ES2183978T3 - Complejos metalicos que contienen indenilo sustituido y procedimiento de polimerizacion de olefinas. - Google Patents

Complejos metalicos que contienen indenilo sustituido y procedimiento de polimerizacion de olefinas.

Info

Publication number
ES2183978T3
ES2183978T3 ES96936227T ES96936227T ES2183978T3 ES 2183978 T3 ES2183978 T3 ES 2183978T3 ES 96936227 T ES96936227 T ES 96936227T ES 96936227 T ES96936227 T ES 96936227T ES 2183978 T3 ES2183978 T3 ES 2183978T3
Authority
ES
Spain
Prior art keywords
indenile
metal complexes
olefin polymerization
replaced
complexes containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96936227T
Other languages
English (en)
Inventor
Peter N Nickias
Mark H Mcadon
Jasson T Patton
Bernard P Friedrichsen
Jorge Soto
James C Stevens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2183978T3 publication Critical patent/ES2183978T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE DESCRIBEN COMPLEJOS METALICOS DEL GRUPO 4 QUE LLEVAN UN GRUPO INDENILO SUSTITUIDO EN LA POSICION 2 O 3 CON AL MENOS UN GRUPO SELECCIONADO DE ENTRE HIDROCARBILO, HIDROCARBILO SUSTITUIDO CON PERFLUOR, SILILO, GERMILO Y SUS MEZCLAS, ESTANDO DICHO GRUPO INDENILO UNIDO DE MANERA COVALENTE CON EL METAL POR MEDIO DE UN GRUPO LIGANDO DIVALENTE, SUS DERIVADOS CATALITICOS Y SU UTILIZACION COMO CATALIZADORES DE POLIMERIZACION.
ES96936227T 1995-10-27 1996-10-03 Complejos metalicos que contienen indenilo sustituido y procedimiento de polimerizacion de olefinas. Expired - Lifetime ES2183978T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US591395P 1995-10-27 1995-10-27

Publications (1)

Publication Number Publication Date
ES2183978T3 true ES2183978T3 (es) 2003-04-01

Family

ID=21718328

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96936227T Expired - Lifetime ES2183978T3 (es) 1995-10-27 1996-10-03 Complejos metalicos que contienen indenilo sustituido y procedimiento de polimerizacion de olefinas.

Country Status (22)

