ES2233710T3 - Elastomeros termoplasticos que tienen endurecimiento mejorado y espumas obtenidas de los mismos. - Google Patents
Elastomeros termoplasticos que tienen endurecimiento mejorado y espumas obtenidas de los mismos.Info
- Publication number
- ES2233710T3 ES2233710T3 ES01989914T ES01989914T ES2233710T3 ES 2233710 T3 ES2233710 T3 ES 2233710T3 ES 01989914 T ES01989914 T ES 01989914T ES 01989914 T ES01989914 T ES 01989914T ES 2233710 T3 ES2233710 T3 ES 2233710T3
- Authority
- ES
- Spain
- Prior art keywords
- thermoplastic
- weight
- rubber
- percent
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- UETLMBWMVIQIGU-UHFFFAOYSA-N calcium azide Chemical compound [Ca+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] UETLMBWMVIQIGU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
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- 229910052801 chlorine Inorganic materials 0.000 description 1
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- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
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- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical group C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
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- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US771044 | 2001-01-26 | ||
| US09/771,044 US6433090B1 (en) | 2001-01-26 | 2001-01-26 | Thermoplastic elastomers having improved set foams made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2233710T3 true ES2233710T3 (es) | 2005-06-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01989914T Expired - Lifetime ES2233710T3 (es) | 2001-01-26 | 2001-12-06 | Elastomeros termoplasticos que tienen endurecimiento mejorado y espumas obtenidas de los mismos. |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6433090B1 (OSRAM) |
| EP (1) | EP1353995B1 (OSRAM) |
| JP (1) | JP4289540B2 (OSRAM) |
| KR (1) | KR20030071860A (OSRAM) |
| AU (1) | AU2002228797A1 (OSRAM) |
| DE (1) | DE60108903T2 (OSRAM) |
| ES (1) | ES2233710T3 (OSRAM) |
| MY (1) | MY134115A (OSRAM) |
| WO (1) | WO2002059194A2 (OSRAM) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20020018958A1 (en) * | 2000-06-20 | 2002-02-14 | Jsr Corporation | Polymeric material for laser processing and a laminated body for laser processing thereof, flexographic printing plate and the method of producing the same, and a seal material |
| JP4031622B2 (ja) * | 2001-05-30 | 2008-01-09 | バセル ポリオレフィン イタリア エス．アール．エル． | ポリプロピレン系樹脂組成物 |
| US7077450B2 (en) * | 2001-09-10 | 2006-07-18 | Nishikawa Rubber Co., Ltd. | Sound-absorbing material for vehicle's lower portion |
| DE60207870T3 (de) * | 2002-01-15 | 2011-12-15 | Advanced Elastomer Systems, L.P. | Thermoplastische elastomere und verfahren zu ihrer herstellung |
| US6713520B2 (en) * | 2002-06-19 | 2004-03-30 | Advanced Elastomer Systems, L.P. | Foams and methods for making the same |
| EP1534772B1 (en) * | 2002-08-15 | 2011-12-21 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having enhanced foaming and physical properties |
| JP4231368B2 (ja) * | 2003-07-17 | 2009-02-25 | リケンテクノス株式会社 | 熱可塑性エラストマー組成物 |
| EP1648959B1 (en) * | 2003-07-30 | 2010-11-24 | PolyOne Corporation | Nucleated thermoplastic elastomer compositions and related methods |
| DE602004024215D1 (de) * | 2003-09-17 | 2009-12-31 | Exxonmobil Chem Patents Inc | Ellungsverfahren dafür |
