ES2496180T3 - Complejos catalíticos bimetálicos para la copolimerización de dióxido de carbono y un epóxido - Google Patents

Complejos catalíticos bimetálicos para la copolimerización de dióxido de carbono y un epóxido Download PDF

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ES2496180T3
ES2496180T3 ES09735513.5T ES09735513T ES2496180T3 ES 2496180 T3 ES2496180 T3 ES 2496180T3 ES 09735513 T ES09735513 T ES 09735513T ES 2496180 T3 ES2496180 T3 ES 2496180T3
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ch3oh
iii
epoxide
copolymerization
carbon dioxide
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Charlotte K Williams
Michael Kember
Paul Knight
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Ip2ipo Innovations Ltd
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Imperial Innovations Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B01J31/1835—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/54—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton
    • C07C217/56—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton with amino groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by carbon chains not further substituted by singly-bound oxygen atoms
    • C07C217/58—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton with amino groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by carbon chains not further substituted by singly-bound oxygen atoms with amino groups and the six-membered aromatic ring, or the condensed ring system containing that ring, bound to the same carbon atom of the carbon chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polyethers (AREA)

Abstract

Un catalizador de fórmula (I)**Fórmula** donde R1 y R2 son independientemente hidrógeno, alquilo, haloalquilo, arilo, haluro, amina, un grupo nitro, un grupo éter, un grupo sililéter, un grupo nitrilo o un grupo acetilido; R3 es alquileno, arileno o cicloalquileno; R4 es H, alquilo, arilo o alquilarilo; E1 es C, E2 es O; X es OCOCH3, OCOCF3, OSO2C7H7, OSO(CH3)2, alquilo, alcoxi, haluro o amido; y M es Zn(II), Cr(II), Co(II), Mn(II), Mg(II), Fe(II), Cr(III)-X, Co(III)-X, Mn(III)-X o Fe(III)-X donde el compuesto no es: [Co2 LCl2(CH3OH)2]·H2O, [Co2 LBr2(CH3OH)2]·H2O, [Mn2 LCl2(CH3OH)2]·H2O, [Mn2 LBr2(CH3OH)2]·H2O, [CoIICoIIILCl2Br(CH3OH)]·0.5CH2Cl2, [MnIIMnIIILCl2Br(CH3OH)], [FeIICoIIL(μ-OAc)(OAc)(H2O)] donde L es**Fórmula**

Description

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Claims (1)

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ES09735513.5T 2008-04-25 2009-04-24 Complejos catalíticos bimetálicos para la copolimerización de dióxido de carbono y un epóxido Active ES2496180T3 (es)

Applications Claiming Priority (3)

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GBGB0807607.7A GB0807607D0 (en) 2008-04-25 2008-04-25 Catalyst
GB0807607 2008-04-25
PCT/GB2009/001043 WO2009130470A1 (en) 2008-04-25 2009-04-24 Bimetallic catalytic complexes for the copolymerisation of carbon dioxide and an epoxide

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ES2496180T3 true ES2496180T3 (es) 2014-09-18

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US (3) US9453104B2 (es)
EP (1) EP2285490B1 (es)
JP (2) JP5681096B2 (es)
AU (1) AU2009239767B2 (es)
ES (1) ES2496180T3 (es)
GB (1) GB0807607D0 (es)
PL (1) PL2285490T3 (es)
WO (1) WO2009130470A1 (es)

