ES2189847T3 - Composiciones fluoroelastomericas. - Google Patents
Composiciones fluoroelastomericas.Info
- Publication number
- ES2189847T3 ES2189847T3 ES96116652T ES96116652T ES2189847T3 ES 2189847 T3 ES2189847 T3 ES 2189847T3 ES 96116652 T ES96116652 T ES 96116652T ES 96116652 T ES96116652 T ES 96116652T ES 2189847 T3 ES2189847 T3 ES 2189847T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- understands
- iodine
- rent
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Sealing Material Composition (AREA)
Abstract
SISTEMAS DE CURACION PARA FLUORELASTOMEROS CURABLES MEDIANTE RUTA PEROXIDICA QUE COMPRENDEN BROMO, OPCIONALMENTE YODO, EL BROMO SIEMPRE SIENDO SUPERIOR AL YODO, QUE COMPRENDE ELEMENTOS ESENCIALES: (I) UN AGENTE DE CURACION QUE COMPRENDE UNA BIS-OLEFINA QUE TIENE LA FORMULA GENERAL: EN DONDE: R{SUB,1}, R{SUB,2}, R{SUB,3}, R{SUB,4}, R{SUB,5}, R{SUB,6}, IGUALES O DIFERENTES ENTRE SI, SON H O C{SUB,1}-C{SUB,5} ALQUILO; Z ES UN RADICAL ALQUILO O CICLOALQUILO C{SUB,1}-C{SUB,18} LINEAL O RAMIFICADO, QUE CONTIENE OPCIONALMENTE ATOMOS DE OXIGENO, O UN RADICAL (PER)FLUOPOLIOXIALQUILO. (II) UN HIDRURO METALORGANICO DE FORMULA: EN DONDE: M SE SELECCIONA DE SN, SI, GE, PB; X ES UN ENTERO DE 1 A 3; Y, Z SON CERO O ENTEROS DE 1 A 3, CON LA CONDICION DE QUE Y + Z = 4 - X; W ES UN ENERO DE 1 A 3; LOS GRUPOS R, IGUALES O DIFERENTES ENTRE SI, SE SELECCIONAN DE ALQUILOS C{SUB,1}C{SUB,4}, ARILOS C{SUB,6}-C{SUB,12}, ARILALQUILOS Y ALQUILARILOS C{SUB,7}-C{SUB,14}, OPCIONALMENTE CONTENIENDO GRUPOS DE NITRILO Y/O HIDROXILOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT95MI002178A IT1276979B1 (it) | 1995-10-20 | 1995-10-20 | Composizioni fluoroelastomeriche |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2189847T3 true ES2189847T3 (es) | 2003-07-16 |
Family
ID=11372409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96116652T Expired - Lifetime ES2189847T3 (es) | 1995-10-20 | 1996-10-17 | Composiciones fluoroelastomericas. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5902857A (es) |
EP (1) | EP0769521B1 (es) |
JP (1) | JP4021960B2 (es) |
CA (1) | CA2188384A1 (es) |
DE (1) | DE69626080T2 (es) |
ES (1) | ES2189847T3 (es) |
IN (1) | IN192201B (es) |
IT (1) | IT1276979B1 (es) |
MX (1) | MX9604997A (es) |
Families Citing this family (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69826463T2 (de) * | 1997-04-15 | 2005-09-22 | Daikin Industries, Ltd. | Vulkanisationsmischung für fluorkautschuke und fluorkautschukformteile |
JP5079187B2 (ja) * | 1998-08-21 | 2012-11-21 | デュポン パフォーマンス エラストマーズ エルエルシー | 良好な加工性および低温特性を有するフルオロエラストマー組成物 |
IT1308627B1 (it) * | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
IT1308628B1 (it) * | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
EP1209175A4 (en) * | 1999-06-29 | 2004-10-06 | Daikin Ind Ltd | FLUORINATED ELASTOMER AND VULCANIZED MOLDING |
CA2377410A1 (en) | 1999-07-02 | 2001-01-11 | Dyneon Llc | Fluoroelastomer compositions and articles made therefrom |
US6593416B2 (en) | 2000-02-01 | 2003-07-15 | 3M Innovative Properties Company | Fluoropolymers |
US6720360B1 (en) | 2000-02-01 | 2004-04-13 | 3M Innovative Properties Company | Ultra-clean fluoropolymers |
