ES2526056T3 - Copolímeros de bloque de olefinas catalíticos por medio de agente de transporte polimerizable - Google Patents
Copolímeros de bloque de olefinas catalíticos por medio de agente de transporte polimerizable Download PDFInfo
- Publication number
- ES2526056T3 ES2526056T3 ES06814747.9T ES06814747T ES2526056T3 ES 2526056 T3 ES2526056 T3 ES 2526056T3 ES 06814747 T ES06814747 T ES 06814747T ES 2526056 T3 ES2526056 T3 ES 2526056T3
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- polymerization
- polymer
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- polymerizable
- hydrocarbyl
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- 229920001400 block copolymer Polymers 0.000 title claims description 51
- 230000003197 catalytic effect Effects 0.000 title claims description 49
- 150000001336 alkenes Chemical class 0.000 title claims description 38
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 146
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- 230000015572 biosynthetic process Effects 0.000 claims abstract description 45
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 claims abstract description 24
- 150000004696 coordination complex Chemical class 0.000 claims abstract description 20
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 9
- 238000012644 addition polymerization Methods 0.000 claims abstract description 6
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 6
- -1 cycloheteroalkyl Chemical group 0.000 claims description 253
- 238000006116 polymerization reaction Methods 0.000 claims description 160
- 238000000034 method Methods 0.000 claims description 131
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 118
- 239000003054 catalyst Substances 0.000 claims description 107
- 229910052751 metal Inorganic materials 0.000 claims description 83
- 229910052739 hydrogen Inorganic materials 0.000 claims description 80
- 239000001257 hydrogen Substances 0.000 claims description 80
- 239000002184 metal Substances 0.000 claims description 76
- 125000004429 atom Chemical group 0.000 claims description 69
- 230000008569 process Effects 0.000 claims description 65
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 57
- 239000003446 ligand Substances 0.000 claims description 47
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 43
- 239000005977 Ethylene Substances 0.000 claims description 39
- 229910052757 nitrogen Inorganic materials 0.000 claims description 37
- 125000000217 alkyl group Chemical group 0.000 claims description 34
- 229920001577 copolymer Polymers 0.000 claims description 34
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 238000009826 distribution Methods 0.000 claims description 30
- 238000012546 transfer Methods 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 29
- 230000007935 neutral effect Effects 0.000 claims description 27
- 125000000129 anionic group Chemical group 0.000 claims description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 17
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 16
- 150000007527 lewis bases Chemical group 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 230000000737 periodic effect Effects 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 229910052735 hafnium Inorganic materials 0.000 claims description 15
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 12
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- 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
- 125000000524 functional group Chemical group 0.000 claims description 11
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 11
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- 239000011574 phosphorus Substances 0.000 claims description 11
- 229920002959 polymer blend Polymers 0.000 claims description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 7
- 125000004404 heteroalkyl group Chemical group 0.000 claims description 6
- 125000001072 heteroaryl group Chemical group 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 5
- 229920000592 inorganic polymer Polymers 0.000 claims description 4
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- 125000001475 halogen functional group Chemical group 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 129
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 80
- 150000001875 compounds Chemical class 0.000 description 47
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 32
- 239000007789 gas Substances 0.000 description 31
- RUIAUVYVCXIZFV-UHFFFAOYSA-N 1-methyl-2h-isoindole Chemical compound C1=CC=CC2=C(C)NC=C21 RUIAUVYVCXIZFV-UHFFFAOYSA-N 0.000 description 27
- 238000007792 addition Methods 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 26