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
US7858729B2 (en) 2008-05-29 2010-12-28 Novomer, Inc. Methods of controlling molecular weight distribution of polymers and compositions thereof
JP2011195635A (ja) * 2010-03-17 2011-10-06 Univ Of Tokyo 二核金属錯体、および当該二核金属錯体を用いたポリカルボナートの製造方法
WO2012037282A2 (en) 2010-09-14 2012-03-22 Novomer, Inc. Catalysts and methods for polymer synthesis
GB201111928D0 (en) 2011-07-12 2011-08-24 Norner As Process
GB201111929D0 (en) 2011-07-12 2011-08-24 Norner As Polycarbonat blends
CN103842082B (zh) * 2011-08-08 2017-07-18 诺沃梅尔公司 聚合物合成的催化剂和方法
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
GB201402109D0 (en) * 2014-02-07 2014-03-26 Imp Innovations Ltd Catalyst
SG11201700229VA (en) * 2014-07-22 2017-02-27 Econic Technologies Ltd Catalysts
DE102014215384A1 (de) 2014-08-05 2016-02-11 Evonik Degussa Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215383B4 (de) 2014-08-05 2020-06-10 Evonik Operations Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215380B4 (de) 2014-08-05 2022-04-28 Evonik Operations Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215382A1 (de) 2014-08-05 2016-02-11 Evonik Degussa Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215387B4 (de) 2014-08-05 2020-06-10 Evonik Operations Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215388A1 (de) 2014-08-05 2016-02-11 Evonik Degussa Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215381B4 (de) 2014-08-05 2020-06-10 Evonik Operations Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
ES2845608T3 (es) 2015-03-03 2021-07-27 Evonik Operations Gmbh Producción de capas de poliuretano porosas
EP3067376A1 (de) 2015-03-11 2016-09-14 Evonik Degussa GmbH Herstellung von Polyurethansystemen unter Einsatz von Polyetherpolycarbonatpolyolen
EP3078696A1 (de) 2015-04-08 2016-10-12 Evonik Degussa GmbH Herstellung emissionsarmer polyurethane
CN107849233B (zh) 2015-06-15 2020-01-17 阿卜杜拉国王科技大学 制备聚碳酸酯的方法以及用于控制聚合物组成的方法
EP3115389B1 (de) 2015-07-07 2020-04-01 Evonik Operations GmbH Herstellung von polyurethanschaum
GB201514506D0 (en) 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
GB201515350D0 (en) * 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
EP3464418B1 (en) * 2016-05-27 2020-11-18 DSM IP Assets B.V. Polymers, processes, compositions & uses
CN110234678B (zh) * 2016-11-11 2022-06-03 陶氏环球技术有限责任公司 通过二氧化碳和环氧乙烷的共聚制备聚碳酸酯多元醇的半分批工艺
GB201703324D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
WO2019001712A1 (en) 2017-06-29 2019-01-03 Georg-August-Universitaet Goettingen Stiftung Oeffentlichen Rechts NEW TRIDENTED CATALYSTS FOR POLYMERIZATION
EP3459984A1 (de) 2017-09-25 2019-03-27 Evonik Degussa GmbH Herstellung von polyurethanschaum
US11753503B2 (en) 2018-05-17 2023-09-12 King Abdullah University Of Science And Technology Supported onium salts as initiators for the synthesis of polycarbonates by copolymerization of CO2 with epoxides
KR20210070319A (ko) 2018-09-24 2021-06-14 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 블록 공중합체 및 이의 방법
ES2898877T3 (es) 2019-01-07 2022-03-09 Evonik Operations Gmbh Producción de espuma dura de poliuretano
EP3908617B1 (de) 2019-01-07 2024-07-17 Evonik Operations GmbH Herstellung von polyurethanhartschaum
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
EP3744745A1 (de) 2019-05-28 2020-12-02 Evonik Operations GmbH Herstellung von pu-schaumstoffen
EP3805285B1 (de) 2019-10-08 2024-07-10 Evonik Operations GmbH Herstellung von polyurethanhartschaum
EP3865527A1 (de) 2020-02-14 2021-08-18 Evonik Operations GmbH Herstellung von pu-schaumstoffen
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
EP3919539A1 (de) 2020-06-04 2021-12-08 Evonik Operations GmbH Herstellung von polyurethanschaum
US20220056231A1 (en) 2020-08-20 2022-02-24 Evonik Operations Gmbh Production of polyurethane foam
US20220106432A1 (en) 2020-10-07 2022-04-07 Evonik Operations Gmbh Shaped flexible pu foam articles
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
US20240043646A1 (en) 2020-12-08 2024-02-08 Evonik Operations Gmbh Production of polyurethane foam
WO2022184543A1 (de) 2021-03-02 2022-09-09 Evonik Operations Gmbh Herstellung von polyurethanschaum
US20240209138A1 (en) 2021-04-14 2024-06-27 Evonik Operations Gmbh Production of hard polyurethane or polyisocyanurate foam
WO2022263273A1 (en) 2021-06-17 2022-12-22 Evonik Operations Gmbh Shaped flexible pu foam articles
JP2024526111A (ja) 2021-07-01 2024-07-17 エボニック オペレーションズ ゲーエムベーハー 硬質ポリウレタンまたはポリイソシアヌレート発泡体の製造
US20240309145A1 (en) 2021-07-02 2024-09-19 Evonik Operations Gmbh Production of pu foams
WO2023017276A1 (en) 2021-08-11 2023-02-16 Econic Technologies Ltd Method for preparing surfactants by copolymerisation of epoxides and co2 using a mixture of a macrocyclic bimetal catalyst and a double metal cyanide catalyst
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
WO2023161253A1 (en) 2022-02-22 2023-08-31 Evonik Operations Gmbh Use of recycled polyol from amine-based hydrolysis process to produce pu foam
WO2023222400A1 (de) 2022-05-17 2023-11-23 Evonik Operations Gmbh Herstellung von polyurethanschaum
EP4299656A1 (de) 2022-07-01 2024-01-03 Evonik Operations GmbH Herstellung von propoxylierten benzoldicarbonsäureamiden und dem entsprechenden polyurethanschaum
GB2626546A (en) 2023-01-25 2024-07-31 Econic Tech Ltd Surface-active agent
GB2626989A (en) 2023-02-10 2024-08-14 Econic Tech Ltd Surface-active agent

