ES2398109T3 - Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas - Google Patents
Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas Download PDFInfo
- Publication number
- ES2398109T3 ES2398109T3 ES06786741T ES06786741T ES2398109T3 ES 2398109 T3 ES2398109 T3 ES 2398109T3 ES 06786741 T ES06786741 T ES 06786741T ES 06786741 T ES06786741 T ES 06786741T ES 2398109 T3 ES2398109 T3 ES 2398109T3
- Authority
- ES
- Spain
- Prior art keywords
- ethylene
- silane
- olefin polymer
- grafted
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 251
- 239000000203 mixture Substances 0.000 title claims abstract description 236
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 235
- 229920000642 polymer Polymers 0.000 title claims description 136
- 150000001336 alkenes Chemical class 0.000 title description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 190
- 239000005977 Ethylene Substances 0.000 claims abstract description 190
- 229920000098 polyolefin Polymers 0.000 claims abstract description 169
- 239000004711 α-olefin Substances 0.000 claims abstract description 49
- 239000000155 melt Substances 0.000 claims abstract description 34
- 229920000573 polyethylene Polymers 0.000 claims abstract description 30
- 238000009826 distribution Methods 0.000 claims abstract description 29
- -1 aralkoxy group Chemical group 0.000 claims description 64
- 239000003999 initiator Substances 0.000 claims description 37
- 239000001993 wax Substances 0.000 claims description 36
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- 239000003921 oil Substances 0.000 claims description 30
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 24
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 19
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 18
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 15
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 11
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 8
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 8
- 150000001993 dienes Chemical class 0.000 claims description 7
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical class C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 4
- OOVQLEHBRDIXDZ-UHFFFAOYSA-N 7-ethenylbicyclo[4.2.0]octa-1,3,5-triene Chemical class C1=CC=C2C(C=C)CC2=C1 OOVQLEHBRDIXDZ-UHFFFAOYSA-N 0.000 claims description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 4
- 150000004291 polyenes Chemical class 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 150000003440 styrenes Chemical class 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- 125000004423 acyloxy group Chemical group 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229920005638 polyethylene monopolymer Polymers 0.000 claims description 2
- 229920001384 propylene homopolymer Polymers 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 description 74
- 239000000853 adhesive Substances 0.000 description 73
- 239000011347 resin Substances 0.000 description 61
- 229920005989 resin Polymers 0.000 description 61
- 239000000523 sample Substances 0.000 description 55
- 229920000578 graft copolymer Polymers 0.000 description 41
- 238000009472 formulation Methods 0.000 description 34
- 229920001577 copolymer Polymers 0.000 description 29
- 238000012360 testing method Methods 0.000 description 29
- 238000002360 preparation method Methods 0.000 description 25
- 238000000034 method Methods 0.000 description 22
- 239000003054 catalyst Substances 0.000 description 20
- 150000002978 peroxides Chemical class 0.000 description 20
- 239000004698 Polyethylene Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 13
- 239000003963 antioxidant agent Substances 0.000 description 13
- 229920005601 base polymer Polymers 0.000 description 13
- 238000004132 cross linking Methods 0.000 description 13
- 229920001155 polypropylene Polymers 0.000 description 13
