ES2192994B1 - Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. - Google Patents
Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.Info
- Publication number
- ES2192994B1 ES2192994B1 ES200200684A ES200200684A ES2192994B1 ES 2192994 B1 ES2192994 B1 ES 2192994B1 ES 200200684 A ES200200684 A ES 200200684A ES 200200684 A ES200200684 A ES 200200684A ES 2192994 B1 ES2192994 B1 ES 2192994B1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- separation
- carbonation
- sorbent
- confinement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/343—Heat recovery
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Abstract
Procedimiento de combustión con separación integrada de CO{sub,2} mediante carbonatación. Se propone un proceso para la separación de CO{sub,2} de gases de combustión aplicable a puntos de gran emisión (centrales térmicas de cualquier combustible carbonoso). La corriente de CO{sub,2} separada es susceptible de utilización y/o confinamiento en formaciones geológicas. El proceso propuesto pretende reducir los altos costes de separación de CO{sub,2}, que impiden el uso a gran escala de estas opciones de confinamiento de CO{sub,2}, recogidas en los informes del IPCC de la ONU. La invención consiste en poner en contacto los gases de combustión con un sorbente calcáreo (caliza, dolomita calcinadas) a 650-750 C donde se produce la reacción de captura de CO{sub,2} por la rápida carbonatación del sorbente. La regeneración del sorbente se lleva a cabo en otro reactor (calcinador) que trabaja en atmósferas de CO{sub,2} o CO{sub,2}/H{sub,2}O y en a presión igual o inferior a la atmosférica.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200200684A ES2192994B1 (es) | 2002-03-22 | 2002-03-22 | Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. |
CN038066807A CN1642620B (zh) | 2002-03-22 | 2003-03-14 | 通过碳化作用进行综合co2分离的燃烧方法 |
EP03712141A EP1495794A1 (en) | 2002-03-22 | 2003-03-14 | Combustion method with integrated co sb 2 /sb separation by means of carbonation |
AU2003216925A AU2003216925B2 (en) | 2002-03-22 | 2003-03-14 | Combustion method with integrated CO2 separation by means of carbonation |
CA2479886A CA2479886C (en) | 2002-03-22 | 2003-03-14 | Combustion method with integrated carbon dioxide separation by means of carbonation |
PCT/ES2003/000118 WO2003080223A1 (es) | 2002-03-22 | 2003-03-14 | Procedimiento de combustión con separación integrada de co2 mediante carbonatación |
JP2003578042A JP2005520678A (ja) | 2002-03-22 | 2003-03-14 | 炭酸塩化によるco2の集積的分離を伴う燃焼方法 |
US10/946,319 US20050060985A1 (en) | 2002-03-22 | 2004-09-21 | Combustion method with integrated CO2 separation by means of carbonation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200200684A ES2192994B1 (es) | 2002-03-22 | 2002-03-22 | Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2192994A1 ES2192994A1 (es) | 2003-10-16 |
ES2192994B1 true ES2192994B1 (es) | 2005-02-16 |
Family
ID=28051967
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200200684A Expired - Fee Related ES2192994B1 (es) | 2002-03-22 | 2002-03-22 | Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. |
Country Status (8)
Country | Link |
---|---|
US (1) | US20050060985A1 (es) |
EP (1) | EP1495794A1 (es) |
JP (1) | JP2005520678A (es) |
CN (1) | CN1642620B (es) |
AU (1) | AU2003216925B2 (es) |
CA (1) | CA2479886C (es) |
ES (1) | ES2192994B1 (es) |
WO (1) | WO2003080223A1 (es) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7618606B2 (en) | 2003-02-06 | 2009-11-17 | The Ohio State University | Separation of carbon dioxide (CO2) from gas mixtures |
AU2003304534A1 (en) | 2003-11-14 | 2004-06-06 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources | Reactivation of lime-based sorbents by co2 shocking |
WO2005046863A1 (en) * | 2003-11-14 | 2005-05-26 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources | Pre-treatment of lime-based sorbents using hydration |