- 229910052799 carbon Inorganic materials 0.000 description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 22
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- 150000001450 anions Chemical class 0.000 description 21
- 239000007788 liquid Substances 0.000 description 21
- JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 21
- 239000012190 activator Substances 0.000 description 19
- 125000004122 cyclic group Chemical group 0.000 description 19
- 238000010348 incorporation Methods 0.000 description 19
- 239000000126 substance Substances 0.000 description 19
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 18
- 239000003963 antioxidant agent Substances 0.000 description 18
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 18
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 17
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000002879 Lewis base Substances 0.000 description 14
- 125000003368 amide group Chemical group 0.000 description 14
- 150000001993 dienes Chemical class 0.000 description 14
- 239000003085 diluting agent Substances 0.000 description 14
- 125000005843 halogen group Chemical group 0.000 description 14
- 125000005842 heteroatom Chemical group 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 14
- 229910052726 zirconium Inorganic materials 0.000 description 14
- 239000004711 α-olefin Substances 0.000 description 14
- 230000003213 activating effect Effects 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 13
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 13
- 229910052796 boron Inorganic materials 0.000 description 13
- 239000012986 chain transfer agent Substances 0.000 description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 229920005605 branched copolymer Polymers 0.000 description 12
- 238000007906 compression Methods 0.000 description 12
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 238000001816 cooling Methods 0.000 description 11
- 239000010408 film Substances 0.000 description 11
- 150000004820 halides Chemical class 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 11
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 10
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 10
- 238000002844 melting Methods 0.000 description 10
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- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 10
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- 239000000835 fiber Substances 0.000 description 9
- 239000008187 granular material Substances 0.000 description 9
- 229910052736 halogen Inorganic materials 0.000 description 9
- 150000002367 halogens Chemical class 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
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- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
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- 238000004458 analytical method Methods 0.000 description 7
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- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 description 7
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
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- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 6
- BZYUMXXOAYSFOW-UHFFFAOYSA-N 2,3-dimethylthiophene Chemical compound CC=1C=CSC=1C BZYUMXXOAYSFOW-UHFFFAOYSA-N 0.000 description 6
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
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- 125000003545 alkoxy group Chemical group 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
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- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 5
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 5
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- 238000000113 differential scanning calorimetry Methods 0.000 description 5
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- JQOATXDBTYKMEX-UHFFFAOYSA-N CC[Zn] Chemical compound CC[Zn] JQOATXDBTYKMEX-UHFFFAOYSA-N 0.000 description 4
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- 125000002091 cationic group Chemical group 0.000 description 4
- 238000012718 coordination polymerization Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 4
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- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 4
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 4
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- 150000004678 hydrides Chemical class 0.000 description 4
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 4
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- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 4