- 239000004831 Hot glue Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 11
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 10
- 238000005481 NMR spectroscopy Methods 0.000 description 9
- 238000000113 differential scanning calorimetry Methods 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 8
- 150000004756 silanes Chemical class 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 239000002655 kraft paper Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 6
- 229920001112 grafted polyolefin Polymers 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 6
- 239000004700 high-density polyethylene Substances 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 239000012943 hotmelt Substances 0.000 description 5
- 229920006270 hydrocarbon resin Polymers 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 239000003209 petroleum derivative Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000008240 homogeneous mixture Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 239000012968 metallocene catalyst Substances 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229920006132 styrene block copolymer Polymers 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical class CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
- 239000005041 Mylar™ Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- 239000011093 chipboard Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000012973 diazabicyclooctane Substances 0.000 description 3
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000011135 tin Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 2
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004821 Contact adhesive Substances 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000001769 aryl amino group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 150000001925 cycloalkenes Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 239000012933 diacyl peroxide Substances 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- QPFMBZIOSGYJDE-QDNHWIQGSA-N 1,1,2,2-tetrachlorethane-d2 Chemical compound [2H]C(Cl)(Cl)C([2H])(Cl)Cl QPFMBZIOSGYJDE-QDNHWIQGSA-N 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- VYWRBUBXZALATG-UHFFFAOYSA-N 2-hydroxyoctadecanamide Chemical compound CCCCCCCCCCCCCCCCC(O)C(N)=O VYWRBUBXZALATG-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- RFSCGDQQLKVJEJ-UHFFFAOYSA-N 2-methylbutan-2-yl benzenecarboperoxoate Chemical compound CCC(C)(C)OOC(=O)C1=CC=CC=C1 RFSCGDQQLKVJEJ-UHFFFAOYSA-N 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- UGJCILYXGIEERK-UHFFFAOYSA-N 2-tert-butylperoxy-1,3-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(C(C)C)=C1OOC(C)(C)C UGJCILYXGIEERK-UHFFFAOYSA-N 0.000 description 1
- VFTWMPNBHNNMAV-UHFFFAOYSA-N 2-tert-butylperoxy-1,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(C(C)C)C(OOC(C)(C)C)=C1 VFTWMPNBHNNMAV-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 239000004169 Hydrogenated Poly-1-Decene Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 241000845082 Panama Species 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 235000019383 crystalline wax Nutrition 0.000 description 1
- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 150000004757 linear silanes Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000001374 small-angle light scattering Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002235 transmission spectroscopy Methods 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Laminated Bodies (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69818305P | 2005-07-11 | 2005-07-11 | |
| US698183P | 2005-07-11 | ||
| PCT/US2006/026689 WO2007008765A2 (en) | 2005-07-11 | 2006-07-10 | Silane-grafted olefin polymers, compositions and articles prepared therefrom, and methods for making the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2398109T3 true ES2398109T3 (es) | 2013-03-13 |
