ES2547729T3 - Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico - Google Patents

Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico Download PDF

Info

Publication number
ES2547729T3
ES2547729T3 ES10784505.9T ES10784505T ES2547729T3 ES 2547729 T3 ES2547729 T3 ES 2547729T3 ES 10784505 T ES10784505 T ES 10784505T ES 2547729 T3 ES2547729 T3 ES 2547729T3
Authority
ES
Spain
Prior art keywords
acid
structure material
metal
gas
furandicarboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10784505.9T
Other languages
English (en)
Spanish (es)
Inventor
Natalia Trukhan
Ulrich Müller
Jens Heimann
Alois Kindler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2547729T3 publication Critical patent/ES2547729T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3014—Kneading
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
ES10784505.9T 2009-11-30 2010-11-25 Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico Active ES2547729T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09177495 2009-11-30
EP09177495 2009-11-30
PCT/EP2010/068234 WO2011064307A1 (de) 2009-11-30 2010-11-25 Metallorganische gerüstmaterialien basierend auf 2,5-furandicarbonsäure oder 2,5-thiophendicarbonsäure

Publications (1)

Publication Number Publication Date
ES2547729T3 true ES2547729T3 (es) 2015-10-08

Family

ID=43431815

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10784505.9T Active ES2547729T3 (es) 2009-11-30 2010-11-25 Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico

Country Status (11)

Country Link
US (1) US9688700B2 (enExample)
EP (1) EP2507247B1 (enExample)
JP (1) JP5847727B2 (enExample)
KR (1) KR101813732B1 (enExample)
CN (1) CN102639540B (enExample)
BR (1) BR112012012910A2 (enExample)
CA (1) CA2782054A1 (enExample)
ES (1) ES2547729T3 (enExample)
MX (1) MX2012005885A (enExample)
RU (1) RU2561603C2 (enExample)
WO (1) WO2011064307A1 (enExample)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504806B (zh) * 2011-10-14 2014-06-11 大连理工大学 一类基于顺磁性金属中心检测一氧化氮的金属有机骨架材料
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
CN102757453B (zh) * 2012-07-16 2014-12-17 南开大学 一种多功能稀土金属-有机框架及其制备方法
AU2014312018B2 (en) * 2013-08-30 2019-01-17 The Coca-Cola Company Furanoic polymer preforms, containers and processing
KR20160134644A (ko) 2014-03-18 2016-11-23 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 미세다공성 금속 유기 구조체의 정렬된 초격자로 구성된 메조스코픽 물질
KR101721556B1 (ko) * 2015-05-18 2017-04-10 한국화학연구원 수분 또는 알코올의 흡착을 위한 유무기 하이브리드 나노세공체를 포함하는 흡착제 및 이의 용도
CN108623814B (zh) * 2017-03-23 2020-10-16 中国石油化工股份有限公司 一种铜基多孔配位聚合物储氢材料及其制备方法
WO2019018591A1 (en) * 2017-07-19 2019-01-24 Youngstown State University SYSTEM AND METHOD FOR REMOVAL OF CONTAMINANTS
CN109021244B (zh) * 2018-06-12 2021-01-05 昆明理工大学 一种MOFs材料的制备方法及应用
JP2020011943A (ja) * 2018-07-05 2020-01-23 トヨタ自動車株式会社 配位不飽和金属有機構造体の製造方法及び配位不飽和金属有機構造体
US11266948B2 (en) 2018-08-14 2022-03-08 Board Of Regents, The University Of Texas System Use of metal organic frameworks for H2O sorption
KR102639663B1 (ko) * 2018-08-20 2024-02-21 주식회사 엘지에너지솔루션 금속 유기 골격체, 이의 제조방법 및 다공성 탄소 구조체의 제조방법
CN109320560B (zh) * 2018-08-27 2021-04-09 天津理工大学 含钴离子的功能配合物湿敏材料及其制备方法和应用
CN109046255A (zh) * 2018-08-30 2018-12-21 东北师范大学 一种金属-有机骨架脱硫吸附剂及其制备方法
CN109400892B (zh) * 2018-09-19 2021-04-09 桂林理工大学 一种可吸附易挥发性气体的铜基框架材料及制备方法
AU2019386080B2 (en) * 2018-11-26 2025-10-02 The Regents Of The University Of California Multivariate and other metal-organic frameworks, and uses thereof
EP3680311A1 (en) * 2019-01-08 2020-07-15 Centre National De La Recherche Scientifique Use of porous 2,5-furanedicarboxylate-based mofs for improved separation of branched alkanes
WO2020154427A1 (en) 2019-01-22 2020-07-30 Water Harvesting Inc. Water harvesting systems, and methods of using thereof
JP7180522B2 (ja) * 2019-04-22 2022-11-30 トヨタ自動車株式会社 有機金属構造体
WO2021067179A1 (en) 2019-09-30 2021-04-08 Water Harvesting Inc. Refrigerator integrated with an atmospheric water harvesting unit, and methods of using thereof
CN110775958B (zh) * 2019-11-06 2022-06-07 渤海大学 一种噻吩基镍配合物衍生的碳纳米管及其合成方法和应用
CN111196875A (zh) * 2020-01-09 2020-05-26 常州工程职业技术学院 一种2,5-呋喃二甲酸与Sm3+离子的配位聚合物、合成方法及应用
US12390760B2 (en) 2020-02-14 2025-08-19 Water Harvesting, Inc. Atmospheric water harvester with high efficiency, and methods of using thereof
JP2021155784A (ja) * 2020-03-26 2021-10-07 トヨタ紡織株式会社 金属ナノ粒子の製造方法、膜電極接合体の製造方法、及び固体高分子形燃料電池の製造方法
WO2022159498A1 (en) 2021-01-19 2022-07-28 Water Harvesting Inc. Atmospheric water harvester with climate-adjustable adsorbant properties
US11559762B1 (en) 2021-04-27 2023-01-24 Water Harvesting, Inc. Heat pump-based water harvesting systems, and methods of using thereof
CN113278156B (zh) * 2021-05-19 2022-03-18 三峡大学 镍基异构金属有机框架材料的制备方法及其应用
TW202314168A (zh) 2021-08-23 2023-04-01 美商水收集公司 基於熱泵的水採集系統及其使用方法
CN116217527B (zh) * 2021-12-02 2026-05-26 中国科学院宁波材料技术与工程研究所 一种呋喃类聚酯催化剂及其制备方法
US12343672B2 (en) 2022-09-23 2025-07-01 Water Harvesting, Inc. Atmospheric water harvesting system
US12420229B2 (en) 2022-10-11 2025-09-23 Water Harvesting, Inc. Low dew point air dehumidification system
CN115910628B (zh) * 2022-11-14 2024-08-06 三峡大学 铜MOFs超薄纳米花异质复合有机框架材料的制备方法及应用
US12472464B2 (en) 2023-01-19 2025-11-18 Water Harvesting, Inc. Atmospheric water harvester having subcooler heat exchanger
US12680279B2 (en) 2023-10-13 2026-07-14 Water Harvesting, Inc. Water harvester adsorption enthalpy removal system
US12351483B1 (en) 2024-11-01 2025-07-08 Water Harvesting, Inc. Water harvester
CN119931084B (zh) * 2025-02-19 2025-12-26 华南理工大学 一种金属有机骨架材料及其制备方法和应用