EP1167441B1 (en) | 2000-06-29 | 2015-07-29 | 3M Innovative Properties Company | Fluoroelastomer composition comprising a mineral oil |
IT1318669B1 (it) * | 2000-08-08 | 2003-08-27 | Ausimont Spa | Ionomeri fluorurati solfonici. |
US6657013B2 (en) * | 2000-09-18 | 2003-12-02 | 3M Innovative Properties Company | Imidate-containing fluoropolymer compositions |
WO2002024772A2 (en) | 2000-09-18 | 2002-03-28 | 3M Innovative Properties Company | Metal amine complex containing fluoropolymer compositions |
JP2004514777A (ja) * | 2000-12-01 | 2004-05-20 | スリーエム イノベイティブ プロパティズ カンパニー | ヒドロシロキサンまたはヒドロシラザンを含む硬化性フルオロエラストマー組成物 |
JP2004517165A (ja) * | 2000-12-01 | 2004-06-10 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロエラストマー製造用組成物およびフルオロエラストマー製造方法 |
US6730760B2 (en) | 2001-01-31 | 2004-05-04 | 3M Innovative Properties Company | Perfluoroelastomers having a low glass transition temperature and method of making them |
US6890995B2 (en) | 2001-01-31 | 2005-05-10 | 3M Innovative Properties Company | Fluoropolymer compositions |
US6803425B2 (en) | 2001-04-12 | 2004-10-12 | 3M Innovative Properties Company | Fluoropolymers having pendant imidate structures |
US6844388B2 (en) | 2001-04-12 | 2005-01-18 | 3M Innovative Properties Company | Fluoropolymer compositions containing a nitrogen cure site monomer |
US6794457B2 (en) | 2001-04-30 | 2004-09-21 | 3M Innovative Properties Company | Fluoropolymer curing system containing a nitrogen cure site monomer |
EP1432744B2 (en) | 2001-05-02 | 2014-10-01 | 3M Innovative Properties Company | Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers |
WO2002088206A2 (en) | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
ITMI20011060A1 (it) * | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
ITMI20011059A1 (it) * | 2001-05-22 | 2002-11-22 | Ausimont Spa | Composizioni fluoroelastomeriche |
WO2003037621A2 (en) | 2001-10-31 | 2003-05-08 | 3M Innovative Properties Company | Bonding of a fluoropolymer layer to a substrate |
US6916871B2 (en) * | 2001-10-31 | 2005-07-12 | 3M Innovative Properties Company | Composition and method for making a fluoroelastomer |
RU2004135531A (ru) | 2002-06-21 | 2005-07-10 | ЗМ Инновейтив Пропертиз Компани (US) | Процесс получения фторполимеров с пониженным содержанием полярных концевых групп |
US6803435B2 (en) | 2002-07-18 | 2004-10-12 | 3M Innovative Properties Company | Curable fluoropolymers containing bromine groups having improved compression set |
US6884860B1 (en) | 2002-07-29 | 2005-04-26 | 3M Innovative Properties Company | Fluoroelastomer copolymer based on tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropylene and vinylidene fluoride |
RU2005101205A (ru) | 2002-07-29 | 2005-08-10 | ЗМ Инновейтив Пропертиз Компани (US) | Сверхчистый фторэластомер, пригодный для использования в производстве электронных элементовв |
WO2004011508A1 (en) | 2002-07-29 | 2004-02-05 | 3M Innovative Properties Company | Process for making a fluoroelastomer |
US6887927B2 (en) | 2002-08-27 | 2005-05-03 | 3M Innovative Properties Company | Fluoropolymer compositions containing a nitrogen cure site monomer and a sulfone or sulfoxide compound |
CN1289545C (zh) | 2002-09-12 | 2006-12-13 | 3M创新有限公司 | 具有低温特性和耐溶剂性的氟弹性体 |
US6846880B2 (en) | 2002-10-11 | 2005-01-25 | 3M Innovative Properties Company | Fluoropolymer compositions |