Family
ID=37402648
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06786741T Active ES2398109T3 (es) | 2005-07-11 | 2006-07-10 | Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas |
| ES11182251.6T Active ES2490990T3 (es) | 2005-07-11 | 2006-07-10 | Composiciones que comprenden polímeros de olefina injertados con silano |
| ES11182252.4T Active ES2508140T3 (es) | 2005-07-11 | 2006-07-10 | Composiciones que comprenden una mezcla de polímeros de olefina injertados con silano |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11182251.6T Active ES2490990T3 (es) | 2005-07-11 | 2006-07-10 | Composiciones que comprenden polímeros de olefina injertados con silano |
| ES11182252.4T Active ES2508140T3 (es) | 2005-07-11 | 2006-07-10 | Composiciones que comprenden una mezcla de polímeros de olefina injertados con silano |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9012563B2 (cg-RX-API-DMAC7.html) |
| EP (3) | EP2407496B1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP5551360B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101369090B1 (cg-RX-API-DMAC7.html) |
| CN (2) | CN104341704B (cg-RX-API-DMAC7.html) |
| AR (1) | AR057447A1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2006269238B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0615500B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2615702A1 (cg-RX-API-DMAC7.html) |
| ES (3) | ES2398109T3 (cg-RX-API-DMAC7.html) |
| TW (1) | TW200706621A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2007008765A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE500281T1 (de) | 2005-12-29 | 2011-03-15 | Dow Global Technologies Inc | Niedermolekulare ethylen-mischpolymere, herstellungsverfahren dafür und verwendungen davon |
| JP5291457B2 (ja) * | 2006-03-31 | 2013-09-18 | 三井化学株式会社 | 熱可塑性重合体組成物、熱可塑性重合体組成物の製造方法、熱可塑性重合体組成物から得られる成形体および電線 |
| EP2363420B1 (en) | 2006-06-15 | 2012-12-12 | Dow Global Technologies LLC | Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same |
| TW200842148A (en) * | 2007-04-24 | 2008-11-01 | Univ Far East | Composite material produced from recycled thermosetting plastic flour and preparing method thereof |
| EP2075297B1 (de) * | 2007-12-04 | 2010-02-24 | Sika Technology AG | Heissschmelzklebstoff mit guter Haftung auf Polyolefinen |
| US8785553B2 (en) | 2007-12-04 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Moisture curable propylene-α-olefin copolymers |
| US8546481B2 (en) * | 2008-01-30 | 2013-10-01 | Idemitsu Kosan Co., Ltd. | Aqueous dispersion containing polyolefin graft copolymer |
| WO2009107690A1 (ja) * | 2008-02-29 | 2009-09-03 | 住友化学株式会社 | 変性オレフィン重合体の製造方法 |
| JP5555410B2 (ja) * | 2008-03-14 | 2014-07-23 | 出光興産株式会社 | ポリオレフィン系グラフト共重合体および接着剤組成物 |
| EP2113545A1 (de) * | 2008-04-28 | 2009-11-04 | Sika Technology AG | Heissschmelzklebstoffe mit verlängerter Offenzeit |
| DE102008002163A1 (de) * | 2008-06-02 | 2009-12-03 | Wacker Chemie Ag | Bindemittel auf der Basis von alpha-silangruppenhaltigen Polymeren |
| GB0812186D0 (en) | 2008-07-03 | 2008-08-13 | Dow Corning | Modified polyolefins |
| GB0812185D0 (en) | 2008-07-03 | 2008-08-13 | Dow Corning | Polymers modified by silanes |
| DE102008041281A1 (de) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Silanmodifizierte Polyolefine mit hohem Erweichungspunkt |
| DE102008041278A1 (de) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Verwendung von Polyolefinen als Haftvermittler für die Herstellung flächiger Laminate |
| DE102008041279A1 (de) * | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Silanmodifizierte Polyolefine mit hohem Funktionalisierungsgrad |
| DE102008041277A1 (de) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Silanmodifizierte Polyolefine |