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- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- 239000007848 Bronsted acid Substances 0.000 description 3
- FFIMZWXRPYQJNC-UHFFFAOYSA-N C1(=CC=CC=C1)C=CC=CC1=CC=CC=C1.[Ti+2].CN([SiH]=O)C Chemical compound C1(=CC=CC=C1)C=CC=CC1=CC=CC=C1.[Ti+2].CN([SiH]=O)C FFIMZWXRPYQJNC-UHFFFAOYSA-N 0.000 description 3
- DVZWQGLVEOWFOU-UHFFFAOYSA-N C[Hf]C Chemical compound C[Hf]C DVZWQGLVEOWFOU-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- OUFDQBZHKJFNEK-UHFFFAOYSA-N N-methyl-N-oxosilylmethanamine titanium Chemical compound [Ti].CN(C)[SiH]=O OUFDQBZHKJFNEK-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 150000001639 boron compounds Chemical class 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
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- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- ILMRJRBKQSSXGY-UHFFFAOYSA-N tert-butyl(dimethyl)silicon Chemical group C[Si](C)C(C)(C)C ILMRJRBKQSSXGY-UHFFFAOYSA-N 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
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- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
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- 229920000428 triblock copolymer Polymers 0.000 description 1
- 125000004360 trifluorophenyl group Chemical group 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- ANEFWEBMQHRDLH-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl) borate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OB(OC=1C(=C(F)C(F)=C(F)C=1F)F)OC1=C(F)C(F)=C(F)C(F)=C1F ANEFWEBMQHRDLH-UHFFFAOYSA-N 0.000 description 1
- ZDMNAVSJDAXTBD-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)alumane 2-undecyl-4,5-dihydro-1H-imidazole Chemical compound CCCCCCCCCCCC1=NCCN1.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F ZDMNAVSJDAXTBD-UHFFFAOYSA-N 0.000 description 1
- NVBHDPLKAHDQDC-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)borane;2-undecyl-1h-imidazole Chemical compound CCCCCCCCCCCC1=NC=CN1.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F NVBHDPLKAHDQDC-UHFFFAOYSA-N 0.000 description 1
- MDYARPNTSPYOED-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)borane;2-undecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCC1=NCCN1.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F.FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F MDYARPNTSPYOED-UHFFFAOYSA-N 0.000 description 1
- RERMPCBBVZEPBS-UHFFFAOYSA-N tris(2,6-dimethylphenyl)phosphane Chemical compound CC1=CC=CC(C)=C1P(C=1C(=CC=CC=1C)C)C1=C(C)C=CC=C1C RERMPCBBVZEPBS-UHFFFAOYSA-N 0.000 description 1
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 1
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- 229910052720 vanadium Inorganic materials 0.000 description 1
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- 150000003752 zinc compounds Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71754405P | 2005-09-15 | 2005-09-15 | |
| US717544P | 2005-09-15 | ||
| PCT/US2006/036048 WO2007035492A1 (en) | 2005-09-15 | 2006-09-14 | Catalytic olefin block copolymers via polymerizable shuttling agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2526056T3 true ES2526056T3 (es) | 2015-01-05 |
Family
ID=37682033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06814747.9T Active ES2526056T3 (es) | 2005-09-15 | 2006-09-14 | Copolímeros de bloque de olefinas catalíticos por medio de agente de transporte polimerizable |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7858707B2 (https=) |
| EP (1) | EP1940896B1 (https=) |
| JP (2) | JP5411502B2 (https=) |
| KR (1) | KR20080055837A (https=) |
| CN (1) | CN101331163B (https=) |
| AR (1) | AR058449A1 (https=) |
| BR (1) | BRPI0617042B1 (https=) |
| CA (1) | CA2622720A1 (https=) |
| ES (1) | ES2526056T3 (https=) |
| RU (1) | RU2008110052A (https=) |
| SG (1) | SG156614A1 (https=) |
| TW (1) | TW200722441A (https=) |
| WO (1) | WO2007035492A1 (https=) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
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| AU2005224259B2 (en) * | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US8829115B2 (en) | 2009-07-01 | 2014-09-09 | Dow Global Technologies Llc | Ethylene-based polymer composition |
| US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
| CA2768987A1 (en) | 2009-07-29 | 2011-02-03 | Dow Global Technologies Llc | Multifunctional chain shuttling agents |
| JP5726873B2 (ja) * | 2009-07-29 | 2015-06-03 | ダウ グローバル テクノロジーズ エルエルシー | 二頭又は多頭連鎖シャトリング剤、及びブロックコポリマーの調製のためのそれらの使用 |
| US20110054122A1 (en) | 2009-08-31 | 2011-03-03 | Jerzy Klosin | Catalyst and process for polymerizing an olefin and polyolefin prepared thereby |
