ES2551273T3 - Artículo revestido con revestimiento de baja emisividad que incluye oxinitruro de silicio circonio y métodos para realizar el mismo - Google Patents
Artículo revestido con revestimiento de baja emisividad que incluye oxinitruro de silicio circonio y métodos para realizar el mismo Download PDFInfo
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- ES2551273T3 ES2551273T3 ES05848837.0T ES05848837T ES2551273T3 ES 2551273 T3 ES2551273 T3 ES 2551273T3 ES 05848837 T ES05848837 T ES 05848837T ES 2551273 T3 ES2551273 T3 ES 2551273T3
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0676—Oxynitrides
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/74—UV-absorbing coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
Abstract
Un artículo revestido que incluye un revestimiento soportado por un sustrato de vidrio (1), revestimiento que comprende: una primera capa (2; 3); una capa reflectante de infrarrojos (IR) (9; 9') que comprende plata ubicada en el sustrato (1) sobre al menos la primera capa (2; 3); una segunda capa (13; 16) ubicada en el sustrato y sobre al menos la capa reflectante de IR (9; 9') y la primera capa; y donde la primera capa (2; 3) y/o la segunda capa (13; 16) comprende oxinitruro de silicio-circonio, y donde el oxinitruro de silicio-circonio contiene más circonio que silicio, y el contenido de oxígeno de la capa que comprende oxinitruro de silicio-circonio se presenta con una cantidad de forma que la(s) capa(s) que comprende(n) oxinitruro de silicio-circonio con una longitud de onda de 550 nm presente(n) un índice de refracción (n) desde 1,8 a 2,4.
Description
E05848837
27-10-2015
Tabla 4: Características ópticas de ejemplo (unidad IG)
Característica General Más preferido Tvis (o TY)(Ill. C, 2 grad.): >= 60 % >= 70%
5 a*t (Ill. C, 2°): -10 a +10 -8 a +8
b*t (Ill. C, 2°): -10 a +10 -8 a +8 RexteriorY (Ill. C, 2 grad.): <= 18 % <= 16 % a*ext (Ill. C, 2°): -10 a +10 -8 a +8
10 b*ext (Ill. C, 2°): -10,0 a +10,0 -9 a +9
RinteriorY (Ill. C, 2 grad.): <=18 % <=16 %
a*interior (Ill. C, 2°): -10 a +10 -8 a +8
15 b*interior (Ill. C, 2°): -14 a +10 -10 a +9
Valor U (IG)(W/(m2K)): <= 1,25 <= 1,15
[0035] La figura 2 es una vista transversal de otra forma de realización de ejemplo de la presente invención. El
20 artículo revestido de la forma de realización de la figura 2 incluye un sustrato de vidrio 1, una capa dieléctrica 2, una capa de contacto inferior 8, una capa reflectante de IR 9, una capa de contacto superior 10, una capa o capas dieléctricas opcionales 12 y una capa dieléctrica 16. Las capas de contacto 8 y 10 pueden ser de materiales tales como NiCrOx, NiCr u óxido de zinc (que pueden doparse o no con otro material tal como las formas de realización alternativas con Al). También se pueden presentar otras capas. Una o ambas capas 2 y 16
25 pueden ser de oxinitruro de silicio-circonio o incluirlo en determinadas formas de realización de ejemplo de la presente invención. Por lo tanto, se puede utilizar oxinitruro de silicio-circonio como un recubrimiento de un revestimiento en determinadas formas de realización de ejemplo de la presente invención. Las características de ejemplo detalladas anteriormente en las tablas 2-4 se pueden aplicar a la forma de realización de la figura 2 en determinados casos.
30 [0036] La figura 3 es una vista transversal de otra forma de realización de ejemplo de la presente invención. La figura 3 ilustra que la(s) capa(s) de oxinitruro de silicio-circonio puede(n) utilizarse en apilamientos de plata dobles así como en determinadas formas de realización de ejemplo de la presente invención. El revestimiento en la forma de realización de la figura 3 incluye capas reflectantes de IR 9 y 9'; capas de contacto 7, 7', 11 y 11', capa
35 de oxinitruro de silicio-circonio 3, 13, capa dieléctrica y posible recubrimiento 15 y capa dieléctrica de óxido metálico 4. Tal y como se ha mencionado previamente, las capas de contacto de óxido de zinc 7 y 7' pueden doparse con otro material tal como Al en determinadas formas de realización de ejemplo y las capas de contacto 11, 11' pueden ser de un óxido de Ni y/o Cr o incluirlo en determinadas formas de realización de ejemplo. Una o ambas capas dieléctricas 3 y 13 pueden ser de oxinitruro de silicio-circonio o incluirlo en determinadas formas de
40 realización de ejemplo. Tal y como se ha mencionado anteriormente, este revestimiento específico se presenta a modo de ejemplo únicamente y no pretende ser limitativo a menos que se reivindique expresamente. Tal y como ocurre con otras formas de realización en el presente documento, la capa de oxinitruro de silicio-circonio 3 puede estar o no en contacto directo con el sustrato de vidrio 1. Por lo tanto, se pueden disponer otras capas entre el sustrato 1 y la capa 3 en determinados casos de ejemplo.