| DE102009001886A1 (de) | 2009-03-26 | 2010-10-07 | Evonik Degussa Gmbh | Haftvermittler zum Beschichten von Polyolefin-Oberflächen basierend auf Polyolefin-graft-poly(meth)acrylat Copolymeren |
| DE102009001885A1 (de) | 2009-03-26 | 2010-09-30 | Evonik Degussa Gmbh | Grundierungsmittel für Polyolefin-Oberflächen basierend auf Polyolefin-graft-poly(meth)acrylat Copolymeren |
| EP2430096B1 (en) | 2009-05-07 | 2015-06-24 | Shell Internationale Research Maatschappij B.V. | Binder composition and asphalt mixture |
| KR101448314B1 (ko) * | 2009-05-15 | 2014-10-08 | 주식회사 엘지화학 | 봉지재 시트, 이의 제조방법 및 이를 포함하는 태양전지 모듈 |
| DE102009027445A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
| DE102009027447A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
| DE102009027446A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
| WO2011005852A1 (en) * | 2009-07-08 | 2011-01-13 | Dow Global Technologies Inc. | Silane-coupled propylene-based polymer and method |
| DE102009028353A1 (de) * | 2009-08-07 | 2011-04-14 | Wacker Chemie Ag | Bindemittel auf der Basis von silangruppenhaltigen hochverzweigten Polyolefinen |
| US8609231B2 (en) * | 2009-12-17 | 2013-12-17 | Dow Global Technologies Llc | Composite laminates and uses thereof |
| ATE555178T1 (de) * | 2009-12-18 | 2012-05-15 | Sika Technology Ag | Heissschmelzklebstoffzusammensetzungen mit guter haftung sowohl auf polaren als auch apolaren substraten |
| GB201000117D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Organopolysiloxanes containing an unsaturated group |
| GB201000121D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Modified polyolefins |
| GB201000120D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Process for forming crosslinked and branched polymers |
| US20120172510A1 (en) * | 2010-12-30 | 2012-07-05 | Union Carbide Chemicals & Plastics Technology Llc | Moisture crosslinkable polyethylene composition |
| WO2012124345A1 (ja) * | 2011-03-16 | 2012-09-20 | 出光興産株式会社 | 反応性ポリオレフィン、その製造方法、及びそれを含む組成物 |
| US20140007940A1 (en) * | 2011-03-31 | 2014-01-09 | Shaofu Wu | Light transmitting thermoplastic resins comprising down conversion material and their use in photovoltaic modules |
| SG10201700173TA (en) * | 2011-12-14 | 2017-03-30 | Dow Global Technologies Llc | Functionalized block composite and crystalline block composite compositions |
| JP6055609B2 (ja) * | 2012-04-27 | 2016-12-27 | ヘンケルジャパン株式会社 | 電力機器用ホットメルト接着剤 |
| ES2654465T3 (es) | 2012-09-11 | 2018-02-13 | Sika Technology Ag | Adhesivo termoplástico de poliolefina reactivo para empleo como revestimiento previo reactivable |
| WO2014040271A1 (en) * | 2012-09-14 | 2014-03-20 | Dow Global Technologies Llc | Composition containing a low viscosity ethylene/alpha-olefin copolymer or a low viscosity functionalized ethylene/alpha-olefin copolymer |
| EP2730626A1 (de) | 2012-11-12 | 2014-05-14 | Sika Technology AG | Reaktiver Polyolefin-Heissschmelzklebstoff mit geringer Haftung zu nichtbeschichteten Aluminiumwerkzeugen und dessen Verwendung als Kaschier-Hotmelt |
| BR112015011243B1 (pt) | 2012-12-07 | 2020-03-03 | Dow Global Technologies Llc | Formulação para cuidado pessoal, e, método para melhorar a sensação de formulações para cuidado pessoal |
| WO2014099256A2 (en) * | 2012-12-19 | 2014-06-26 | Dow Global Technologies Llc | Silicon-containing polyolefins in personal care applications |
| KR102196688B1 (ko) * | 2012-12-31 | 2020-12-31 | 다우 글로벌 테크놀로지스 엘엘씨 | 실란 그라프트된 올레핀 블록 공중합체를 함유하는 감압성 접착제 조성물 |
| CN105209002A (zh) * | 2013-05-10 | 2015-12-30 | 宝洁公司 | 包含硅烷改性的油的消费产品 |
| US10040888B1 (en) * | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
| BR112016001169B1 (pt) | 2013-07-24 | 2022-01-04 | Dow Global Technologies Llc | Composição e artigo |
| US10100139B2 (en) | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
| CN105764976B (zh) * | 2013-10-30 | 2017-08-18 | 株式会社Lg化学 | 烯烃树脂 |
| JP6736465B2 (ja) * | 2013-12-30 | 2020-08-05 | ダウ グローバル テクノロジーズ エルエルシー | 官能化低粘度エチレン系ポリマーを生成するための方法 |