RU2342403C2 (ru) | 2002-10-31 | 2008-12-27 | Зм Инновейтив Пропертиз Компани | Полимеризация в водной эмульсии без эмульгатора для получения сополимеров фторированного олефина и углеводородного олефина |
DE60314901T2 (de) | 2002-11-20 | 2008-03-13 | 3M Innovative Properties Co., St. Paul | Verfahren zur herstellung von fluorpolymeren mit endständigen nitril-gruppen |
US6734254B1 (en) | 2003-01-13 | 2004-05-11 | 3M Innovative Properties Company | Co-curable blends featuring bromine-and iodine-containing fluoroplastic polymers |
US20040142135A1 (en) | 2003-01-21 | 2004-07-22 | 3M Innovative Properties Company | Fuel management system comprising a fluoroelastomer layer having a hydrotalcite compound |
US6956085B2 (en) | 2003-02-14 | 2005-10-18 | 3M Innovative Properties Company | Fluoroelastomer compositions |
EP1454740B1 (en) | 2003-03-04 | 2006-02-08 | 3M Innovative Properties Company | Method of bonding a fluoroelastomer layer to a silicone rubber layer, laminate for use in said method and article produced therewith |
US7304115B2 (en) | 2003-12-30 | 2007-12-04 | 3M Innovative Properties Company | Fluoropolymer coagulation method and composition |
ITMI20041252A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Composizioni perfluoroelastomeriche |
ITMI20041251A1 (it) * | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di perfluoroelastomeri |
ITMI20041253A1 (it) | 2004-06-22 | 2004-09-22 | Solvay Solexis Spa | Gel di fluoroelastomeri |
US7402630B2 (en) | 2004-12-16 | 2008-07-22 | 3M Innovative Properties Company | Curing compositions for fluoropolymers |
US7300985B2 (en) | 2004-12-21 | 2007-11-27 | 3M Innovative Properties Company | Fluoropolymers having pendant amidoxime or amidrazone structures |
US7294677B2 (en) | 2005-08-25 | 2007-11-13 | 3M Innovative Properties Company | Catalyst for making fluoroelastomer compositions and methods of using the same |
ITMI20061290A1 (it) * | 2006-07-03 | 2008-01-04 | Solvay Solexis Spa | Composizioni (per) fluoroelastometriche |
ITMI20061292A1 (it) * | 2006-07-03 | 2008-01-04 | Solvay Solexis Spa | Composizioni (per) fluoroelastomeriche |
ITMI20061291A1 (it) * | 2006-07-03 | 2008-01-04 | Solvay Solexis Spa | Composizioni (per) fluoroelastomeriche |
US7592386B2 (en) | 2006-11-20 | 2009-09-22 | 3M Innovative Properties Company | Dual cure hydrotalcite containing fluoropolymer compositions |
KR101595137B1 (ko) | 2008-02-29 | 2016-02-17 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 낮은 카르보닐 말단기 비를 갖는 퍼플루오로엘라스토머 |
FR2934274B1 (fr) * | 2008-07-25 | 2013-01-11 | Hutchinson | Composition de caoutchouc pour structure multicouches, telle qu'un raccord pour systeme d'admission d'air de turbocompresseur, cette structure et ce systeme |
EP2324076B1 (en) | 2008-07-31 | 2017-11-01 | 3M Innovative Properties Company | Fluoropolymer compositions and method of making and using thereof |
US8906821B2 (en) | 2009-06-25 | 2014-12-09 | 3M Innovative Properties Company | Curing compositions for fluoropolymers |
US20110143138A1 (en) * | 2009-12-10 | 2011-06-16 | 3M Properties Company | Perfluoroelastomer bonding |
EP2610303B1 (en) | 2010-08-25 | 2016-07-20 | Daikin Industries, Ltd. | Fluoro rubber molding with complex shape |