CA2613698C (en) * | 2005-06-28 | 2013-02-05 | The Ohio State University | Separation of carbon dioxide (co2) from gas mixtures by calcium based reaction separation (cars-co2) process |
CN101378826B (zh) * | 2005-10-21 | 2013-02-27 | Calix有限公司 | 用于煅烧/碳酸化循环处理的系统和方法 |
AU2006303828C1 (en) * | 2005-10-21 | 2011-04-14 | Calix Limited | System and method for calcination/carbonation cycle processing |
ES2695300T3 (es) * | 2005-10-21 | 2019-01-03 | Calix Ltd | Compuesto de material Mg(OH)2.CaCO3 y procedimiento de fabricación del mismo |
EP2004319B8 (en) | 2006-03-31 | 2015-07-22 | Calix Ltd | System and method for the calcination of minerals |
ES2302610B1 (es) * | 2006-03-31 | 2009-06-12 | Consejo Superior Investig. Cientificas | Procedimiento de calcinacion con produccion de co2 puro o facilmente purificable proveniente de la descomposicion de carbonatos. |
FR2908327B1 (fr) * | 2006-11-09 | 2009-01-30 | Air Liquide | Procede de fabrication de clinker a emission de co2 controlee |
US8561702B2 (en) * | 2007-02-10 | 2013-10-22 | Vast Power Portfolio, Llc | Hot fluid recovery of heavy oil with steam and carbon dioxide |
ES2345135B1 (es) * | 2007-07-17 | 2011-07-18 | Fundacion Circe- Centro De Investigacion De Recursos Y Consumos Energeticos | Dispositivo ciclonico para calcinacion y procedimiento de separacion de co2 usando dicho dispositivo. |
FR2921059B1 (fr) * | 2007-09-14 | 2011-06-24 | Rech S Geol Et Minieres Brgm Bureau De | Procede et installation de production de clinker |
CA2724378C (en) | 2008-05-15 | 2016-10-18 | Calix Limited | System and method for processing flue gas |
WO2009148334A1 (en) | 2008-06-05 | 2009-12-10 | Industrial Research Limited | Gas separation process |
DE102008050816B4 (de) * | 2008-10-08 | 2013-09-05 | Alstom Technology Ltd. | Verfahren und Anordnung zur Abscheidung von CO2 aus Verbrennungsabgas |
ES2339733B1 (es) | 2008-11-21 | 2011-03-15 | Union Fenosa Generacion, S.A. | Procedimiento y dispositivo para la combustion de biomasa sin emisionde dioxido de carbono. |
FR2944217B1 (fr) * | 2009-04-08 | 2011-04-01 | Inst Francais Du Petrole | Procede de captage du dioxyde de carbone avec integration thermique de la regeneration avec la chaine de compression |
DE102009039055A1 (de) * | 2009-08-28 | 2011-03-10 | Technische Universität Darmstadt | Verfahren und Einrichtung zur Abscheidung von CO2 aus Abgas |
CN102575178B (zh) * | 2009-09-18 | 2014-12-10 | 沃姆瑟能源解决方案公司 | 带有焦炭制备系统的整体煤气化联合循环装置 |
CA2778179C (en) | 2009-10-24 | 2017-07-25 | Calix Limited | System and method for processing an input fuel gas and steam to produce carbon dioxide and an output fuel gas |
US8647413B2 (en) * | 2009-10-30 | 2014-02-11 | General Electric Company | Spray process for the recovery of CO2 from a gas stream and a related apparatus |
ES2370619B1 (es) * | 2010-04-27 | 2012-10-26 | Fundación Investigación E Innovación Para El Desarrollo Social | Procedimiento para la obtención de hidrogeno, a partir de la biomasa y carbón vegetal. |
ES2401294B1 (es) * | 2011-06-24 | 2014-05-09 | Consejo Superior De Investigaciones Científicas (Csic) | DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO |
EP2756068B1 (en) | 2011-09-15 | 2015-11-25 | Energy Knowledge Group BV | Process for the preparation of biofuel using algae |
KR101863967B1 (ko) * | 2011-09-30 | 2018-06-04 | 한국전력공사 | 저에너지 소비형 이산화탄소의 회수방법 |
NO343140B1 (no) * | 2013-06-14 | 2018-11-19 | Zeg Power As | Fremgangsmåte for bærekraftig energiproduksjon i et kraftverk som omfatter en fastoksid brenselcelle |
US9586827B2 (en) | 2013-09-06 | 2017-03-07 | David LeRoy Hagen | CO2 producing calciner |
TWI516302B (zh) * | 2013-12-11 | 2016-01-11 | 財團法人工業技術研究院 | 循環塔二氧化碳捕獲系統、碳酸化爐、煅燒爐及其使用方法 |
KR101529823B1 (ko) * | 2014-05-21 | 2015-06-29 | 현대중공업 주식회사 | 석탄가스화 복합발전 시스템 |
EP2959966B1 (en) * | 2014-06-24 | 2018-09-05 | General Electric Technology GmbH | A calciner and a method for calcination of a carbon dioxide rich sorbent |