| US8202954B2 (en) | 2010-02-19 | 2012-06-19 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| ES2874670T3 (es) | 2010-02-19 | 2021-11-05 | Dow Global Technologies Llc | Proceso para polimerizar un monómero de olefina y catalizador para el mismo |
| US8609794B2 (en) | 2010-05-17 | 2013-12-17 | Dow Global Technologies, Llc. | Process for selectively polymerizing ethylene and catalyst therefor |
| US8907034B2 (en) * | 2010-09-30 | 2014-12-09 | Dow Global Technologies Llc | Comb architecture olefin block copolymers |
| WO2012061706A1 (en) | 2010-11-04 | 2012-05-10 | Dow Global Technologies Llc | Double shuttling of polyolefin polymeryl chains |
| WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
| US20140088276A1 (en) * | 2011-05-09 | 2014-03-27 | Riken | Manufacturing method for multidimensional polymer, and multidimensional polymer |
| EP3037438A1 (en) * | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a branched polyolefin |
| EP3037437A1 (en) * | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a polyolefin having one or multiple end-functionalized branches. |
| JP6779230B2 (ja) | 2015-05-11 | 2020-11-04 | ダウ グローバル テクノロジーズ エルエルシー | 改質剤を有する高メルトフロー熱可塑性ポリオレフィン |
| EP3344385A4 (en) * | 2015-08-31 | 2019-08-14 | ExxonMobil Chemical Patents Inc. | ALUMINUM ALKYLE WITH HANGING OLEFINS ON SOUND |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| JP2018525507A (ja) * | 2015-08-31 | 2018-09-06 | エクソンモービル・ケミカル・パテンツ・インク | ビニル連鎖移動剤の使用によって製造されたポリマー |
| CN107922527A (zh) * | 2015-08-31 | 2018-04-17 | 埃克森美孚化学专利公司 | 用于聚烯烃反应的具有悬垂烯烃的铝烷基 |
| US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
| US10787545B2 (en) * | 2015-12-09 | 2020-09-29 | Sabic Global Technologies B.V. | Process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains |
| US10059788B2 (en) | 2016-04-29 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | Organoaluminum activators on clays |
| US10208140B2 (en) | 2016-06-30 | 2019-02-19 | Exxonmobil Chemical Patents Inc. | Quinolinyldiamido transition metal complexes, production and use thereof |
| JP2019527679A (ja) * | 2016-06-30 | 2019-10-03 | エクソンモービル ケミカル パテンツ インコーポレイテッド | キノリニルジアミド遷移金属錯体、生成物およびその使用 |
| US10927196B2 (en) | 2016-06-30 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| WO2018005201A1 (en) * | 2016-06-30 | 2018-01-04 | Exxonmobil Chemical Patents Inc. | Quinolinyldiamido transition metal complexes, production and use thereof |
| CN106589181B (zh) * | 2016-11-15 | 2020-01-14 | 浙江大学 | 多嵌段支化聚乙烯及其制备方法 |
| WO2018160276A1 (en) * | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| WO2018160277A1 (en) * | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| US10676551B2 (en) | 2017-03-01 | 2020-06-09 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| JP7179750B2 (ja) | 2017-03-15 | 2022-11-29 | ダウ グローバル テクノロジーズ エルエルシー | マルチブロックコポリマー形成用触媒系 |
| WO2019099116A1 (en) * | 2017-11-14 | 2019-05-23 | Exxonmobil Chemical Patents Inc. | Bimodal ethylene, alpha-olefin, and diene polymers using dual organometallic catalysts |
| US11008449B2 (en) | 2017-11-14 | 2021-05-18 | Exxonmobil Chemical Patents Inc. | Bimodal ethylene, alpha-olefin, and diene polymers using dual organometallic catalysts |
| CN117986722A (zh) | 2017-12-18 | 2024-05-07 | 博里利斯股份公司 | 具有优越电性能的用于电线电缆应用的聚合物组合物 |
| CN109456445B (zh) * | 2018-09-29 | 2020-08-04 | 浙江大学 | 一种梳状丙烯基聚烯烃热塑性弹性体的制备方法 |
| CN109535323B (zh) * | 2018-09-29 | 2020-08-11 | 浙江大学 | 一种梳状丙烯基聚烯烃热塑性弹性体的制备方法 |
| US11198745B2 (en) | 2018-11-29 | 2021-12-14 | Exxonmobil Chemical Patents Inc. | Poly(alpha-olefin)s and methods thereof |
| CN110441253A (zh) * | 2019-07-22 | 2019-11-12 | 杭州华聚复合材料有限公司 | 一种快速检测PP-g-MAH接枝率的方法 |
| CN110655623A (zh) * | 2019-09-19 | 2020-01-07 | 天津大学 | 采用链穿梭聚合的方法制备无规聚丙烯-等规聚丙烯立构嵌段聚合物 |
| EP4182365A1 (en) * | 2020-07-17 | 2023-05-24 | Dow Global Technologies LLC | Hydrocarbyl-modified methylaluminoxane cocatalysts for constrained geometry procatalysts |
| CN112724343A (zh) * | 2021-01-19 | 2021-04-30 | 天津大学 | 一种聚烯烃嵌段共聚物及其制备方法 |
| CN115779962B (zh) * | 2022-10-19 | 2024-04-05 | 浙江大学 | 一种氢键供体-亲核双功能试剂和有机硼试剂组成的双组分有机催化体系及其应用 |
| CN120813615A (zh) * | 2023-03-28 | 2025-10-17 | 陶氏环球技术有限责任公司 | 用于生产支化聚烯烃的方法 |
Family Cites Families (180)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2973344A (en) * | 1957-12-11 | 1961-02-28 | Exxon Research Engineering Co | Modified polymers |
| US3970719A (en) | 1958-01-16 | 1976-07-20 | Phillips Petroleum Company | Preparation of block copolymers |
| US4039632A (en) | 1958-01-16 | 1977-08-02 | Phillips Petroleum Company | Preparation of block copolymers |
| US2997432A (en) * | 1958-08-14 | 1961-08-22 | Phillips Petroleum Co | Dyeing of 1-olefin polymers |
| US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