JP5790655B2 (ja) | 2010-08-25 | 2015-10-07 | ダイキン工業株式会社 | フッ素ゴム組成物 |
US9006328B2 (en) * | 2010-08-25 | 2015-04-14 | Daikin Industries, Ltd. | Fluororubber composition |
EP2610301B1 (en) | 2010-08-25 | 2017-10-11 | Daikin Industries, Ltd. | Belt material |
CN103080616B (zh) | 2010-08-25 | 2016-04-27 | 大金工业株式会社 | 密封材料 |
JP5781076B2 (ja) | 2010-08-25 | 2015-09-16 | ダイキン工業株式会社 | ホース |
WO2012049093A1 (en) | 2010-10-15 | 2012-04-19 | Solvay Specialty Polymers Italy S.P.A. | Fluoroelastomers |
GB201108963D0 (en) | 2011-05-27 | 2011-07-13 | 3M Innovative Properties Co | Composite materials comprising polyamides and fluoroelastomers |
EP2557109B1 (en) | 2011-08-11 | 2019-01-23 | 3M Innovative Properties Company | Method of bonding a fluoroelastomer compound to a metal substrate using low molecular weight functional hydrocarbons as bonding promoter |
US20130158154A1 (en) | 2011-12-15 | 2013-06-20 | E.I.Du Pont De Nemours And Company | Coagent for free radical curing fluoroelastomers |
EP2791191B1 (en) * | 2011-12-16 | 2016-03-16 | Solvay Specialty Polymers Italy S.p.A. | Crosslinkable vinylidene fluoride and trifluoroethylene polymers |
EP2935356B1 (en) | 2012-12-19 | 2016-10-05 | 3M Innovative Properties Company | Method of making fluoropolymers with a polyiodide, compositions and articles thereof |
US10294344B2 (en) | 2013-12-09 | 2019-05-21 | 3M Innovative Properties Company | Fluoroelastomer component for contacting ammonia and/or urea |
CN106574016B (zh) * | 2014-07-22 | 2019-06-18 | 索尔维特殊聚合物意大利有限公司 | 全氟弹性体组合物 |
JP6630355B2 (ja) * | 2014-10-31 | 2020-01-15 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | フルオロエラストマー組成物 |
CN107318265A (zh) * | 2014-12-19 | 2017-11-03 | 3M创新有限公司 | 可固化的部分氟化的聚合物组合物 |
EP3135477B1 (en) | 2015-08-27 | 2018-04-18 | 3M Innovative Properties Company | Multilayer articles with improved thermal resistance containing one or more fluoropolymers |
CN111433238B (zh) * | 2017-12-06 | 2021-12-10 | Agc株式会社 | 含氟弹性共聚物及含氟弹性共聚物的制造方法 |
WO2019162491A1 (en) | 2018-02-23 | 2019-08-29 | Solvay Specialty Polymers Italy S.P.A. | Fluorinated monomers comprising anthracene moieties |
WO2020132203A1 (en) | 2018-12-20 | 2020-06-25 | 3M Innovative Properties Company | Dry powder blends of amorphous perfluorinated polymers, methods of making the same, and articles derived from the dry powder blends |
EP3898835A1 (en) | 2018-12-20 | 2021-10-27 | 3M Innovative Properties Company | Latex blends of amorphous perfluorinated polymers and articles derived therefrom |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3810874A (en) * | 1969-03-10 | 1974-05-14 | Minnesota Mining & Mfg | Polymers prepared from poly(perfluoro-alkylene oxide) compounds |
US4035565A (en) * | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
JPS53125491A (en) * | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
JPS5920310A (ja) * | 1982-07-27 | 1984-02-02 | Daikin Ind Ltd | 含フッ素ポリマー硬化用組成物 |
IT1206517B (it) * | 1983-09-07 | 1989-04-27 | Montedison Spa | Composizioni covulcanizzabili da fluoroelastomeri a base di fluoruro di vinilidene e copolimeri tetrafluoeoetilene-propilene. |
US4564662A (en) * | 1984-02-23 | 1986-01-14 | Minnesota Mining And Manufacturing Company | Fluorocarbon elastomer |
