RU2561603C2 - Металлорганические скелетные материалы на основе 2,5-фурандикарбоновой или 2,5-тиофендикарбоновой кислоты - Google Patents
Металлорганические скелетные материалы на основе 2,5-фурандикарбоновой или 2,5-тиофендикарбоновой кислоты Download PDFInfo
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- RU2561603C2 RU2561603C2 RU2012127209/04A RU2012127209A RU2561603C2 RU 2561603 C2 RU2561603 C2 RU 2561603C2 RU 2012127209/04 A RU2012127209/04 A RU 2012127209/04A RU 2012127209 A RU2012127209 A RU 2012127209A RU 2561603 C2 RU2561603 C2 RU 2561603C2
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- acid
- furandicarboxylic
- skeletal material
- metal
- gas
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3007—Moulding, shaping or extruding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3014—Kneading
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/204—Metal organic frameworks (MOF's)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Furan Compounds (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09177495.0 | 2009-11-30 | ||
| EP09177495 | 2009-11-30 | ||
| PCT/EP2010/068234 WO2011064307A1 (de) | 2009-11-30 | 2010-11-25 | Metallorganische gerüstmaterialien basierend auf 2,5-furandicarbonsäure oder 2,5-thiophendicarbonsäure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012127209A RU2012127209A (ru) | 2014-01-10 |
| RU2561603C2 true RU2561603C2 (ru) | 2015-08-27 |
Family
ID=43431815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012127209/04A RU2561603C2 (ru) | 2009-11-30 | 2010-11-25 | Металлорганические скелетные материалы на основе 2,5-фурандикарбоновой или 2,5-тиофендикарбоновой кислоты |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9688700B2 (enExample) |
| EP (1) | EP2507247B1 (enExample) |
| JP (1) | JP5847727B2 (enExample) |
| KR (1) | KR101813732B1 (enExample) |
| CN (1) | CN102639540B (enExample) |
| BR (1) | BR112012012910A2 (enExample) |
| CA (1) | CA2782054A1 (enExample) |
| ES (1) | ES2547729T3 (enExample) |
| MX (1) | MX2012005885A (enExample) |
| RU (1) | RU2561603C2 (enExample) |
| WO (1) | WO2011064307A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2699640C2 (ru) * | 2013-08-30 | 2019-09-06 | Дзе Кока-Кола Компани | Фурановые полимерные предварительно отформованные заготовки, контейнеры и способы обработки |
| RU2716125C1 (ru) * | 2018-07-05 | 2020-03-05 | Тойота Дзидося Кабусики Кайся | Способ получения координационно ненасыщенного металл-органического каркаса и координационно ненасыщенный металл-органический каркас |
| RU2741968C1 (ru) * | 2019-04-22 | 2021-02-01 | Тойота Дзидося Кабусики Кайся | Металлоорганический каркас |
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| CN102504806B (zh) * | 2011-10-14 | 2014-06-11 | 大连理工大学 | 一类基于顺磁性金属中心检测一氧化氮的金属有机骨架材料 |
| US9527751B2 (en) | 2011-11-11 | 2016-12-27 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure |
| CN102757453B (zh) * | 2012-07-16 | 2014-12-17 | 南开大学 | 一种多功能稀土金属-有机框架及其制备方法 |
| KR20160134644A (ko) | 2014-03-18 | 2016-11-23 | 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 | 미세다공성 금속 유기 구조체의 정렬된 초격자로 구성된 메조스코픽 물질 |
| KR101721556B1 (ko) * | 2015-05-18 | 2017-04-10 | 한국화학연구원 | 수분 또는 알코올의 흡착을 위한 유무기 하이브리드 나노세공체를 포함하는 흡착제 및 이의 용도 |
| CN108623814B (zh) * | 2017-03-23 | 2020-10-16 | 中国石油化工股份有限公司 | 一种铜基多孔配位聚合物储氢材料及其制备方法 |
| WO2019018591A1 (en) * | 2017-07-19 | 2019-01-24 | Youngstown State University | SYSTEM AND METHOD FOR REMOVAL OF CONTAMINANTS |
| CN109021244B (zh) * | 2018-06-12 | 2021-01-05 | 昆明理工大学 | 一种MOFs材料的制备方法及应用 |
| US11266948B2 (en) | 2018-08-14 | 2022-03-08 | Board Of Regents, The University Of Texas System | Use of metal organic frameworks for H2O sorption |