Country Link
EP (1) EP0874860B1 (es)
JP (1) JP4454698B2 (es)
KR (1) KR100419698B1 (es)
CN (1) CN1098857C (es)
AR (1) AR006266A1 (es)
AT (1) ATE227729T1 (es)
AU (1) AU717869B2 (es)
BR (1) BR9611128A (es)
CA (1) CA2229608C (es)
CZ (1) CZ129998A3 (es)
DE (1) DE69624839T2 (es)
ES (1) ES2183978T3 (es)
HU (1) HUP9802868A3 (es)
MY (1) MY127666A (es)
NO (1) NO322510B1 (es)
PL (1) PL186283B1 (es)
PT (1) PT874860E (es)
RO (1) RO118295B1 (es)
RU (1) RU2175325C2 (es)
TW (1) TW430674B (es)
WO (1) WO1997015583A1 (es)
ZA (1) ZA969000B (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5965756A (en) * 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
ID21507A (id) * 1996-12-19 1999-06-17 Dow Chemical Co Kompleks logam yang mengandung indenil tersubstitusi pada 3-aril dan proses polimerisasinya
US6420507B1 (en) 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
AR012645A1 (es) * 1997-05-01 2000-11-08 Dow Global Technologies Inc Polimeros de alfa-olefinas preparados por polimerizacion en presencia de complejos de metales que contienen grupos indenilo
US6630545B2 (en) 1997-09-15 2003-10-07 The Dow Chemical Company Polymerization process
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
DK0980375T3 (da) * 1998-01-30 2006-03-13 Boulder Scient Co Syntese af silylerede og N-silylerede forbindelser
CN1134467C (zh) 1998-11-02 2004-01-14 杜邦唐弹性体公司 剪切稀化的乙烯/α-烯烃共聚体及它们的制备
JP4964389B2 (ja) 2000-06-30 2012-06-27 ダウ グローバル テクノロジーズ エルエルシー 多環式、縮合環化合物、金属錯体及び重合方法
US6806327B2 (en) 2000-06-30 2004-10-19 Dow Global Technologies Inc. Substituted polycyclic, fused ring compounds, metal complexes and polymerization process
US6946531B2 (en) 2001-05-14 2005-09-20 Dow Global Technologies Inc. Low molecular weight ethylene interpolymers and polymerization process
ES2240735T3 (es) * 2001-05-14 2005-10-16 Dow Global Technologies Inc. Complejos metalicos ciclopentadienilo 3-aril-sustituido y procedimiento de polimerizacion.
ATE403684T1 (de) * 2002-03-14 2008-08-15 Dow Global Technologies Inc Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US8957167B2 (en) 2009-07-28 2015-02-17 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
CA2724943A1 (en) * 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
EP2683764B1 (en) 2011-03-08 2018-07-04 Dow Global Technologies LLC Process for recycling solvent used in an ethylene-based polymerization reaction
US8664461B2 (en) * 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
EP3492532A1 (en) 2015-01-06 2019-06-05 Scg Chemicals Co. Ltd. Sio2-layered double hydroxide microspheres and methods of making them
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
GB201610457D0 (en) * 2016-06-15 2016-07-27 Scg Chemicals Co Ltd Catalysts
KR101870513B1 (ko) 2016-06-29 2018-06-22 강정영 소형 탈취장치
CN112939844B (zh) * 2019-12-10 2023-02-03 华东师范大学 一种多取代四氢咔唑及其衍生物及其合成方法和应用
US20240124618A1 (en) 2021-01-12 2024-04-18 Exxonmobil Chemical Patents Inc. Asymmetric Constrained Geometry Catalysts

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
ATE147748T1 (de) * 1993-06-24 1997-02-15 Dow Chemical Co Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren
JP3795072B2 (ja) * 1993-11-18 2006-07-12 出光興産株式会社 遷移金属化合物，オレフィン重合用触媒，該触媒を用いたオレフィン系重合体の製造方法
AU700074B2 (en) * 1994-09-02 1998-12-17 Dow Chemical Company, The Thermoset elastomers

Also Published As

Publication number Publication date
ZA969000B (en) 1998-04-28
BR9611128A (pt) 1999-03-30
DE69624839D1 (de) 2002-12-19
RO118295B1 (ro) 2003-04-30
WO1997015583A1 (en) 1997-05-01
AR006266A1 (es) 1999-08-11
DE69624839T2 (de) 2003-08-28
JPH11514376A (ja) 1999-12-07
CN1098857C (zh) 2003-01-15
KR19990067045A (ko) 1999-08-16
PL326426A1 (en) 1998-09-14
MY127666A (en) 2006-12-29
CN1200735A (zh) 1998-12-02
ATE227729T1 (de) 2002-11-15
AU7392996A (en) 1997-05-15
CZ129998A3 (cs) 1998-08-12
JP4454698B2 (ja) 2010-04-21
AU717869B2 (en) 2000-04-06
HUP9802868A3 (en) 1999-04-28
NO981854L (no) 1998-06-23
PL186283B1 (pl) 2003-12-31
NO981854D0 (no) 1998-04-24
TW430674B (en) 2001-04-21
KR100419698B1 (ko) 2004-05-17
CA2229608C (en) 2005-06-21
PT874860E (pt) 2003-02-28
NO322510B1 (no) 2006-10-16
CA2229608A1 (en) 1997-05-01
EP0874860B1 (en) 2002-11-13
HUP9802868A2 (hu) 1999-03-29
EP0874860A1 (en) 1998-11-04
RU2175325C2 (ru) 2001-10-27

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