| US20080045660A1 (en) * | 2004-01-14 | 2008-02-21 | Rodrigue Jerry W | Thermoplastic Olefin Compositions |
| US7235609B2 (en) * | 2004-01-14 | 2007-06-26 | Amitkumar Dharia | Thermoplastic olefin compositions and articles |
| US7671106B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
| US7579408B2 (en) * | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
| US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| US7514517B2 (en) * | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
| US7622529B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| US7863379B2 (en) * | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
| US7795321B2 (en) * | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
| US7671131B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
| US20060014903A1 (en) * | 2004-07-14 | 2006-01-19 | Thierry Vromman | Thermoplastic vulcanizates with enhanced cooling and articles made therefrom |
| US20060052540A1 (en) | 2004-09-09 | 2006-03-09 | Maria Ellul | Thermoplastic vulcanizates |
| EP1799758A1 (en) * | 2004-09-21 | 2007-06-27 | Advanced Elastomer Systems L.P. | Modification of thermolastic vulcanizates with particulate fillers |
| US7829623B2 (en) * | 2004-11-05 | 2010-11-09 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates having improved fabricability |
| EP1674530A1 (en) * | 2004-12-24 | 2006-06-28 | Kraton Polymers Research B.V. | High melt strength thermoplastic elastomer composition |
| US7906600B2 (en) | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| EP1833856B1 (en) | 2004-12-29 | 2013-10-23 | ExxonMobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
| US8076416B2 (en) * | 2005-02-04 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and their use |
| US7989542B2 (en) | 2005-03-16 | 2011-08-02 | Sumitomo Chemical Company, Limited | Process for producing thermoplastic elastomer composition, and process for producing foamed thermoplastic elastomer composition |
| RU2007134344A (ru) * | 2005-03-17 | 2009-03-20 | Дау Глобал Текнолоджиз Инк. (Us) | ТЕРМОПЛАСТИЧНЫЙ ВУЛКАНИЗАТ, СОДЕРЖАЩИЙ ИНТЕРПОЛИМЕРЫ ЭТИЛЕНА/α-ОЛЕФИНОВ |
| US7319121B2 (en) | 2005-10-07 | 2008-01-15 | Advanced Elestomer Systems, Inc. | Microcellular foams of thermoplastic vulcanizates |
| US20090270525A1 (en) * | 2005-12-05 | 2009-10-29 | Jsr Corporation | Thermoplastic elastomer composition, foam product, and process for production of the composition or foam product |
| US9029477B2 (en) * | 2006-03-03 | 2015-05-12 | 3M Innovative Properties Company | Compositions comprising melt-processable thermoplastic fluoropolymers and methods of making the same |
| US7504458B2 (en) * | 2006-04-12 | 2009-03-17 | Advanced Elastomer Systems, Llp | Method for improving compression set in thermoplastic vulcanizates |
| US20070254971A1 (en) * | 2006-05-01 | 2007-11-01 | Synco De Vogel | Foamable thermoplastic vulcanizate blends, methods, and articles thereof |
| DE102007011076B4 (de) * | 2007-03-07 | 2011-06-01 | Teijin Monofilament Germany Gmbh | Antimikrobiell ausgerüstete Fäden, Verfahren zu deren Herstellung und textile Flächengebilde |
| US8011913B2 (en) * | 2008-02-29 | 2011-09-06 | Exxonmobil Chemical Patents Inc. | Method of melt blending curable polymer compositions using silicone hydrides |
| US8877867B2 (en) * | 2008-11-06 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and extruded articles therefrom |
| US20100119855A1 (en) * | 2008-11-10 | 2010-05-13 | Trazollah Ouhadi | Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction |