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3231498A1 (de) 1982-08-25 1984-03-01 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von harten, bruchfesten katalysatoren aus zeolith-pulver
IT1187661B (it) 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
GB8906726D0 (en) 1989-03-23 1989-05-10 Shell Int Research Titania extrudates
JPH0337156A (ja) 1989-07-03 1991-02-18 Sumitomo Metal Mining Co Ltd ゼオライト成型焼成体及びその製造方法
AU663621B2 (en) 1992-10-08 1995-10-12 Shell Internationale Research Maatschappij B.V. Process for extruding crystalline aluminosilicates
DE69330963T2 (de) 1992-12-16 2002-04-25 Chevron U.S.A. Inc., San Ramon Herstellung von aluminosilikatzeolithen
US5378671A (en) 1993-06-03 1995-01-03 Mobil Oil Corp. Method for preparing catalysts comprising zeolites
JP4135970B2 (ja) 1994-01-12 2008-08-20 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー イオン交換用完全フッ素置換ポリマーと金属酸化物からゾル−ゲルで生成させた多孔質ミクロ複合体
US5648508A (en) * 1995-11-22 1997-07-15 Nalco Chemical Company Crystalline metal-organic microporous materials
US20030078311A1 (en) * 2001-10-19 2003-04-24 Ulrich Muller Process for the alkoxylation of organic compounds in the presence of novel framework materials
US6893564B2 (en) 2002-05-30 2005-05-17 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks
WO2007044473A2 (en) 2005-10-06 2007-04-19 The Board Of Trustees Of The University Of Illinois High gain selective preconcentrators
WO2008057140A2 (en) * 2006-04-14 2008-05-15 The Board Of Trustees Of The University Of Illinois Rapid metal organic framework molecule synthesis method
DE102006020846A1 (de) * 2006-05-04 2007-11-08 Robert Bosch Gmbh Gassorptionsspeicher mit optimierter Kühlung
WO2009092777A1 (de) * 2008-01-24 2009-07-30 Basf Se Poröse metallorganische gerüstmaterialien als trockenmittel
US8343261B2 (en) 2008-03-17 2013-01-01 Basf Se Use of formate-based porous metal organic frameworks for methane storage
ES2387349T3 (es) 2008-07-21 2012-09-20 Basf Se Procedimiento para la obtención industrial de propeno
JP5491504B2 (ja) 2008-07-30 2014-05-14 ビーエーエスエフ ソシエタス・ヨーロピア リチウム系金属有機フレーム構造物
EP2387459A2 (de) 2009-01-14 2011-11-23 Basf Se Vakuumisolationseinheiten mit gettermaterialien
EP2408684B1 (de) 2009-03-20 2013-08-21 Basf Se Biologisch abbaubares material aus einem polymer enthaltenden porösen metallorganischen gerüstmaterial
JP5642148B2 (ja) 2009-03-20 2014-12-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ギ酸マグネシウムを基礎とする多孔質の有機金属骨格材料を無溶媒で製造する方法
KR20110139222A (ko) 2009-03-20 2011-12-28 바스프 에스이 아민으로 함침된 금속-유기 골격에 의해 산성 기체를 분리시키는 방법