| EP3112415B1 (en) * | 2014-02-26 | 2020-09-30 | LG Chem, Ltd. | Encapsulation material for optical module, method for manufacturing same, and optical module |
| CN111853380A (zh) | 2014-07-02 | 2020-10-30 | 库博标准汽车配件有限公司 | 软管、耐磨组合物和软管制造工艺 |
| WO2016056635A1 (ja) * | 2014-10-08 | 2016-04-14 | 古河電気工業株式会社 | 架橋樹脂成形体及び架橋性樹脂組成物とそれらの製造方法、シランマスターバッチ、並びに、成形品 |
| CN107922517B (zh) * | 2015-09-25 | 2022-02-08 | 陶氏环球技术有限责任公司 | 用于使低粘度聚烯烃官能化的非挤出工艺 |
| JP6735772B2 (ja) * | 2015-12-07 | 2020-08-05 | 株式会社Moresco | ホットメルト組成物、ホットメルト組成物の製造方法、シール材、電子装置、及び灯具 |
| US10975272B2 (en) | 2015-12-07 | 2021-04-13 | Moresco Corporation | Hot melt composition, hot melt composition production method, seal material, electronic device, and lamp |
| BR112018069435A2 (pt) | 2016-06-03 | 2019-02-12 | Borealis Ag | composição de polímero de etileno, artigo, e, processo para produzir um artigo. |
| EP3287276A1 (en) * | 2016-08-26 | 2018-02-28 | Sika Technology Ag | Reactive polyolefin hot-melt adhesive with lower reactivation temperature and use thereof in deep draw vacuum lamination |
| KR102291384B1 (ko) | 2016-09-27 | 2021-08-20 | 코오롱인더스트리 주식회사 | 경화 가능한 변성 석유수지, 이의 제조방법 및 이의 용도 |
| WO2018107118A1 (en) | 2016-12-10 | 2018-06-14 | Cooper-Standard Automotive Inc. | Polyolefin elastomer compositions and methods of making the same |
| CN110291168A (zh) | 2016-12-10 | 2019-09-27 | 库珀标准汽车公司 | 微致密密封件、制造其的组合物和方法 |
| CN108359097B (zh) * | 2017-01-26 | 2020-11-10 | 中国石油化工股份有限公司 | 一种乙烯与端烯基硅烷/硅氧烷的共聚方法 |
| EP3665210B1 (en) | 2017-07-25 | 2022-02-23 | Dow Silicones Corporation | Method for preparing a graft copolymer with a polyolefin backbone and polyorganosiloxane pendant groups |
| WO2019115723A1 (en) | 2017-12-15 | 2019-06-20 | Byk-Chemie Gmbh | Thermoplastic composition having improved flame retardant properties |
| JP6782222B2 (ja) * | 2017-12-27 | 2020-11-11 | 古河電気工業株式会社 | シラン架橋アクリルゴム成形体及びその製造方法、シラン架橋性アクリルゴム組成物、並びに耐油性製品 |
| US11814555B2 (en) | 2018-03-19 | 2023-11-14 | Dow Silicones Corporation | Hot melt adhesive compositions containing polyolefin-polydiorganosiloxane copolymers and methods for the preparation and use thereof |
| EP3768765B1 (en) | 2018-03-19 | 2023-05-17 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof |
| EP3768766B8 (en) | 2018-03-19 | 2025-11-05 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof |
| US11193051B2 (en) | 2018-03-19 | 2021-12-07 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin-polydiorganosiloxane copolymer and methods for the preparation and use thereof |
| JP7006429B2 (ja) * | 2018-03-23 | 2022-01-24 | Ｍｃｐｐイノベーション合同会社 | 接着シート用変性ポリエチレン組成物及び接着シート |
| US10162141B1 (en) * | 2018-03-28 | 2018-12-25 | Dow Global Technologies Llc | Flooding composition with polysiloxane |
| JP2021526728A (ja) * | 2018-04-16 | 2021-10-07 | セ エス エ エム サントル スイス デレクトロニク エ ド ミクロテクニク ソシエテ アノニム ルシェルシェ エ ディベロップメント | 光電池モジュールの製造方法 |
| US11718738B2 (en) | 2018-05-04 | 2023-08-08 | Lg Chem, Ltd. | Adhesive composition including ethylene/alpha-olefin copolymer |
| CN112074565B (zh) * | 2018-05-25 | 2023-01-31 | 联合碳化公司 | 可湿固化聚烯烃调配物 |
| JP7334195B2 (ja) | 2018-07-17 | 2023-08-28 | ダウ シリコーンズ コーポレーション | ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法 |
| JP7083723B2 (ja) * | 2018-08-07 | 2022-06-13 | リケンテクノス株式会社 | 摺動材料組成物、摺動性成形物、および摺動性部材 |
| EP3861038A1 (en) * | 2018-10-02 | 2021-08-11 | Borealis AG | Cross-linked plastomers as a replacement for rubber |
| CN109749663B (zh) * | 2018-12-27 | 2022-03-11 | 广州鹿山新材料股份有限公司 | 一种连续纤维增强塑料复合管用粘接树脂及其制备方法 |
| CN110330593A (zh) * | 2019-06-03 | 2019-10-15 | 中韩(武汉)石油化工有限公司 | 一种以钛系催化剂制备的聚烯烃制造高支化度聚烯烃树脂的方法 |
| WO2021043782A1 (en) * | 2019-09-06 | 2021-03-11 | Borealis Ag | Method for improving the storage stability and/or transport stability of a polymer |
| EP4034589A4 (en) * | 2019-09-27 | 2023-06-07 | Dow Global Technologies LLC | SILANE CROSSLINKED ETHYLENE/A-OLEFIN BLOCK COPOLYMER BEAD FOAM |
