DE69005819D1 - Thiolgruppen enthaltende polymerisation-co-katalysatoren. - Google Patents

Thiolgruppen enthaltende polymerisation-co-katalysatoren.

Info

Publication number
DE69005819D1
DE69005819D1 DE90906994T DE69005819T DE69005819D1 DE 69005819 D1 DE69005819 D1 DE 69005819D1 DE 90906994 T DE90906994 T DE 90906994T DE 69005819 T DE69005819 T DE 69005819T DE 69005819 D1 DE69005819 D1 DE 69005819D1
Authority
DE
Germany
Prior art keywords
polymerization
thiol groups
catalysts containing
containing thiol
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE90906994T
Other languages
English (en)
Other versions
DE69005819T2 (de
Inventor
Gualtiero Giovando
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Peter Srl
Akzo NV
Original Assignee
Saint Peter Srl
Akzo NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT8967301A external-priority patent/IT1232850B/it
Priority claimed from IT8967302A external-priority patent/IT1232851B/it
Priority claimed from IT67954A external-priority patent/IT1239005B/it
Priority claimed from IT06810989A external-priority patent/IT1238066B/it
Application filed by Saint Peter Srl, Akzo NV filed Critical Saint Peter Srl
Application granted granted Critical
Publication of DE69005819D1 publication Critical patent/DE69005819D1/de
Publication of DE69005819T2 publication Critical patent/DE69005819T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C08F299/0442—Catalysts
    • C08F299/0464—Metals or metal containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66—Mercaptans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyesters Or Polycarbonates (AREA)
DE69005819T 1989-04-26 1990-04-26 Thiolgruppen enthaltende polymerisation-co-katalysatoren. Expired - Fee Related DE69005819T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
IT8967301A IT1232850B (it) 1989-04-26 1989-04-26 Acceleranti per l'indurimento di resine poliesteri insature, maleiche, alliliche ed epossidiche e procedimenti di indurimento che li utlizzano
IT8967302A IT1232851B (it) 1989-04-26 1989-04-26 Composti tiolici attivi come co-catalizzatori per la polimerizzazione di resine poliesteri insature, maleiche, alliliche o epossidiche
IT67954A IT1239005B (it) 1989-11-07 1989-11-07 Fosfiti e fosfine organiche come catalizzatori ed acceleranti per l'indurimento di resine epossidiche anche in presenza di mercaptani, sali di litio ed anidridi organiche.
IT06810989A IT1238066B (it) 1989-12-18 1989-12-18 Composti tiolici attivati od inibiti, con gruppi funzionali particolari nella loro molecola o con composti ad essi aggiunti, ad azione complessante e/o sinergica, impiegati come co-catalizzatori od induritori per la polimerizzazione di resine epossidiche e resine insature: poliesteri, maleiche, alliliche, viniliche
PCT/EP1990/000729 WO1990012826A1 (en) 1989-04-26 1990-04-26 Thiolic compound polymerization cocatalysts

Publications (2)

Publication Number Publication Date
DE69005819D1 true DE69005819D1 (de) 1994-02-17
DE69005819T2 DE69005819T2 (de) 1994-07-28

Family

ID=27452968

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69005819T Expired - Fee Related DE69005819T2 (de) 1989-04-26 1990-04-26 Thiolgruppen enthaltende polymerisation-co-katalysatoren.

Country Status (7)

Country Link
US (1) US5310826A (de)
EP (1) EP0470139B1 (de)
JP (1) JPH04504873A (de)
CA (1) CA2053856A1 (de)
DE (1) DE69005819T2 (de)
ES (1) ES2062524T3 (de)
WO (1) WO1990012826A1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265519B1 (en) 1998-12-08 2001-07-24 Molex Incorporated Thiolamide curing agents
DE102004022106A1 (de) 2004-05-05 2005-11-24 Bayer Ag Verwendung von Metall-Alkandithiole als Vernetzungsagenzien für ungesättigte Kautschuke
EP1705215A1 (de) * 2005-03-23 2006-09-27 DSM IP Assets B.V. Harzzusammensetzungen ohne Abtrift der Gelzeit
EP1772502A1 (de) * 2005-10-07 2007-04-11 DSMIP Assets B.V. Oxidativ trocknende Zusammensetzung enthaltend 1,2 dioxo Verbindungen zur Herstellung von dünnen Schichten
CN101484509B (zh) * 2006-07-06 2012-07-04 帝斯曼知识产权资产管理有限公司 自由基固化的方法
ATE453673T1 (de) * 2006-07-06 2010-01-15 Dsm Ip Assets Bv Ungesättigtes polyesterharz oder vinylesterharz enthaltende zusammensetzungen
CN105764958B (zh) * 2013-12-12 2017-12-08 阿克苏诺贝尔化学品国际有限公司 固化自由基可固化树脂的方法
US9284446B2 (en) * 2013-12-26 2016-03-15 Itaconix Corporation Soluble aqueous compositions of zinc salts of selected polyitaconic acid polymers
US9790395B2 (en) 2013-12-26 2017-10-17 Itaconix Corporation Soluble aqueous compositions of zinc salts of selected polyitaconic acid polymers
EP3481893A1 (de) 2016-07-08 2019-05-15 United Initiators GmbH Beschleunigte härtung von ungesättigten polymerharzen
BR112019004816A2 (pt) * 2016-09-12 2019-09-03 Poly6 Tech Inc método de reciclagem de alto desempenho, de um vaso, para resíduo de polímero usando síntese de polímero renovável
SG11201902790SA (en) * 2016-10-26 2019-05-30 Showa Denko Kk Curing accelerator and radical polymerizable resin composition
JP7368366B2 (ja) 2018-02-19 2023-10-24 アーケマ・インコーポレイテッド 長いオープンタイムを有する、加速されたペルオキシド硬化樹脂組成物
JP7329350B2 (ja) * 2019-03-29 2023-08-18 株式会社ダイセル 硬化性エポキシ樹脂組成物