45 [0037] Las figuras 5-7 ilustran otras formas de realización de ejemplo de la presente invención. Tal y como se ha explicado anteriormente, se puede utilizar oxinitruro de silicio-circonio como reemplazo del nitruro de silicio en un revestimiento, o se puede utilizar de forma alternativa como capa adicional justo encima y/o justo debajo de una capa de nitruro de silicio o que lo incluya. Sorprendentemente, esto tiene como resultado una estabilidad química
50 y térmica mejorada en determinadas formas de realización de ejemplo.
[0038] La forma de realización de la figura 5 incluye un revestimiento que incluye una capa dieléctrica de nitruro de silicio 20 o que lo incluye, una capa de contacto inferior 8 de un material tal como óxido de zinc (que puede doparse de forma opcional con aluminio en determinadas formas de realización de ejemplo tal y como se muestra
55 en la figura 5), NiCrOx o similares, una capa reflectante de IR 9 de plata o similar, una capa de contacto superior 10 de un material tal como óxido de zinc (que puede doparse de forma opcional con aluminio en determinadas formas de realización de ejemplo), una capa dieléctrica 15 de nitruro de silicio o similar, o que lo incluye, y un recubrimiento de oxinitruro de silicio-circonio o que lo incluye 16. Se ha hallado que mediante el uso de oxinitruro de silicio-circonio como capa superior o de recubrimiento 16 con nitruro de silicio 15 por debajo de esta tal y como
60 se muestra en la figura 5, el artículo revestido alcanza una transmisión de luz mayor y una caída significativa en la resistencia laminar, resultados/mejoras no esperados. Las ventajas UV no esperadas también se consiguen como se ha detallado anteriormente, debido al uso de oxinitruro de silicio-circonio. Esta forma de realización puede tratarse térmicamente (templada térmicamente con el revestimiento sobre el mismo) en determinadas
8
E05848837
27-10-2015
formas de realización de ejemplo de la presente invención.
[0039] En determinadas formas de realización de ejemplo de la forma de realización de la figura 5, las capas 20 y 15 pueden presentar un grosor cada una desde aproximadamente 100 a 300 Å (más preferiblemente 5 aproximadamente 200 Å de grosor), las capas 8 y 10 pueden presentar un grosor cada una desde aproximadamente 100 a 300 Å (más preferiblemente aproximadamente 180 Å de grosor), la capa reflectante de IR 9 puede presentar un grosor desde aproximadamente 80 a 200 Å (más preferiblemente aproximadamente 120 Å de grosor), y la capa de oxinitruro de silicio-circonio 16 puede presentar un grosor desde aproximadamente 100 a 300 Å (más preferiblemente aproximadamente 200 Å de grosor). Los grosores de las diferentes capas pueden
10 adaptarse a los diferentes posibles usos del revestimiento (p. ej., como revestido o tratado térmicamente).
[0040] La figura 6 ilustra otra forma de realización de ejemplo de la presente invención. La forma de realización de la figura 6 es similar a la forma de realización de la figura 5, a excepción del orden de las capas 15 y 16 que se ha intercambiado. Después del intercambio del orden de estas capas, la transmisión de luz y la resistencia
15 laminar quedan casi al mismo nivel incluso después del tratamiento térmico opcional (HT) tal como el templado térmico. De nuevo, tal y como se ha explicado anteriormente, el uso de oxinitruro de silicio-circonio en la capa 13 (o 16) tiene como resultado una estabilidad térmica y química mejorada, además de las ventajas UV de ejemplo detalladas en el presente documento.
20 [0041] La figura 7 ilustra otra forma de realización de ejemplo de la presente invención. La forma de realización de la figura 7 es similar a la forma de realización de la figura 5, con la excepción de que la capa de nitruro de silicio inferior se ha reemplazado con la capa de oxinitruro de silicio-circonio 3. De nuevo, el uso de oxinitruro de silicio-circonio tiene como resultado una estabilidad térmica y química mejorada, así como las ventajas UV de ejemplo detalladas en el presente documento.
25 [0042] De forma opcional, en cualquiera de las formas de realización de las figuras 5-7, puede disponerse una capa de contacto de NiCrOx entre la capa reflectante de IR 9 y la capa con óxido de zinc 10 en determinadas formas de realización de ejemplo de la presente invención. Se ha hallado que esto mejora la durabilidad en determinadas formas de realización de ejemplo de la presente invención.
30 [0043] Aunque se ha descrito la invención en relación con lo que se considera actualmente que es la forma de realización más práctica y preferida, ha de entenderse que la invención no ha de limitarse a la forma de realización expuesta, sino al contrario, pretende cubrir diferentes modificaciones y disposiciones equivalentes incluidas dentro del alcance de las reivindicaciones adjuntas.