| US8829349B2 (en) * | 2008-12-18 | 2014-09-09 | Exxonmobil Chemical Patents Inc. | Oxides for protection against electrochemical oxidation and ionic contamination in medium-voltage power-cable insulation |
| EP2228325A1 (en) * | 2009-03-13 | 2010-09-15 | Habasit AG | Belt comprising a layer of foamed soft thermoplastic elastomer |
| CN102459377B (zh) * | 2009-06-03 | 2013-11-27 | 可乐丽股份有限公司 | 氢化嵌段共聚物的制造方法、由该制造方法得到的氢化嵌段共聚物及其组合物 |
| JP6022144B2 (ja) * | 2010-04-01 | 2016-11-09 | 東海興業株式会社 | ガラスランチャンネルとその組立体及び製造方法 |
| KR101231004B1 (ko) * | 2010-11-23 | 2013-02-07 | 주식회사 화승알앤에이 | 자동차 웨더스트립용 발포 열가소성 탄성체 조성물 |
| EP2658919B1 (en) | 2010-12-30 | 2018-07-25 | Dow Global Technologies LLC | Thermoplastic vulcanizate composition, method of producing the same, and articles made therefrom |
| US10836853B2 (en) * | 2012-09-20 | 2020-11-17 | Exxonmobil Chemical Patents Inc. | Crack-resistant polyethylene compositions |
| US10822479B2 (en) * | 2012-09-20 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Foamed polyethylene compositions |
| JP5655106B2 (ja) * | 2013-03-21 | 2015-01-14 | 住友ゴム工業株式会社 | 導電性ゴム組成物、転写ローラ、および画像形成装置 |
| US9382412B2 (en) * | 2013-05-10 | 2016-07-05 | Exxonmobil Chemicals Patents Inc. | Foamed compositions comprising propylene-based elastomers, articles made therefrom, and methods of making the same |
| EP3087133B1 (en) | 2013-12-24 | 2020-01-15 | ExxonMobil Chemical Patents Inc. | Compositions comprising thermoplastic vulcanizate, foamed material and articles made therefrom |
| JP6135629B2 (ja) * | 2014-09-25 | 2017-05-31 | 株式会社アドヴィックス | 摩擦材及び摩擦材の製造方法 |
| CN107567476A (zh) * | 2015-04-28 | 2018-01-09 | 埃克森美孚化学专利公司 | 基于丙烯的抗冲共聚物 |
| JP6700313B2 (ja) * | 2015-05-29 | 2020-05-27 | エクソンモービル・ケミカル・パテンツ・インク | 広い分子量分布のポリプロピレンを含んでいる熱可塑性加硫物 |
| EP3775035B1 (en) * | 2018-04-10 | 2025-12-10 | ExxonMobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions |
| WO2020252293A1 (en) | 2019-06-13 | 2020-12-17 | Exxonmobil Chemical Patents Inc. | Automotive weather seals formed with thermoplastic vulcanizate compositions |
| EP3778734A1 (en) * | 2019-08-15 | 2021-02-17 | Sika Technology Ag | Thermally expandable compositions comprising a chemical blowing agent |
| CN115584117B (zh) * | 2022-10-12 | 2025-04-18 | 镇江美达塑胶有限公司 | 一种tpu改性树脂发泡材料及其成型方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2972600A (en) | 1957-09-27 | 1961-02-21 | Schenectady Varnish Company In | Substituted phenols |
| NL134120C (OSRAM) | 1961-11-24 | 1900-01-01 | ||
| DE2822815C2 (de) | 1977-05-26 | 1994-02-17 | Mitsui Petrochemical Ind | Verfahren zur Herstellung einer teilweise vulkanisierten thermoplastischen Masse |
| US4311628A (en) | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| ZA86528B (en) | 1985-01-31 | 1986-09-24 | Himont Inc | Polypropylene with free-end long chain branching,process for making it,and use thereof |
| US5013793A (en) * | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| US4978717A (en) * | 1989-04-19 | 1990-12-18 | Exxon Chemical Patents Inc. | Thermoelastic composition of ethylene-1-olefin copolymer and rubber |
| US5157081A (en) | 1989-05-26 | 1992-10-20 | Advanced Elastomer Systems, L.P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| US5100947A (en) | 1989-05-26 | 1992-03-31 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having improved stiffness/impact balance |
