ES2513593T3 - Siloxano provisto de grupos terminales hidroxi, copolímero de polisiloxano - policarbonato, y procedimientos de preparación de éstos - Google Patents

Siloxano provisto de grupos terminales hidroxi, copolímero de polisiloxano - policarbonato, y procedimientos de preparación de éstos Download PDF

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Publication number
ES2513593T3
ES2513593T3 ES11762939.4T ES11762939T ES2513593T3 ES 2513593 T3 ES2513593 T3 ES 2513593T3 ES 11762939 T ES11762939 T ES 11762939T ES 2513593 T3 ES2513593 T3 ES 2513593T3
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group
independently
ranging
carbon atoms
polysiloxane
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ES11762939.4T
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English (en)
Inventor
Sun Mi Kim
Jae Hyun Kim
Kyung Moo Shin
Sung Hwan Cho
Whan Gi Kim
Dong Wan Seo
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Samyang Corp
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Samyang Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/186—Block or graft polymers containing polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/452—Block-or graft-polymers containing polysiloxane sequences containing nitrogen-containing sequences
    • C08G77/455—Block-or graft-polymers containing polysiloxane sequences containing nitrogen-containing sequences containing polyamide, polyesteramide or polyimide sequences

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Silicon Polymers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

Un siloxano provisto de grupos terminales hidroxi, de la siguiente fórmula química 1. **Fórmula** en donde, en la anterior fórmula química 1, R1, representa, de una forma independiente, un átomo de hidrógeno, un átomo de halógeno, un grupo hidroxi, un grupo alquilo, un grupo alcoxi ó un grupo arilo. R2, representa, de una forma independiente, un grupo hidrocarburo, el cual tiene un número de átomos de carbono que va de 1 a 13, ó un grupo hidroxi, Re, representa, de una forma independiente, un grupo alquileno, el cual tiene un número de átomos de carbono que va de 2 a 8. A, es X ó NH-X-NH, en donde, X, representa un grupo alifático, lineal o ramificado, el cual tiene un número de átomos de carbono, que va de 1 a 20, un grupo cicloalquileno, un grupo arileno mono- ó policíclíco, el cual tiene un número de átomos de carbono que va de 6 a 30, y el cual se encuentra insustituido o sustituido con un átomo de halógeno, un grupo alquilo, un grupo alcoxi, un grupo arilo ó un grupo carboxi. m, representa, de una forma independiente, un número entero que va de 0 a 4, y n, representa, de una forma independiente, un número entero que va de 2 a 1.000.

Description

imagen1
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E11762939
08-10-2014
copolímero de polisiloxano – policarbonato preparado, se midieron y éstas de encuentran recopiladas en la siguiente Tabla 3.
Ejemplo comparativo 5
5 Mediante la utilización de un porcentaje del 15 %, en peso, del siloxano provisto de grupos terminales hidroxi, el cual tiene la anterior fórmula química 10, se procedió a preparar el copolímero de polisiloxano – policarbonato, de la misma forma que la correspondiente al procedimiento llevado a cabo en el Ejemplo 16. Las propiedades del copolímero de polisiloxano – policarbonato preparado, se midieron y éstas de encuentran recopiladas en la
10 siguiente Tabla 3.
Tabla 2
Propiedades
Ejemplos
16
17 18 19 20 21 22 23 24 25 26
Cantidad de siloxano (% en peso)
1 5 7 10 15 5 5 5 5 5 5
Peso molecular medio medido por viscosidad (Mv)
32000 30500 31800 29500 29600 30300 31700 30400 31000 31.800 31300
Resis . al impa cto (Kgc m / cm)
Tem. amb. 84 84 86 87 83 84 82 83 84 82 81
-50°C
34 59 60 62 59 58 58 57 59 52 53
Transmitanci a (%)
90 82 81 78 73 81 83 82 81 81 80
Opacidad (%)
2 27 29 32 39 25 27 24 28 26 24
Ca ntidad de abr asió n (m g)
12 horas 7 6 4 4 5 6 7 6 6 5 7
24 horas
16 14 11 11 13 14 15 14 15 13 14
48 horas
32 27 25 23 26 27 30 31 27 25 32
15 Tabla 3
Propiedades
Ejemplos comparativos
9
3 4 5
Cantidad de siloxano (% en peso)
0 5 10 15
Peso molecular medio medido por viscosidad (Mv)
31200 30500 30200 30800
Resis. al impacto (Kgcm /
Temp. amb. 85 83 79 77
-50°C
20 57 60 58
17
imagen16

Claims (1)

  1. imagen1
    imagen2
ES11762939.4T 2010-03-29 2011-02-23 Siloxano provisto de grupos terminales hidroxi, copolímero de polisiloxano - policarbonato, y procedimientos de preparación de éstos Active ES2513593T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20100027893 2010-03-29
KR1020100027893A KR101289201B1 (ko) 2010-03-29 2010-03-29 에스테르 결합을 갖는 히드록시 말단 실록산, 폴리실록산-폴리카보네이트 공중합체 및 그 제조 방법
PCT/KR2011/001254 WO2011122767A2 (ko) 2010-03-29 2011-02-23 히드록시 말단 실록산, 폴리실록산-폴리카보네이트 공중합체 및 그 제조 방법

Publications (1)

Publication Number Publication Date
ES2513593T3 true ES2513593T3 (es) 2014-10-27

Family

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Country Status (7)

Country Link
US (1) US8802804B2 (es)
EP (1) EP2554571B1 (es)
JP (1) JP5576552B2 (es)
KR (1) KR101289201B1 (es)
CN (1) CN102822241B (es)
ES (1) ES2513593T3 (es)
WO (1) WO2011122767A2 (es)

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Publication number Publication date
KR20110108610A (ko) 2011-10-06
EP2554571B1 (en) 2014-07-23
WO2011122767A2 (ko) 2011-10-06
WO2011122767A3 (ko) 2012-01-12
CN102822241A (zh) 2012-12-12
JP2013523938A (ja) 2013-06-17
EP2554571A2 (en) 2013-02-06
EP2554571A4 (en) 2013-10-30
CN102822241B (zh) 2014-10-08
KR101289201B1 (ko) 2013-07-29
US8802804B2 (en) 2014-08-12
JP5576552B2 (ja) 2014-08-20
US20120309922A1 (en) 2012-12-06

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