CN104841363A (zh) * | 2015-04-22 | 2015-08-19 | 马鞍山市顺达环保设备有限公司 | 一种矿热炉用吸附剂及其制备方法 |
US9956517B2 (en) * | 2016-05-23 | 2018-05-01 | General Electric Company Gmbh | System and method for reducing carbon dioxide emissions from a flue gas generated via combusting a fossil fuel |
CN106595363B (zh) * | 2016-12-09 | 2018-10-23 | 南京工业大学 | 高温钙循环热化学储能方法及系统 |
EP3592451A4 (en) | 2017-03-09 | 2020-12-30 | Hot Lime Labs Limited | IMPROVED PROCESS AND DEVICE FOR SEPARATION AND RELEASE OF CARBON DIOXIDE |
CN108619896B (zh) * | 2018-05-16 | 2023-11-21 | 安徽建筑大学 | 一种基于切换式填充床反应器的co2循环脱除装置及方法 |
NO345216B1 (en) | 2019-08-28 | 2020-11-09 | Zeg Power As | Hydrogen-fuelled gas turbine power system and method for its operation |
EP4065668A4 (en) | 2019-11-25 | 2023-12-27 | Wormser Energy Solutions, Inc. | CARBONIZATION PRODUCT PREPARATION SYSTEM AND GASIFICATION REACTOR FOR ALL-STEAM GASIFICATION WITH CARBON CAPTURE |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1938202A (en) | 1930-09-12 | 1933-12-05 | Du Pont | Hydrogen production |
US3108857A (en) * | 1961-04-10 | 1963-10-29 | Consolidation Coal Co | Method for the production of hydrogen |
CA1081466A (en) * | 1976-03-26 | 1980-07-15 | David S. Mitchell | Countercurrent plug-like flow of two solids |
US4191538A (en) | 1979-03-12 | 1980-03-04 | Continental Oil Company | Synthetic CO2 acceptor and gasification process therewith |
ES2003265A6 (es) * | 1987-04-21 | 1988-10-16 | Espan Carburos Metal | Procedimiento para la obtencion de co2 y n2 a partir de los gases generados en un motor o turbina de combustion interna |
JPH04190831A (ja) * | 1990-11-22 | 1992-07-09 | Hitachi Ltd | 炭酸ガス再資源化リサイクルシステム |
NL9201179A (nl) * | 1992-07-02 | 1994-02-01 | Tno | Werkwijze voor het regeneratief verwijderen van kooldioxide uit gasstromen. |
JP3853398B2 (ja) * | 1994-05-23 | 2006-12-06 | 株式会社四国総合研究所 | 二酸化炭素の回収方法及び二酸化炭素吸着剤 |
JP2710267B2 (ja) * | 1994-07-12 | 1998-02-10 | 工業技術院長 | 二酸化炭素含有ガスからの二酸化炭素の分離装置と、二酸化炭素分離機能を有する燃焼装置 |
JPH10137533A (ja) * | 1996-11-08 | 1998-05-26 | Agency Of Ind Science & Technol | 燃焼排ガス中の特定ガス成分の回収方法 |
JP2000120447A (ja) * | 1998-10-12 | 2000-04-25 | Toshiba Corp | 火力発電プラント |
JP2002079052A (ja) * | 2000-09-08 | 2002-03-19 | Toshiba Corp | 二酸化炭素回収方法およびシステム |
FR2814533B1 (fr) * | 2000-09-27 | 2002-10-31 | Alstom Power Nv | Procede pour reduire simultanement les emissions de co2 de so2 dans une installation de combustion |
US6667022B2 (en) * | 2001-08-14 | 2003-12-23 | General Electric Co. | Process for separating synthesis gas into fuel cell quality hydrogen and sequestration ready carbon dioxide |
US7067456B2 (en) * | 2003-02-06 | 2006-06-27 | The Ohio State University | Sorbent for separation of carbon dioxide (CO2) from gas mixtures |
-
2002
- 2002-03-22 ES ES200200684A patent/ES2192994B1/es not_active Expired - Fee Related
-
2003
- 2003-03-14 JP JP2003578042A patent/JP2005520678A/ja active Pending
- 2003-03-14 AU AU2003216925A patent/AU2003216925B2/en not_active Ceased
- 2003-03-14 EP EP03712141A patent/EP1495794A1/en not_active Ceased
- 2003-03-14 WO PCT/ES2003/000118 patent/WO2003080223A1/es active Application Filing
- 2003-03-14 CA CA2479886A patent/CA2479886C/en not_active Expired - Fee Related
- 2003-03-14 CN CN038066807A patent/CN1642620B/zh not_active Expired - Fee Related
-
2004
- 2004-09-21 US US10/946,319 patent/US20050060985A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN1642620B (zh) | 2011-08-10 |
WO2003080223A1 (es) | 2003-10-02 |
US20050060985A1 (en) | 2005-03-24 |
JP2005520678A (ja) | 2005-07-14 |
AU2003216925A1 (en) | 2003-10-08 |
EP1495794A1 (en) | 2005-01-12 |
CA2479886C (en) | 2011-05-17 |
CA2479886A1 (en) | 2003-10-02 |
AU2003216925B2 (en) | 2008-09-11 |
CN1642620A (zh) | 2005-07-20 |
ES2192994A1 (es) | 2003-10-16 |
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