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| CN109400892B (zh) * | 2018-09-19 | 2021-04-09 | 桂林理工大学 | 一种可吸附易挥发性气体的铜基框架材料及制备方法 |
| JP7543266B2 (ja) * | 2018-11-26 | 2024-09-02 | ザ リージェンツ オブ ザ ユニヴァーシティ オブ カリフォルニア | 多成分有機金属構造体およびその他の有機金属構造体ならびにこれらの使用方法 |
| EP3680311A1 (en) * | 2019-01-08 | 2020-07-15 | Centre National De La Recherche Scientifique | Use of porous 2,5-furanedicarboxylate-based mofs for improved separation of branched alkanes |
| US12054402B2 (en) | 2019-01-22 | 2024-08-06 | Water Harvesting Inc. | Water harvesting systems, and methods of using thereof |
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| CN110775958B (zh) * | 2019-11-06 | 2022-06-07 | 渤海大学 | 一种噻吩基镍配合物衍生的碳纳米管及其合成方法和应用 |
| CN111196875A (zh) * | 2020-01-09 | 2020-05-26 | 常州工程职业技术学院 | 一种2,5-呋喃二甲酸与Sm3+离子的配位聚合物、合成方法及应用 |
| WO2021162894A1 (en) | 2020-02-14 | 2021-08-19 | Water Harvesting Inc. | Atmospheric water harvester with high efficiency, and methods of using thereof |
| JP2021155784A (ja) * | 2020-03-26 | 2021-10-07 | トヨタ紡織株式会社 | 金属ナノ粒子の製造方法、膜電極接合体の製造方法、及び固体高分子形燃料電池の製造方法 |
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| US11559762B1 (en) | 2021-04-27 | 2023-01-24 | Water Harvesting, Inc. | Heat pump-based water harvesting systems, and methods of using thereof |
| CN113278156B (zh) * | 2021-05-19 | 2022-03-18 | 三峡大学 | 镍基异构金属有机框架材料的制备方法及其应用 |
| TW202314168A (zh) | 2021-08-23 | 2023-04-01 | 美商水收集公司 | 基於熱泵的水採集系統及其使用方法 |
| CN116217527A (zh) * | 2021-12-02 | 2023-06-06 | 中国科学院宁波材料技术与工程研究所 | 一种呋喃类聚酯催化剂及其制备方法 |
| US12343672B2 (en) | 2022-09-23 | 2025-07-01 | Water Harvesting, Inc. | Atmospheric water harvesting system |
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| CN115910628B (zh) * | 2022-11-14 | 2024-08-06 | 三峡大学 | 铜MOFs超薄纳米花异质复合有机框架材料的制备方法及应用 |
| US12472464B2 (en) | 2023-01-19 | 2025-11-18 | Water Harvesting, Inc. | Atmospheric water harvester having subcooler heat exchanger |
| US20250122701A1 (en) | 2023-10-13 | 2025-04-17 | Water Harvesting, Inc. | Water Harvester Adsorption Enthalpy Removal System |
| US12351483B1 (en) | 2024-11-01 | 2025-07-08 | Water Harvesting, Inc. | Water harvester |
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| WO2007044473A2 (en) * | 2005-10-06 | 2007-04-19 | The Board Of Trustees Of The University Of Illinois | High gain selective preconcentrators |
| RU2308465C2 (ru) * | 2001-10-19 | 2007-10-20 | Басф Акциенгезелльшафт | Способ алкоксилирования органических соединений в присутствии новых каркасных материалов |
| WO2008057140A2 (en) * | 2006-04-14 | 2008-05-15 | The Board Of Trustees Of The University Of Illinois | Rapid metal organic framework molecule synthesis method |
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| DE3231498A1 (de) | 1982-08-25 | 1984-03-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von harten, bruchfesten katalysatoren aus zeolith-pulver |
| IT1187661B (it) | 1985-04-23 | 1987-12-23 | Enichem Sintesi | Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica |
| GB8906726D0 (en) | 1989-03-23 | 1989-05-10 | Shell Int Research | Titania extrudates |
| JPH0337156A (ja) | 1989-07-03 | 1991-02-18 | Sumitomo Metal Mining Co Ltd | ゼオライト成型焼成体及びその製造方法 |
| EP0592050B1 (en) | 1992-10-08 | 1996-04-10 | Shell Internationale Researchmaatschappij B.V. | Process for extruding crystalline aluminosilicates |
| WO1994013584A1 (en) | 1992-12-16 | 1994-06-23 | Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. | Preparation of aluminosilicate zeolites |
| US5378671A (en) | 1993-06-03 | 1995-01-03 | Mobil Oil Corp. | Method for preparing catalysts comprising zeolites |