| FR3105245B1 (fr) | 2019-12-24 | 2021-11-26 | Michelin & Cie | Nouvelle composition de caoutchouc pour pneumatique |
| FR3105244B1 (fr) | 2019-12-24 | 2022-03-25 | Michelin & Cie | Nouvelle composition de caoutchouc pour pneumatique |
| CN111808552A (zh) * | 2020-07-08 | 2020-10-23 | 陈坚 | 一种多用途反应型热熔胶及其制造方法 |
| CN115702191B (zh) * | 2020-07-13 | 2024-07-05 | 古河电气工业株式会社 | 纤维素纤维增强树脂成型体及其制造方法 |
| WO2022080396A1 (ja) * | 2020-10-15 | 2022-04-21 | 三井化学株式会社 | 有機ケイ素化合物グラフト共重合体および当該共重合体を含むタイヤ用ゴム組成物 |
| WO2022107871A1 (ja) * | 2020-11-19 | 2022-05-27 | 株式会社Moresco | 粘着剤組成物 |
| US20240059887A1 (en) | 2020-12-30 | 2024-02-22 | Avient Corporation | Polymer blends of thermoplastic elastomer and cross-linked silane grafted polyolefin |
| EP4351888A4 (en) * | 2021-06-08 | 2025-06-04 | Cooper-Standard Automotive, Inc. | FORTREX ADDITIVE FOR LOW ROLLING RESISTANCE TIRES |
| FR3123920B1 (fr) | 2021-06-15 | 2023-04-28 | Michelin & Cie | Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene |
| FR3123919B1 (fr) | 2021-06-15 | 2023-04-28 | Michelin & Cie | Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene |
| CN113444191B (zh) * | 2021-06-29 | 2022-11-15 | 成都硅宝科技股份有限公司 | 一种硅烷改性聚烯烃成膜剂及其制备方法与应用 |
| EP4112660A1 (de) | 2021-07-01 | 2023-01-04 | Clariant International Ltd | Verarbeitungsoptimierte, reaktive polymerzusammensetzung |
| US20230044510A1 (en) * | 2021-07-13 | 2023-02-09 | Exxonmobil Chemical Patents Inc. | Silylation of Copolymers Comprising Para-Methylstyrene: Synthesis and Composites Thereof |
| CZ36024U1 (cs) * | 2021-09-21 | 2022-05-24 | Univerzita Pardubice | Přípravky pro zvýšení kluznosti povrchů polymerních materiálů a kompozitů |
| WO2024025591A1 (en) * | 2022-07-25 | 2024-02-01 | Cooper-Standard Automotive, Inc. | Fortrex additive for low rolling resistance tires |
| CN115627132B (zh) * | 2022-12-19 | 2023-03-21 | 广州鹿山新材料股份有限公司 | 导电粘接材料及其制备方法和应用 |
| CN119662032B (zh) * | 2025-02-24 | 2025-05-06 | 宁波汉吉高分子材料有限公司 | 一种热塑性弹性体组合物及其制备方法 |
Family Cites Families (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| US3660261A (en) * | 1970-04-20 | 1972-05-02 | Dow Chemical Co | Method for reduction of bromine contamination of chlorine |
| JPS5222988B2 (cg-RX-API-DMAC7.html) | 1971-08-20 | 1977-06-21 | ||
| AR218611A1 (es) * | 1975-06-23 | 1980-06-30 | Kabel Metallwerke Ghh | Procedimiento para la elaboracion de termoplasticos o elastomeros reticulables por injerto de un compuesto de silano en presencia de humedad |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| EP0188777B1 (de) | 1985-01-16 | 1989-03-15 | Walter Rose GmbH & Co. KG | Kabelmuffe mit einer querschnittlich kreuzförmigen Vorrichtung zum Stützen von in Kabelmuffen einlaufenden Kabelenden |
| US4806594A (en) * | 1987-06-17 | 1989-02-21 | Union Carbide Corporation | Water curable compositions of silane containing ole36in polymers |
| MX172794B (es) | 1988-08-01 | 1994-01-13 | Exxon Chemical Patents Inc | Mejoras en composicion de aditivos dispersante lubricadores a base de novedosos polimeros etilen alfa-olefinicos sustituidos con acidos mono y dicarboxilicos y proceso para producirlos |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5044438A (en) * | 1990-03-16 | 1991-09-03 | Young Joe A | Wellhead bowl protector and retrieving tool |
| PL166690B1 (pl) | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5266627A (en) | 1991-02-25 | 1993-11-30 | Quantum Chemical Corporation | Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process |
| JP3275211B2 (ja) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
| US6118013A (en) | 1991-05-20 | 2000-09-12 | The Dow Chemical Company | Preparation of addition polymerization catalysts |