Also Published As

Publication number Publication date
RU2561603C2 (ru) 2015-08-27
CN102639540A (zh) 2012-08-15
EP2507247B1 (de) 2015-08-05
BR112012012910A2 (pt) 2017-03-01
EP2507247A1 (de) 2012-10-10
KR101813732B1 (ko) 2017-12-29
JP2013512223A (ja) 2013-04-11
US9688700B2 (en) 2017-06-27
CA2782054A1 (en) 2011-06-03
MX2012005885A (es) 2012-06-19
KR20120105020A (ko) 2012-09-24
US20120251438A1 (en) 2012-10-04
RU2012127209A (ru) 2014-01-10
JP5847727B2 (ja) 2016-01-27
CN102639540B (zh) 2015-12-02
WO2011064307A1 (de) 2011-06-03

Similar Documents

Publication Publication Date Title
US9688700B2 (en) Metal-organic frameworks based on on 2,5-furandicarboxylic acid or 2,5-thiophenedicarboxylic acid
ES2402323T3 (es) Aminocarboxilatos de aluminio como materiales estructurales organometálicos porosos
EP2746248B1 (en) Metal complex and adsorbent material, storage material, and separating material comprising same
Wade et al. Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3 (BTC) 2 (M= Cr, Fe, Ni, Cu, Mo, Ru)
CN108925135B (zh) 制备(S)-(2R,3R,11bR)-3-异丁基-9,10-二甲氧基-2,3,4,6,7,11b-六氢-1H-吡啶并[2,1-a]异喹啉-2-基2-氨基-3-甲基丁酸酯二(4-甲基苯磺酸盐)的合成方法
ES2565977T3 (es) Método para la preparación de estructuras organo-metálicas
ES2761402T3 (es) Complejo metálico de polímero poroso, adsorbente de gas, dispositivo de separación de gas y dispositivo de almacenamiento de gas que usa el mismo
US9132411B2 (en) Strategies, linkers and coordination polymers for high-performance sorbents
Arici et al. A porous Zn (II)-coordination polymer based on a tetracarboxylic acid exhibiting selective CO2 adsorption and iodine uptake
KR20080103986A (ko) 다공성 금속 유기 골격체 물질의 제조 방법
US20140287514A1 (en) Luminescent microporous material for detection and discrimination of low-levels of common gases and vapors
Zamani et al. Fast and efficient reduction of nitro aromatic compounds over Fe3O4/β-alanine-acrylamide-Ni nanocomposite as a new magnetic catalyst
Gao et al. Rational construction and remarkable gas adsorption properties of a HKUST-1-like tbo-type MOF based on a tetraisophthalate linker
Wang et al. Rational construction of an ssa-type of MOF through pre-organizing the ligand's conformation and its exceptional gas adsorption properties
Almáši et al. Synthesis, characterization and sorption properties of zinc (II) metal–organic framework containing methanetetrabenzoate ligand
JP6221910B2 (ja) 金属錯体およびその製造方法
JP5491504B2 (ja) リチウム系金属有機フレーム構造物
US20090062498A1 (en) Novel strategies, linkers and coordination polymers for high-performance sorbents
KR20150058430A (ko) 아세틸렌 가교 링커 및 그로부터 제조된 금속-유기 골격체(MOFs)
Yu et al. Various crystal structures based on 4, 4′-(diethynylanthracene-9, 10-diyl) dibenzoic acid: from 0D dimer to 3D net framework
CN109608652A (zh) MOFs晶体材料及其制备、应用
Boldog et al. Influence of sterically non-hindering methyl groups on adsorption properties of two classical zinc and copper MOF types
KR20090131099A (ko) 전자공여 아조그룹의 리간드를 포함하는 ＮｂＯ-망위상기하학적 구조의 영구 다공성 기체 저장용 금속-유기골격체 및 이를 포함하는 기체 저장체
KR101029326B1 (ko) 큰 다공성의 금속-유기 골격체 및 이를 포함하는 가스 저장체 및 금속-유기 골격체 제조방법
US20250281899A1 (en) METAL-ORGANIC FRAMEWORKS BASED ON UiO-66 AND METHOD FOR DIRECT AIR CAPTURE OF CARBON DIOXIDE