| JP4135970B2 (ja) | 1994-01-12 | 2008-08-20 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | イオン交換用完全フッ素置換ポリマーと金属酸化物からゾル−ゲルで生成させた多孔質ミクロ複合体 |
| US5648508A (en) * | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
| US6893564B2 (en) | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| DE102006020846A1 (de) * | 2006-05-04 | 2007-11-08 | Robert Bosch Gmbh | Gassorptionsspeicher mit optimierter Kühlung |
| ES2377105T3 (es) * | 2008-01-24 | 2012-03-22 | Basf Se | Material estructural organometálico poroso como agente desecante |
| ES2378441T3 (es) | 2008-03-17 | 2012-04-12 | Basf Se | Empleo de materiales estructurales organometálicos porosos basados en formiato para almacenaje de metano |
| CA2728314A1 (en) | 2008-07-21 | 2010-01-28 | Basf Se | Process for the industrial isolation of propene |
| WO2010012715A1 (de) | 2008-07-30 | 2010-02-04 | Basf Se | Lithiumbasierte metallorganische gerüstmaterialien |
| WO2010081797A2 (de) | 2009-01-14 | 2010-07-22 | Basf Se | Vakuumisolationseinheiten mit gettermaterialien |
| WO2010106105A2 (de) | 2009-03-20 | 2010-09-23 | Basf Se | Biologisch abbaubares material aus einem polymer enthaltend poröses metallorganisches gerüstmaterial |
| AU2010224830A1 (en) | 2009-03-20 | 2011-10-13 | Basf Se | Method for separating acid gases using metal-organic frameworks impregnated with amines |
| EP2408732B1 (de) | 2009-03-20 | 2013-01-23 | Basf Se | Lösemittelfreie herstellung von magnesiumformiat-basiertem porösen metallorganischen gerüstmaterial |
-
2010
- 2010-11-25 RU RU2012127209/04A patent/RU2561603C2/ru not_active IP Right Cessation
- 2010-11-25 CN CN201080054078.1A patent/CN102639540B/zh not_active Expired - Fee Related
- 2010-11-25 ES ES10784505.9T patent/ES2547729T3/es active Active
- 2010-11-25 JP JP2012540433A patent/JP5847727B2/ja not_active Expired - Fee Related
- 2010-11-25 MX MX2012005885A patent/MX2012005885A/es active IP Right Grant
- 2010-11-25 US US13/512,637 patent/US9688700B2/en not_active Expired - Fee Related
- 2010-11-25 WO PCT/EP2010/068234 patent/WO2011064307A1/de not_active Ceased
- 2010-11-25 KR KR1020127017012A patent/KR101813732B1/ko not_active Expired - Fee Related
- 2010-11-25 EP EP10784505.9A patent/EP2507247B1/de not_active Not-in-force
- 2010-11-25 CA CA2782054A patent/CA2782054A1/en not_active Abandoned
- 2010-11-25 BR BR112012012910A patent/BR112012012910A2/pt not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| RU2699640C2 (ru) * | 2013-08-30 | 2019-09-06 | Дзе Кока-Кола Компани | Фурановые полимерные предварительно отформованные заготовки, контейнеры и способы обработки |
| RU2716125C1 (ru) * | 2018-07-05 | 2020-03-05 | Тойота Дзидося Кабусики Кайся | Способ получения координационно ненасыщенного металл-органического каркаса и координационно ненасыщенный металл-органический каркас |
| RU2741968C1 (ru) * | 2019-04-22 | 2021-02-01 | Тойота Дзидося Кабусики Кайся | Металлоорганический каркас |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5847727B2 (ja) | 2016-01-27 |
| US20120251438A1 (en) | 2012-10-04 |
| BR112012012910A2 (pt) | 2017-03-01 |
| JP2013512223A (ja) | 2013-04-11 |
| KR101813732B1 (ko) | 2017-12-29 |
| CN102639540A (zh) | 2012-08-15 |
| RU2012127209A (ru) | 2014-01-10 |
| KR20120105020A (ko) | 2012-09-24 |
| WO2011064307A1 (de) | 2011-06-03 |
| EP2507247B1 (de) | 2015-08-05 |
| EP2507247A1 (de) | 2012-10-10 |
| CA2782054A1 (en) | 2011-06-03 |
| ES2547729T3 (es) | 2015-10-08 |
| MX2012005885A (es) | 2012-06-19 |
| CN102639540B (zh) | 2015-12-02 |
| US9688700B2 (en) | 2017-06-27 |
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