大利有限公司 烯烃的气相聚合方法
US11078304B2 (en) * 2017-07-07 2021-08-03 Borealis Ag Process for preparing heterophasic propylene copolymers
ES2765849T3 (es) 2017-08-28 2020-06-11 Borealis Ag Composición de polipropileno con baja contracción en un intervalo amplio de temperaturas de aplicación
CN111148788B (zh) * 2017-10-13 2023-04-18 博里利斯股份公司 多峰无规多相聚丙烯组合物
EP3505566A1 (en) * 2017-12-28 2019-07-03 Borealis AG Cable jacket
EP3735442B1 (en) 2018-01-05 2023-11-08 Borealis AG Single-site catalyst based impacted copolymers with excellent mechanical and optical properties
US11034827B2 (en) 2018-04-12 2021-06-15 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and polymerization methods
WO2020064313A1 (en) 2018-09-26 2020-04-02 Borealis Ag Propylene random copolymer for use in film applications
WO2021058740A1 (en) * 2019-09-25 2021-04-01 Borealis Ag Catalysts
US20220396693A1 (en) * 2019-11-20 2022-12-15 Sabic Global Technologies B.V. Biaxially oriented pipe
EP4259719A1 (en) * 2020-12-14 2023-10-18 Basell Poliolefine Italia S.r.l. Ultrasoft polyolefin composition
EP4083134A1 (en) * 2021-04-27 2022-11-02 Borealis AG Beta nucleated heterophasic polypropylene composition
ES3038710T3 (en) * 2021-08-04 2025-10-14 Borealis Gmbh Multilayer nonwoven structure

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DE69518094T2 (de) * 1994-04-11 2001-03-22 Mitsui Chemicals, Inc. Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
CA2483206A1 (en) 2002-06-12 2003-12-24 Basell Polyolefine Gmbh Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency
AU2003263188A1 (en) 2002-07-24 2004-02-16 Basell Polyolefine Gmbh At least two-stage process for preparing propylene polymer compositions
JP2005139282A (ja) * 2003-11-06 2005-06-02 Japan Polypropylene Corp プロピレン・エチレンブロック共重合体
EP1858907B1 (en) 2005-03-18 2008-10-15 Basell Polyolefine GmbH Metallocene compounds
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
KR101107825B1 (ko) 2006-08-11 2012-02-08 가부시키가이샤 프라임 폴리머 포장 재료용 프로필렌계 수지 조성물
BRPI0722162A2 (pt) 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
EP2075284B1 (en) 2007-12-17 2013-05-29 Borealis Technology OY Heterophasic polypropylene with high flowability and excellent low temperature impact properties
ES2337195T5 (es) * 2007-12-18 2013-03-01 Borealis Technology Oy Polipropileno heterofásico con elevadas propiedades de impacto
EP2283072B2 (en) * 2008-04-24 2018-07-18 Borealis AG Process for producing high purity heterophasic propylene copolymers
JP5147530B2 (ja) * 2008-05-14 2013-02-20 日本ポリプロ株式会社 プロピレン−エチレン共重合体
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
ES2619729T3 (es) 2008-11-07 2017-06-26 Borealis Ag Composición de catalizador sólida
WO2010052260A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
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KR101626069B1 (ko) 2010-04-28 2016-05-31 보레알리스 아게 브릿지된 메탈로센을 포함하는 고체 미립자 촉매
CN103025767B (zh) 2010-04-28 2015-01-14 博瑞立斯有限公司 包含桥连的茂金属的固体颗粒催化剂
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
ES2572507T3 (es) 2011-07-08 2016-05-31 Borealis Ag Copolímeros heterofásicos
EP2899077B1 (en) * 2012-09-19 2016-12-21 Mitsubishi Chemical Corporation Airbag housing cover
PL2824142T3 (pl) 2013-07-12 2016-08-31 Borealis Ag Kopolimer heterofazowy
PL2891667T3 (pl) 2014-01-07 2017-07-31 Borealis Ag Heterofazowy polimer polipropylenu
PL3126411T3 (pl) * 2014-04-04 2018-04-30 Borealis Ag Heterofazowy kopolimer propylenu o niskiej zawartości substancji ekstrahowalnych
ES2659731T3 (es) * 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles

Also Published As

Publication number Publication date
RU2016127547A (ru) 2018-02-13
JP6545703B2 (ja) 2019-07-17
PL2891667T3 (pl) 2017-07-31
KR20160106690A (ko) 2016-09-12
CN105899553B (zh) 2018-02-02
JP2017502163A (ja) 2017-01-19
RU2016127547A3 (enExample) 2018-08-22
RU2677463C2 (ru) 2019-01-17
WO2015104266A1 (en) 2015-07-16
EP2891667A1 (en) 2015-07-08
US9932469B2 (en) 2018-04-03
CN105899553A (zh) 2016-08-24
US20160333175A1 (en) 2016-11-17
EP2891667B1 (en) 2017-03-15

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