| US3758643A (en) | 1971-01-20 | 1973-09-11 | Uniroyal Inc | D polyolefin plastic thermoplastic blend of partially cured monoolefin copolymer rubber an |
| US3806558A (en) | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| US4104210A (en) | 1975-12-17 | 1978-08-01 | Monsanto Company | Thermoplastic compositions of high unsaturation diene rubber and polyolefin resin |
| US4146492A (en) * | 1976-04-02 | 1979-03-27 | Texaco Inc. | Lubricant compositions which exhibit low degree of haze and methods of preparing same |
| US4340684A (en) | 1977-06-13 | 1982-07-20 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
| US4250273A (en) | 1977-06-13 | 1981-02-10 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
| US4311628A (en) | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4202801A (en) | 1977-12-30 | 1980-05-13 | Uniroyal, Inc. | Thermoplastic elastomer composition |
| US4271049A (en) | 1979-09-10 | 1981-06-02 | Monsanto Company | Elastoplastic compositions of cured diene rubber and polypropylene |
| US4260661A (en) * | 1980-01-23 | 1981-04-07 | General Electric Company | Polyolefin compounds having improved heat curing stability, method of improving heat aging stability therein, an electrical conductor insulated therewith and method of forming |
| US4299931A (en) * | 1980-03-10 | 1981-11-10 | Monsanto Company | Compatibilized polymer blends |
| JPS5734145A (en) * | 1980-08-07 | 1982-02-24 | Mitsui Petrochem Ind Ltd | Ethylene-alpha-olefin copolymer composition |
| US4322027A (en) | 1980-10-02 | 1982-03-30 | Crown Zellerbach Corporation | Filament draw nozzle |
| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| NZ202251A (en) | 1981-10-22 | 1985-01-31 | Commw Austral Defence Support | Winch system:moving trolleys mounted on rails between pairs of winches |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
| US4430563A (en) | 1982-04-30 | 1984-02-07 | Minnesota Mining And Manufacturing Company | Data processing form |
| JPS5975929A (ja) * | 1982-10-25 | 1984-04-28 | Sekisui Chem Co Ltd | ポリオレフイン発泡体の製造方法 |
| CA1264880A (en) * | 1984-07-06 | 1990-01-23 | John Brooke Gardiner | Viscosity index improver - dispersant additive useful in oil compositions |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
| US4798081A (en) * | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| JPH0832734B2 (ja) * | 1986-07-08 | 1996-03-29 | 東燃株式会社 | プロピレン共重合体の製造法 |
| US5391629A (en) * | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US4797081A (en) | 1987-03-10 | 1989-01-10 | Prater Ronald E | Mandrel for making elastomeric articles |
| US5248729A (en) | 1987-12-28 | 1993-09-28 | Nippon Petrochemicals Company Limited | Process for preparing thermoplastic resin composition |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US4927882A (en) | 1988-10-11 | 1990-05-22 | The West Company, Incorporated | SBR thermoplastic elastomer |
| US5266626A (en) * | 1989-02-22 | 1993-11-30 | Norsolor | Thermoplastic elastomer based on an ethylene/α-olefin copolymer and on polynorbornene |
| US6025448A (en) * | 1989-08-31 | 2000-02-15 | The Dow Chemical Company | Gas phase polymerization of olefins |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5068047A (en) * | 1989-10-12 | 1991-11-26 | Exxon Chemical Patents, Inc. | Visosity index improver |
| FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| US5032562A (en) | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5051478A (en) | 1990-07-26 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Ethylene copolymer - modified dynamically vulcanized alloys |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5783638A (en) * | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| US5210338A (en) | 1991-10-25 | 1993-05-11 | Ethyl Corporation | Catalyzed chain growth process |
| WO1993013143A1 (en) * | 1991-12-30 | 1993-07-08 | The Dow Chemical Company | Ethylene interpolymer polymerizations |
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| JP3275078B2 (ja) | 1992-01-06 | 2002-04-15 | ザ ダウ ケミカル カンパニー | オレフィンの重合法 |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| JPH05331243A (ja) * | 1992-06-03 | 1993-12-14 | Japan Synthetic Rubber Co Ltd | 多分岐状重合体の製造方法 |
| BE1005957A5 (fr) | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
| US5276220A (en) | 1992-06-18 | 1994-01-04 | Ethyl Corporation | Actinide catalyzed chain growth process |
| TW272985B (https=) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| WO1994006859A1 (en) | 1992-09-15 | 1994-03-31 | The Dow Chemical Company | Impact modification of thermoplastics |
| US5322728A (en) * | 1992-11-24 | 1994-06-21 | Exxon Chemical Patents, Inc. | Fibers of polyolefin polymers |