35
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Claims (1)
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Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4225 | 2004-12-06 | ||
US11/004,225 US7153578B2 (en) | 2004-12-06 | 2004-12-06 | Coated article with low-E coating including zirconium silicon oxynitride and methods of making same |
PCT/US2005/043946 WO2006062903A1 (en) | 2004-12-06 | 2005-12-06 | Coated article with low-e coating including zirconium silicon oxynitride and methods of making same |
Publications (2)
Publication Number | Publication Date |
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ES2551273T3 true ES2551273T3 (es) | 2015-11-17 |
ES2551273T5 ES2551273T5 (es) | 2019-05-14 |
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ID=36574638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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ES05848837T Active ES2551273T5 (es) | 2004-12-06 | 2005-12-06 | Artículo revestido con revestimiento de baja emisividad que incluye oxinitruro de silicio circonio y métodos para realizar el mismo |
Country Status (6)
Country | Link |
---|---|
US (2) | US7153578B2 (es) |
EP (1) | EP1831013B2 (es) |
CA (1) | CA2590295C (es) |
ES (1) | ES2551273T5 (es) |
PL (1) | PL1831013T5 (es) |
WO (1) | WO2006062903A1 (es) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7153578B2 (en) * | 2004-12-06 | 2006-12-26 | Guardian Industries Corp | Coated article with low-E coating including zirconium silicon oxynitride and methods of making same |
US7592068B2 (en) * | 2005-01-19 | 2009-09-22 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Heat treatable coated article with zirconium silicon oxynitride layer(s) and methods of making same |
FR2881757B1 (fr) * | 2005-02-08 | 2007-03-30 | Saint Gobain | Procede d'elaboration par projection thermique d'une cible a base de silicium et de zirconium |
MX2007014164A (es) | 2005-05-12 | 2008-02-25 | Agc Flat Glass North America | Recubrimiento de baja emisividad con bajo coeficiente de ganancia de calor solar, propiedades quimicas y mecanicas mejoradas y metodo para fabricar el mismo. |
GB0600425D0 (en) * | 2006-01-11 | 2006-02-15 | Pilkington Plc | Heat treatable coated glass pane |
US7744951B2 (en) * | 2006-04-13 | 2010-06-29 | Guardian Industries Corp. | Coated glass substrate with infrared and ultraviolet blocking characteristics |
DE102006024524A1 (de) | 2006-05-23 | 2007-12-06 | Von Ardenne Anlagentechnik Gmbh | Infrarotstrahlung reflektierendes, transparentes Schichtsystem |
WO2008060453A2 (en) * | 2006-11-09 | 2008-05-22 | Agc Flat Glass North America, Inc. | Optical coating with improved durability |
US8199264B2 (en) * | 2007-11-26 | 2012-06-12 | Guardian Industries Corp. | Ruggedized switchable glazing comprising a liquid crystal inclusive layer and a multi-layer low-E ultraviolet blocking coating |
US9333728B2 (en) * | 2007-11-06 | 2016-05-10 | Guardian Industries Corp. | Ruggedized switchable glazing, and/or method of making the same |
US7901781B2 (en) | 2007-11-23 | 2011-03-08 | Agc Flat Glass North America, Inc. | Low emissivity coating with low solar heat gain coefficient, enhanced chemical and mechanical properties and method of making the same |
US8263227B2 (en) † | 2008-06-25 | 2012-09-11 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including zirconium oxide and/or zirconium silicon oxynitride and methods of making same |
US8722210B2 (en) * | 2008-08-14 | 2014-05-13 | Lg Hausys, Ltd. | Low emissivity glass and method for manufacturing the same |
DE102008054139B4 (de) * | 2008-10-31 | 2010-11-11 | Schott Ag | Glas- oder Glaskeramik-Substrat mit Kratzschutzbeschichtung, dessen Verwendung und Verfahren zu dessen Herstellung |
EP2501660B1 (en) * | 2009-11-19 | 2017-06-07 | Guardian Europe S.à.r.l. | Bronze colored coated article with low-e coating |
KR101642708B1 (ko) * | 2010-01-19 | 2016-07-28 | 삼성전자주식회사 | 화상형성장치와 그 프리뷰 이미지 디스플레이방법, 및 서버와 그 프리뷰 이미지 제공방법 |
US8939606B2 (en) | 2010-02-26 | 2015-01-27 | Guardian Industries Corp. | Heatable lens for luminaires, and/or methods of making the same |
US8834976B2 (en) | 2010-02-26 | 2014-09-16 | Guardian Industries Corp. | Articles including anticondensation and/or low-E coatings and/or methods of making the same |
US8808882B2 (en) | 2010-09-17 | 2014-08-19 | Guardian Industries Corp. | Coated article having boron doped zinc oxide based seed layer with enhanced durability under functional layer and method of making the same |
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EP1831013B1 (en) | 2015-07-29 |
PL1831013T5 (pl) | 2019-11-29 |
US8663433B2 (en) | 2014-03-04 |
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PL1831013T3 (pl) | 2016-05-31 |
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