| JPH06500158A (ja) | 1991-06-26 | 1994-01-06 | アルフレッド・テヴェス・ゲーエムベーハー | ディスクブレーキ用自動調整装置 |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| US6043401A (en) | 1992-05-26 | 2000-03-28 | Bp Amoco Corporation | Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture |
| WO1994000500A1 (en) | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
| US5750813A (en) | 1992-12-15 | 1998-05-12 | Clarian & Gmbh | Process for the preparation of polyolefin waxes |
| IL107927A0 (en) | 1992-12-17 | 1994-04-12 | Exxon Chemical Patents Inc | Oil soluble ethylene/1-butene copolymers and lubricating oils containing the same |
| TW304958B (cg-RX-API-DMAC7.html) | 1993-01-07 | 1997-05-11 | Hoechst Ag | |
| DE4404635C2 (de) * | 1993-02-17 | 1998-06-18 | Hitachi Ltd | Schwimmender optischer Abtastkopf, der integral mit einer Lichtquelle und einem Photodetektor ausgebildet ist, und optisches Plattengerät mit einem solchen |
| US5346963A (en) | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
| PL175846B1 (pl) * | 1993-06-24 | 1999-02-26 | Dow Chemical Co | Kompleksy tytanu (II) i sposób polimeryzacji addycyjnej |
| US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| WO1995029197A1 (en) | 1994-04-20 | 1995-11-02 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
| US5461110A (en) * | 1994-05-04 | 1995-10-24 | Du Pont Canada Inc. | Cross-linkable adhesive polymers |
| US5824718A (en) | 1995-04-20 | 1998-10-20 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
| US5741594A (en) | 1995-08-28 | 1998-04-21 | The Dow Chemical Company | Adhesion promoter for a laminate comprising a substantially linear polyolefin |
| JP3782458B2 (ja) | 1995-09-29 | 2006-06-07 | ザ ダウ ケミカル カンパニー | 架橋ポリオレフィン発泡品およびそれの製造方法 |
| ID16442A (id) | 1996-01-22 | 1997-10-02 | Dow Chemical Co | Polimer etilena berat molekul ultra rendah |
| DE69717645T2 (de) | 1996-07-22 | 2003-09-25 | Dow Global Technologies, Inc. | Verbrückte nicht-aromatische anionische dienylgruppen enthaltende metallkomplexe und darauf basierte polymerisatonskatalysatoren |
| ATE230004T1 (de) * | 1996-09-04 | 2003-01-15 | Degussa | Verwendung von silangepfropften amorphen poly- alpha-olefinen als feuchtigkeitsvernetzender klebrohstoff oder klebstoff |
| CN1177623A (zh) * | 1996-09-04 | 1998-04-01 | 希尔斯股份公司 | 硅烷接枝的无定形聚α－烯烃作为湿潮交联的粘性材料或胶粘剂的用途 |
| BR9713411A (pt) * | 1996-11-25 | 2000-04-18 | Dupont Dow Elastomers Llc | Composição de mistura polimérica termoplástica e processo para preparar um artigo moldado |
| AU743999B2 (en) | 1996-12-13 | 2002-02-14 | Dow Global Technologies Inc. | Abrasion-resistant, silane-crosslinkable polymer and polymer blend compositions |
| CN1248986A (zh) | 1997-02-28 | 2000-03-29 | 陶氏化学公司 | 填充的聚乙烯组合物 |
| GB9707842D0 (en) * | 1997-04-18 | 1997-06-04 | Bp Chem Int Ltd | Oligomerisation process |
| US6172015B1 (en) * | 1997-07-21 | 2001-01-09 | Exxon Chemical Patents, Inc | Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof |
| DE19750663A1 (de) * | 1997-11-15 | 1999-05-20 | Clariant Gmbh | Verwendung von Polyolefinwachsen in Lösemittelpasten |
| US6166142A (en) * | 1998-01-27 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Adhesive compositions based on blends of grafted metallocene catalyzed and polar ethylene copolymers |
| DE19808886A1 (de) * | 1998-03-03 | 1999-09-09 | Huels Chemische Werke Ag | Vernetzbare Formmasse |
| US6124370A (en) * | 1999-06-14 | 2000-09-26 | The Dow Chemical Company | Crosslinked polyolefinic foams with enhanced physical properties and a dual cure process of producing such foams |
| US6265493B1 (en) * | 1999-07-21 | 2001-07-24 | The Penn State Research Foundation | Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same |
| US6331597B1 (en) | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
| EP1254191A2 (en) | 1999-12-03 | 2002-11-06 | The Dow Chemical Company | Grafted thermoplastic compositions and fabricated articles therefrom |
| DE10015593A1 (de) | 2000-03-29 | 2001-10-11 | Clariant Gmbh | Verwendung von Polyolefinwachsen in der Kunststoffverarbeitung |