| US5073597A (en) * | 1989-05-26 | 1991-12-17 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| WO1991017194A1 (en) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
| US5070111A (en) | 1991-03-13 | 1991-12-03 | Advanced Elastomer Systems, L.P. | Foaming thermoplastic elastomers |
| US5290886A (en) | 1993-04-20 | 1994-03-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved low temperature properties |
| DE4326326A1 (de) | 1993-08-05 | 1995-02-09 | Happich Gmbh Gebr | Kunststofformteil und Verfahren zum Herstellen desselben |
| DE4401432C1 (de) | 1994-01-19 | 1995-06-22 | Berstorff Gmbh Masch Hermann | Verfahren und Vorrichtung zum Herstellen eines TPE-Schaumprofiles für die Bau- und Kfz.-Industrie |
| US5656693A (en) | 1995-06-14 | 1997-08-12 | Exxon Chemical Patents Inc. | Thermoplastic elastomers having improved cure |
| IT1275514B (it) | 1995-07-12 | 1997-08-07 | Montell North America Inc | Polimeri atattici reticolati del propene |
| US5670595A (en) | 1995-08-28 | 1997-09-23 | Exxon Chemical Patents Inc. | Diene modified polymers |
| US5672660A (en) | 1995-12-01 | 1997-09-30 | Advanced Elastomer Systems, L.P. | Hydrosilylation crosslinking |
| MY115666A (en) | 1996-03-04 | 2003-08-30 | Mitsui Chemicals Inc | Foamable olefin thermoplastic elastomer compositions formed products thereof |
| US5763533A (en) * | 1996-12-10 | 1998-06-09 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers |
| US6245856B1 (en) * | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
| EP0849323A1 (en) * | 1996-12-20 | 1998-06-24 | Advanced Elastomer Systems, L.P. | Blow moldable dynamically vulcanized alloys |
| KR20000075698A (ko) * | 1997-02-26 | 2000-12-26 | 칼루자 마이클 이. | 열가소성 탄성중합체의 하이드로실릴화 가교결합 |
| EP0872516A1 (en) | 1997-04-15 | 1998-10-21 | Dsm N.V. | Foamable polymeric composition |
| US6143828A (en) * | 1997-06-14 | 2000-11-07 | Honam Petrochemical Corporation | Olefin-based crosslinked thermoplastic elastomers and a process of preparation thereof |
| US5889119A (en) * | 1997-07-17 | 1999-03-30 | The University Of Akron | Thermoplastic rubbery compositions |
-
2001
- 2001-01-26 US US09/771,044 patent/US6433090B1/en not_active Expired - Lifetime
- 2001-12-06 JP JP2002559489A patent/JP4289540B2/ja not_active Expired - Fee Related
- 2001-12-06 KR KR10-2003-7009873A patent/KR20030071860A/ko not_active Withdrawn
- 2001-12-06 DE DE60108903T patent/DE60108903T2/de not_active Expired - Fee Related
- 2001-12-06 AU AU2002228797A patent/AU2002228797A1/en not_active Abandoned
- 2001-12-06 EP EP01989914A patent/EP1353995B1/en not_active Expired - Lifetime
- 2001-12-06 ES ES01989914T patent/ES2233710T3/es not_active Expired - Lifetime
- 2001-12-06 WO PCT/US2001/046452 patent/WO2002059194A2/en not_active Ceased
-
2002
- 2002-01-24 MY MYPI20020277A patent/MY134115A/en unknown
- 2002-06-12 US US10/171,177 patent/US6503985B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002228797A1 (en) | 2002-08-06 |
| US6433090B1 (en) | 2002-08-13 |
| WO2002059194A2 (en) | 2002-08-01 |
| MY134115A (en) | 2007-11-30 |
| JP4289540B2 (ja) | 2009-07-01 |
| DE60108903D1 (de) | 2005-03-17 |
| DE60108903T2 (de) | 2006-04-13 |
| EP1353995A2 (en) | 2003-10-22 |
| EP1353995B1 (en) | 2005-02-09 |
| US20030013813A1 (en) | 2003-01-16 |
| US6503985B1 (en) | 2003-01-07 |
| JP2004521173A (ja) | 2004-07-15 |
| WO2002059194A3 (en) | 2003-01-23 |
| KR20030071860A (ko) | 2003-09-06 |
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