| TW275076B (https=) * | 1992-12-02 | 1996-05-01 | Hoechst Ag | |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US5608019A (en) | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
| ES2206090T3 (es) | 1993-01-29 | 2004-05-16 | Dow Global Technologies Inc. | Interpolimerizaciones de etileno. |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| ES2178648T3 (es) * | 1993-02-05 | 2003-01-01 | Idemitsu Kosan Co | Polietileno, composicion de resina termoplastica que lo contiene, y procedimiento de produccion de polietileno. |
| TW298593B (https=) | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
| EP1623999A1 (en) | 1993-04-26 | 2006-02-08 | ExxonMobil Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| BE1007148A3 (fr) | 1993-05-17 | 1995-04-11 | Solvay | Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur. |
| FR2705252B1 (fr) | 1993-05-19 | 1995-07-21 | Bp Chemicals Snc | Procédé d'introduction d'un solide dans un réacteur et appareillage. |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
| JP3031142B2 (ja) * | 1993-11-01 | 2000-04-10 | 住友化学工業株式会社 | ポリプロピレン樹脂組成物 |
| JPH07144455A (ja) | 1993-11-25 | 1995-06-06 | Canon Inc | インクジェット記録装置 |
| US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
| US5672669A (en) | 1993-12-23 | 1997-09-30 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
| US5461123A (en) | 1994-07-14 | 1995-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase fluidized bed polyolefin polymerization process using sound waves |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| US6030917A (en) | 1996-07-23 | 2000-02-29 | Symyx Technologies, Inc. | Combinatorial synthesis and analysis of organometallic compounds and catalysts |
| US5550194A (en) * | 1995-01-31 | 1996-08-27 | Shell Oil Company | Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins |
| US5543458A (en) * | 1995-01-31 | 1996-08-06 | Shell Oil Company | Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| WO1996041808A1 (en) | 1995-06-08 | 1996-12-27 | Showa Denko K.K. | Ionic compounds and catalyst for olefin polymerization using the compounds |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| CN1261501C (zh) * | 1995-09-12 | 2006-06-28 | 三井化学株式会社 | 粘合的乙烯共聚物树脂组合物和含它的层压材料 |
| US6051681A (en) | 1995-11-17 | 2000-04-18 | Dsm N.V. | Process for the preparation of a thermoplastic elastomer |
| AR006240A1 (es) * | 1996-03-14 | 1999-08-11 | Fuller H B Licensing Financ | Adhesivo de fusion caliente que comprende interpolimeros, articulo no tejido que lo comprende, procedimiento de polimerizacion para preparlo y caja, envase, bandeja y libro unidos con dicho adhesivo |
| US5916953A (en) * | 1996-03-15 | 1999-06-29 | Bp Amoco Corporation | Stiff, strong, tough glass-filled olefin polymer |
| BR9708335A (pt) | 1996-03-27 | 1999-08-03 | Dow Chemical Co | Processo de polimerização em solução para polimerizar olefinas |
| CA2247506A1 (en) * | 1996-03-27 | 1997-10-02 | The Dow Chemical Company | Allyl containing metal complexes and olefin polymerization process |
| ATE194629T1 (de) | 1996-03-27 | 2000-07-15 | Dow Chemical Co | Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| DE69730718T2 (de) | 1996-08-08 | 2005-09-22 | Dow Global Technologies, Inc., Midland | Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren |
| US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
| US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
| US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| KR20000049229A (ko) | 1996-12-19 | 2000-07-25 | 그레이스 스티븐 에스. | 3-아릴 치환된 인데닐 함유 금속 착체 및 이를 이용한 중합방법 |
| US6362252B1 (en) * | 1996-12-23 | 2002-03-26 | Vladimir Prutkin | Highly filled polymer composition with improved properties |
| DE69808243T2 (de) * | 1997-02-07 | 2003-05-08 | Exxonmobil Chemical Patents Inc., Baytown | Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren |
| US5783531A (en) * | 1997-03-28 | 1998-07-21 | Exxon Research And Engineering Company | Manufacturing method for the production of polyalphaolefin based synthetic greases (LAW500) |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6319989B1 (en) | 1997-07-21 | 2001-11-20 | The Dow Chemical Company | Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom |
| WO1999007785A1 (en) * | 1997-08-08 | 1999-02-18 | The Dow Chemical Company | Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same |
| US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
| US6096668A (en) * | 1997-09-15 | 2000-08-01 | Kimberly-Clark Worldwide, Inc. | Elastic film laminates |
| US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
| ES2212348T3 (es) * | 1997-09-19 | 2004-07-16 | The Dow Chemical Company | Composicion optimizada de interpolimero de etileno con distribucion estrecha del peso molecular, procedimiento para obtenerla y articulos hechos a partir de ella. |