| JP3516925B2 (ja) * | 2000-09-19 | 2004-04-05 | 三井化学株式会社 | 変性ポリオレフィンおよびそれを含有する樹脂組成物 |
| JP2005508415A (ja) | 2001-11-06 | 2005-03-31 | ダウ グローバル テクノロジーズ インコーポレイティド | アイソタクチックプロピレンコポリマー類、その製法および用途 |
| ATE327265T1 (de) | 2002-04-12 | 2006-06-15 | Dow Global Technologies Inc | Copolymere mit niedrigem molekulargewicht aus ethylen und vinylaromatischen monomeren und anwendungen davon |
| ES2399364T3 (es) | 2002-10-02 | 2013-03-27 | Dow Global Technologies Llc | Composiciones poliméricas que comprenden un extendedor de etileno/alfa-olefina homogéneamente ramificado, de baja viscosidad |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| ATE402222T1 (de) | 2002-10-17 | 2008-08-15 | Dow Global Technologies Inc | Hochgefüllte polymerzusammensetzungen |
| DE10338344A1 (de) * | 2003-08-21 | 2005-03-24 | Clariant Gmbh | Modifizierte Polyolefinwachse |
| EP2281859B1 (en) * | 2004-12-21 | 2014-03-26 | Dow Global Technologies LLC | Polypropylene-based adhesive compounds |
-
2006
- 2006-07-10 KR KR1020087003117A patent/KR101369090B1/ko active Active
- 2006-07-10 CN CN201410584120.0A patent/CN104341704B/zh active Active
- 2006-07-10 AR ARP060102963A patent/AR057447A1/es unknown
- 2006-07-10 ES ES06786741T patent/ES2398109T3/es active Active
- 2006-07-10 EP EP11182252.4A patent/EP2407496B1/en active Active
- 2006-07-10 BR BRPI0615500-6A patent/BRPI0615500B1/pt active IP Right Grant
- 2006-07-10 JP JP2008521485A patent/JP5551360B2/ja active Active
- 2006-07-10 AU AU2006269238A patent/AU2006269238B2/en not_active Ceased
- 2006-07-10 CN CNA2006800311502A patent/CN101248099A/zh active Pending
- 2006-07-10 ES ES11182251.6T patent/ES2490990T3/es active Active
- 2006-07-10 US US11/994,559 patent/US9012563B2/en active Active
- 2006-07-10 WO PCT/US2006/026689 patent/WO2007008765A2/en not_active Ceased
- 2006-07-10 EP EP06786741A patent/EP1913042B1/en active Active
- 2006-07-10 ES ES11182252.4T patent/ES2508140T3/es active Active
- 2006-07-10 EP EP11182251.6A patent/EP2407495B1/en active Active
- 2006-07-10 CA CA002615702A patent/CA2615702A1/en not_active Abandoned
- 2006-07-10 TW TW095125041A patent/TW200706621A/zh unknown
-
2012
- 2012-09-05 JP JP2012195205A patent/JP5851367B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2407496B1 (en) | 2014-08-20 |
| JP5851367B2 (ja) | 2016-02-03 |
| EP1913042A2 (en) | 2008-04-23 |
| JP5551360B2 (ja) | 2014-07-16 |
| EP2407495B1 (en) | 2014-06-18 |
| CN104341704B (zh) | 2017-11-10 |
| ES2490990T3 (es) | 2014-09-04 |
| WO2007008765A3 (en) | 2007-03-22 |
| ES2508140T3 (es) | 2014-10-16 |
| US20080167421A1 (en) | 2008-07-10 |
| KR101369090B1 (ko) | 2014-03-06 |
| JP2013036040A (ja) | 2013-02-21 |
| KR20080039407A (ko) | 2008-05-07 |
| JP2009500513A (ja) | 2009-01-08 |
| US9012563B2 (en) | 2015-04-21 |
| CN104341704A (zh) | 2015-02-11 |
| CA2615702A1 (en) | 2007-01-18 |
| EP1913042B1 (en) | 2012-11-07 |
| EP2407496A1 (en) | 2012-01-18 |
| WO2007008765A2 (en) | 2007-01-18 |
| AU2006269238B2 (en) | 2012-04-26 |
| EP2407495A1 (en) | 2012-01-18 |
| BRPI0615500A2 (pt) | 2011-05-17 |
| BRPI0615500B1 (pt) | 2018-02-14 |
| AR057447A1 (es) | 2007-12-05 |
| AU2006269238A1 (en) | 2007-01-18 |
| CN101248099A (zh) | 2008-08-20 |
| TW200706621A (en) | 2007-02-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2398109T3 (es) | Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas | |
| ES2803224T3 (es) | Interpolímeros de olefina funcionalizados, composiciones y artículos preparados a partir de ellos, y procedimientos para obtener los mismos | |
| AU2013274889B2 (en) | Adhesive compositions containing modified ethylene-based polymers | |
| EP3957698B1 (en) | Adhesive compositions comprising low molecular weight functionalized olefin-based polymers | |
| BR122017011141B1 (pt) | Composição compreendendo uma mistura e artigo |