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565845A (en) 1984-09-05 1986-01-21 Hitachi Chemical Company, Ltd. Process for producing polyester and block copolymer thereof
JPS6164721A (ja) 1984-09-05 1986-04-03 Hitachi Chem Co Ltd ブロツクコポリマ−の製造方法
JPS63280086A (ja) * 1987-05-12 1988-11-17 Hiroyoshi Shirai 複核錯体またはその塩体およびラングミュア・ブロジェット膜
US20060223973A1 (en) 2005-03-29 2006-10-05 Basf Corporation Method of forming a polyethercarbonate polyol
JP2008081518A (ja) * 2006-09-25 2008-04-10 Tokyo Univ Of Science アルキレンオキシドと二酸化炭素の共重合体の製造方法、及び共重合体
RU2355694C2 (ru) 2007-04-20 2009-05-20 Игорь Леонидович Федюшкин Катализатор получения полилактидов и способ его синтеза
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
WO2009137540A1 (en) 2008-05-09 2009-11-12 Cornell University Polymers of ethylene oxide and carbon dioxide
KR101774533B1 (ko) 2008-09-08 2017-09-04 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물
WO2010110460A1 (ja) 2009-03-27 2010-09-30 国立大学法人名古屋大学 ラクチド・ε－カプロラクトン共重合体の製造方法
WO2012019405A1 (zh) 2010-08-13 2012-02-16 浙江大学 一种金属氰化物配位催化剂及其制备方法和应用
WO2012037282A2 (en) 2010-09-14 2012-03-22 Novomer, Inc. Catalysts and methods for polymer synthesis
BR112013012108A2 (pt) 2010-11-18 2017-11-07 Saudi Basic Ind Corp processo para a preparação de um poliéster
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
KR101491119B1 (ko) 2012-09-28 2015-02-10 부산대학교 산학협력단 폴리카보네이트의 제조방법
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
GB201402109D0 (en) 2014-02-07 2014-03-26 Imp Innovations Ltd Catalyst
SG11201700229VA (en) 2014-07-22 2017-02-27 Econic Technologies Ltd Catalysts
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols

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AU2009239767B2 (en) 2014-05-15
US20110118435A1 (en) 2011-05-19
US9453104B2 (en) 2016-09-27
US9994675B2 (en) 2018-06-12
US10308762B2 (en) 2019-06-04
EP2285490B1 (en) 2014-06-11
AU2009239767A1 (en) 2009-10-29
PL2285490T3 (pl) 2014-11-28
US20170247508A1 (en) 2017-08-31
JP2011518911A (ja) 2011-06-30
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EP2285490A1 (en) 2011-02-23
US20150051370A1 (en) 2015-02-19

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