DE3662142D1 (en) * | 1985-03-28 | 1989-03-30 | Daikin Ind Ltd | Novel fluorovinyl ether and copolymer comprising the same |
IT1187684B (it) * | 1985-07-08 | 1987-12-23 | Montefluos Spa | Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti |
US4694045A (en) * | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
EP0365053B1 (en) * | 1985-07-12 | 1994-05-04 | E.I. Du Pont De Nemours And Company | Peroxide-curable brominated fluoroelastomer compositions |
IT1189092B (it) * | 1986-04-29 | 1988-01-28 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati |
JPS62260807A (ja) * | 1986-05-07 | 1987-11-13 | Nippon Mektron Ltd | 含フッ素重合体の製造方法 |
IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
JPS63304009A (ja) * | 1987-06-04 | 1988-12-12 | Nippon Mektron Ltd | パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法 |
IT1235545B (it) * | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
IT1231174B (it) * | 1989-07-24 | 1991-11-22 | Ausimont Srl | Mescole vulcanizzabili di fluoroelastomeri contenenti bromo o iodio e di perossidi organici |
DE69233097T2 (de) * | 1991-01-11 | 2004-05-06 | Dyneon Llc, Oakdale | Fluorelastomerzusammensetzung |
EP0639208A1 (en) * | 1992-05-07 | 1995-02-22 | E.I. Du Pont De Nemours And Company | Perfluoroelastomers with enhanced properties |
JPH06122802A (ja) * | 1992-08-28 | 1994-05-06 | Asahi Glass Co Ltd | フッ素ゴム組成物 |
GB9304004D0 (en) * | 1993-02-26 | 1993-04-14 | Automotive Products Plc | Friction clutch carrier assembly |
JPH07196881A (ja) * | 1993-12-02 | 1995-08-01 | E I Du Pont De Nemours & Co | 含フッ素系エラストマー加硫組成物 |
IT1265461B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
JP3307046B2 (ja) * | 1993-12-29 | 2002-07-24 | ダイキン工業株式会社 | フッ素ゴム組成物および成形品 |
US5447993A (en) * | 1994-04-19 | 1995-09-05 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer curing |
JP3477892B2 (ja) * | 1995-03-20 | 2003-12-10 | ダイキン工業株式会社 | 含フッ素ポリマー組成物、ならびにその架橋体および用途 |
IT1277445B1 (it) * | 1995-08-04 | 1997-11-10 | Ausimont Spa | Composizioni vulcanizzabili di fluoroelastomeri contenenti bromo |
-
1995
- 1995-10-20 IT IT95MI002178A patent/IT1276979B1/it active IP Right Grant
-
1996
- 1996-10-16 IN IN1825CA1996 patent/IN192201B/en unknown
- 1996-10-17 ES ES96116652T patent/ES2189847T3/es not_active Expired - Lifetime
- 1996-10-17 EP EP96116652A patent/EP0769521B1/en not_active Expired - Lifetime
- 1996-10-17 DE DE69626080T patent/DE69626080T2/de not_active Expired - Fee Related
- 1996-10-18 US US08/733,938 patent/US5902857A/en not_active Expired - Fee Related
- 1996-10-18 JP JP27631196A patent/JP4021960B2/ja not_active Expired - Fee Related
- 1996-10-21 CA CA002188384A patent/CA2188384A1/en not_active Abandoned
- 1996-10-21 MX MX9604997A patent/MX9604997A/es unknown
Also Published As
Publication number | Publication date |
---|---|
IT1276979B1 (it) | 1997-11-03 |
US5902857A (en) | 1999-05-11 |
JPH09124871A (ja) | 1997-05-13 |
IN192201B (es) | 2004-03-13 |
DE69626080D1 (de) | 2003-03-13 |
MX9604997A (es) | 1997-06-28 |
EP0769521B1 (en) | 2003-02-05 |
DE69626080T2 (de) | 2003-12-04 |
EP0769521A1 (en) | 1997-04-23 |
JP4021960B2 (ja) | 2007-12-12 |
ITMI952178A0 (es) | 1995-10-20 |
ITMI952178A1 (it) | 1997-04-20 |
CA2188384A1 (en) | 1997-04-21 |
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