| US6197404B1 (en) * | 1997-10-31 | 2001-03-06 | Kimberly-Clark Worldwide, Inc. | Creped nonwoven materials |
| US6169151B1 (en) | 1998-01-09 | 2001-01-02 | The Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
| US6380341B1 (en) | 1998-01-09 | 2002-04-30 | The Board Of Trustees Of Leland Stanford Jr. University | Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof |
| AU749065B2 (en) | 1998-02-20 | 2002-06-20 | Dow Chemical Company, The | Catalyst activators comprising expanded anions |
| US6815023B1 (en) * | 1998-07-07 | 2004-11-09 | Curwood, Inc. | Puncture resistant polymeric films, blends and process |
| AU4440499A (en) | 1998-08-11 | 2000-03-06 | Dow Chemical Company, The | Ansa-group-4-metal bis (.mu.-substituted) aluminum complexes |
| US6214760B1 (en) | 1998-08-11 | 2001-04-10 | The Dow Chemical Company | Catalyst activator composition |
| US6306658B1 (en) | 1998-08-13 | 2001-10-23 | Symyx Technologies | Parallel reactor with internal sensing |
| US6316663B1 (en) | 1998-09-02 | 2001-11-13 | Symyx Technologies, Inc. | Catalyst ligands, catalytic metal complexes and processes using and methods of making the same |
| KR100565151B1 (ko) | 1999-02-04 | 2006-03-30 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 블록 공중합체 수지 및 제조 방법 |
| JP2002537302A (ja) | 1999-02-19 | 2002-11-05 | ザ ダウ ケミカル カンパニー | トリフルオロアリールアルミニウムエーテレートの製造方法 |
| US6680265B1 (en) * | 1999-02-22 | 2004-01-20 | Kimberly-Clark Worldwide, Inc. | Laminates of elastomeric and non-elastomeric polyolefin blend materials |
| AU4186500A (en) | 1999-04-01 | 2000-10-23 | Symyx Technologies, Inc. | Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and methods of making same |
| CA2368111A1 (en) | 1999-05-13 | 2000-11-23 | The Dow Chemical Company | Di- and tri-heteroatom substituted indenyl metal complexes |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| KR100714508B1 (ko) | 1999-12-10 | 2007-05-07 | 다우 글로벌 테크놀로지스 인크. | 치환된 4족 금속 착체, 촉매 및 올레핀 중합 방법 |
| US6537472B2 (en) * | 2000-02-29 | 2003-03-25 | Asahi Kasei Kabushiki Kaisha | Process for producing a cushioning article |
| US6160029A (en) * | 2000-03-08 | 2000-12-12 | The Dow Chemical Company | Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams |
| TW583266B (en) | 2000-04-27 | 2004-04-11 | Idemitsu Petrochemical Co | Polycarbonate resin composition for optical disk substrate |
| US6455638B2 (en) * | 2000-05-11 | 2002-09-24 | Dupont Dow Elastomers L.L.C. | Ethylene/α-olefin polymer blends comprising components with differing ethylene contents |
| DE60110794T2 (de) * | 2000-05-26 | 2005-10-06 | Dow Global Technologies, Inc., Midland | Pelyethylene-reiche mischungen mit polypropylene und ihre verwendung |
| RU2258712C2 (ru) * | 2000-12-04 | 2005-08-20 | Юнивейшн Технолоджиз, Ллс | Способ полимеризации |
| US20030069127A1 (en) * | 2000-12-26 | 2003-04-10 | Kazuo Takaoki | Modified particle,support, catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer |
| US20040092662A1 (en) * | 2001-03-29 | 2004-05-13 | Yasuhiro Goto | Propylene polymer composition, molded object, and polyolefin copolymer |
| US6444867B1 (en) | 2001-05-17 | 2002-09-03 | Bp Corporation North America Inc. | Process for linear alpha olefins |
| SG120869A1 (en) | 2001-05-31 | 2006-04-26 | Mitsui Chemicals Inc | Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition |
| DE10127926A1 (de) * | 2001-06-08 | 2002-12-12 | Bayer Ag | 1,3-disubstituierte Indenkomplexe |
| WO2003008497A1 (en) * | 2001-07-12 | 2003-01-30 | Idemitsu Petrochemical Co., Ltd. | Polyolefin resin composition |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| EP1444276A1 (en) * | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| EP1454931B1 (en) * | 2001-11-09 | 2018-01-24 | Japan Polypropylene Corporation | Propylene block copolymer |
| US7005395B2 (en) * | 2002-12-12 | 2006-02-28 | Invista North America S.A.R.L. | Stretchable composite sheets and processes for making |
| US6992049B2 (en) * | 2002-01-31 | 2006-01-31 | Exxonmobil Research And Engineering Company | Lubricating oil compositions |
| US6897276B2 (en) | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| US20030224623A1 (en) | 2002-05-31 | 2003-12-04 | Tohoku Pioneer Corporation | Insulating resin film and method of forming fine patterns of insulating resin film |
| US7031450B2 (en) | 2002-08-27 | 2006-04-18 | Itxl Ip Holdings, S.A.R.L. | Call routing system and method |
| EP1543014B1 (en) | 2002-09-12 | 2006-10-04 | Dow Global Technologies Inc. | Preparation of metal complexes |
| ES2399364T3 (es) * | 2002-10-02 | 2013-03-27 | Dow Global Technologies Llc | Composiciones poliméricas que comprenden un extendedor de etileno/alfa-olefina homogéneamente ramificado, de baja viscosidad |
| ES2394304T3 (es) * | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US6953764B2 (en) * | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
| WO2005021600A1 (ja) | 2003-08-27 | 2005-03-10 | Mitsui Chemicals, Inc. | 片末端官能性ポリオレフィン |
| US7622179B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof |
| US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| US7514517B2 (en) * | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
| US7803728B2 (en) * | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
| US7524911B2 (en) * | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
| US8816006B2 (en) * | 2004-03-17 | 2014-08-26 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer suitable for films |
| US7666918B2 (en) * | 2004-03-17 | 2010-02-23 | Dow Global Technologies, Inc. | Foams made from interpolymers of ethylene/α-olefins |
| US7582716B2 (en) * | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
| US7671106B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
| NZ549262A (en) * | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| US7622529B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| US7355089B2 (en) * | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| US7662881B2 (en) * | 2004-03-17 | 2010-02-16 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
| AU2005224259B2 (en) * | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US7897689B2 (en) * | 2004-03-17 | 2011-03-01 | Dow Global Technologies Inc. | Functionalized ethylene/α-olefin interpolymer compositions |
| US7504347B2 (en) * | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
| US7795321B2 (en) * | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
| US7608668B2 (en) * | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
| US7863379B2 (en) * | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
| US7671131B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
| JP5159302B2 (ja) * | 2004-03-17 | 2013-03-06 | ダウ グローバル テクノロジーズ エルエルシー | エチレンコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| US7579408B2 (en) * | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
| US7687442B2 (en) * | 2004-03-17 | 2010-03-30 | Dow Global Technologies Inc. | Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils |
| US7741397B2 (en) * | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
| US7557147B2 (en) * | 2004-03-17 | 2009-07-07 | Dow Global Technologies Inc. | Soft foams made from interpolymers of ethylene/alpha-olefins |
| CA2601376A1 (en) | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/alpha-olefins |
| AU2007325009A1 (en) * | 2006-11-30 | 2008-06-05 | Dow Global Technologies Inc. | Olefin block compositions for heavy weight stretch fabrics |
-
2006
- 2006-09-14 SG SG200906592-1A patent/SG156614A1/en unknown
- 2006-09-14 BR BRPI0617042-0A patent/BRPI0617042B1/pt active IP Right Grant
- 2006-09-14 ES ES06814747.9T patent/ES2526056T3/es active Active
- 2006-09-14 CN CN2006800340435A patent/CN101331163B/zh active Active
- 2006-09-14 CA CA002622720A patent/CA2622720A1/en not_active Abandoned
- 2006-09-14 US US12/065,867 patent/US7858707B2/en active Active
- 2006-09-14 JP JP2008531357A patent/JP5411502B2/ja active Active
- 2006-09-14 WO PCT/US2006/036048 patent/WO2007035492A1/en not_active Ceased
- 2006-09-14 KR KR1020087006334A patent/KR20080055837A/ko not_active Withdrawn
- 2006-09-14 RU RU2008110052/04A patent/RU2008110052A/ru not_active Application Discontinuation
- 2006-09-14 AR ARP060104033A patent/AR058449A1/es active IP Right Grant
- 2006-09-14 EP EP06814747.9A patent/EP1940896B1/en active Active
- 2006-09-14 TW TW095134017A patent/TW200722441A/zh unknown
-
2010
- 2010-12-23 US US12/978,006 patent/US8415434B2/en active Active
-
2011
- 2011-10-24 JP JP2011233174A patent/JP5596655B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| SG156614A1 (en) | 2009-11-26 |
| CA2622720A1 (en) | 2007-03-29 |
| RU2008110052A (ru) | 2009-09-20 |
| BRPI0617042B1 (pt) | 2018-05-15 |
| US20090163667A1 (en) | 2009-06-25 |
| CN101331163A (zh) | 2008-12-24 |
| US20110092651A1 (en) | 2011-04-21 |
| CN101331163B (zh) | 2011-03-23 |
| US8415434B2 (en) | 2013-04-09 |
| JP5411502B2 (ja) | 2014-02-12 |
| US7858707B2 (en) | 2010-12-28 |
| JP5596655B2 (ja) | 2014-09-24 |
| JP2012017475A (ja) | 2012-01-26 |
| EP1940896B1 (en) | 2014-10-22 |
| TW200722441A (en) | 2007-06-16 |
| AR058449A1 (es) | 2008-02-06 |
| BRPI0617042A2 (pt) | 2011-07-12 |
| WO2007035492A1 (en) | 2007-03-29 |
| EP1940896A1 (en) | 2008-07-09 |
| KR20080055837A (ko) | 2008-06-19 |
| JP2009509002A (ja) | 2009-03-05 |
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