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL268646A (de) * 1960-08-26
US3291776A (en) * 1962-10-26 1966-12-13 Shell Oil Co Process for curing polyepoxides with polymercaptans
US3318974A (en) * 1965-03-23 1967-05-09 Bell Telephone Labor Inc Unsaturated polyester curing system consisting of cumene hydroperoxide, methylethyl ketone peroxide and thioglycolic acid
US3553283A (en) * 1967-06-29 1971-01-05 Phillips Petroleum Co Epoxy resin cured with polymercaptan ester as olefin polymer coating
GB1170983A (en) * 1967-08-04 1969-11-19 Bp Chem Int Ltd Process for the Production of Cured Products.
US3626031A (en) * 1968-06-04 1971-12-07 Atlantic Richfield Co Vinyl halide polymer stabilized with partial ester salt of maleic anhydride-vinyl compound polymer
DE2025410C3 (de) * 1970-05-25 1978-04-13 Bayer Ag, 5090 Leverkusen Verfahren zum Härten ungesättigter Polyesterform- und -Überzugsmassen
US3839494A (en) * 1970-11-16 1974-10-01 Dow Chemical Co Thiol-diene adducts as epoxy resin curing agents
US4120875A (en) * 1974-08-26 1978-10-17 M&T Chemicals Inc. Novel curing agents derived from organothiostannoic acids
US4092293A (en) * 1976-06-24 1978-05-30 Diamond Shamrock Corporation Polymercaptans for curing epoxy resins and method of preparation thereof
DE2901685A1 (de) * 1978-01-20 1979-07-26 Ciba Geigy Ag Epoxidhaltige massen und deren polymerisation
US4153586A (en) * 1978-03-13 1979-05-08 Ppg Industries, Inc. Process of making epoxy resins modified with mercaptocarboxylates
US4177173A (en) * 1978-12-20 1979-12-04 Diamond Shamrock Corporation Polyepoxide curing by polymercaptans catalyzed by dimethylamino alkyl ethers
JPS5740524A (en) * 1980-08-25 1982-03-06 Toshiba Corp Epoxy resin composition
US4329263A (en) * 1980-12-01 1982-05-11 Tenneco Chemicals, Inc. Accelerator systems for polyester resin compositions
US4380605A (en) * 1981-09-21 1983-04-19 Pennwalt Corporation Room temperature crosslinking unsaturated polyester resins
US4446264A (en) * 1982-04-15 1984-05-01 The Goodyear Tire & Rubber Company Synergistic antioxidant mixtures
JPS59126430A (ja) * 1983-01-07 1984-07-21 Denki Kagaku Kogyo Kk 半導体封止用エポキシ樹脂組成物
US4571420A (en) * 1984-02-17 1986-02-18 Rohm And Haas Company Quick-cure, flexible polymer composition
DE3572182D1 (en) * 1984-04-28 1989-09-14 Ciba Geigy Ag Curable compositions
US4663072A (en) * 1984-12-24 1987-05-05 Ford Motor Company Acid anhydride mixtures in paste form useful for curing epoxy resins and a dual catalyst system therefor
JPS62212418A (ja) * 1986-03-13 1987-09-18 Mitsubishi Petrochem Co Ltd 一液性エポキシ樹脂組成物
JPS62257936A (ja) * 1986-05-02 1987-11-10 Showa Highpolymer Co Ltd 硬化可能な組成物
JPS63186727A (ja) * 1987-01-29 1988-08-02 Kashima Kogyo Kk ゴム状弾性を有するエポキシ樹脂組成物
JPH0784512B2 (ja) * 1987-06-24 1995-09-13 三菱電機株式会社 半導体封止用エポキシ樹脂組成物
JPH01174518A (ja) * 1987-12-28 1989-07-11 Mitsui Petrochem Ind Ltd トナー用エポキシ樹脂およびこれをバインダー樹脂とする静電荷像現像用トナー
US4879414A (en) * 1988-02-17 1989-11-07 Henkel Corporation Polythiols and use as epoxy resin curing agents
JPH01294726A (ja) * 1988-05-20 1989-11-28 Mitsubishi Petrochem Co Ltd 一液性エポキシ樹脂組成物

Also Published As

Publication number Publication date
EP0470139B1 (de) 1994-01-05
ES2062524T3 (es) 1994-12-16
EP0470139A1 (de) 1992-02-12
DE69005819T2 (de) 1994-07-28
WO1990012826A1 (en) 1990-11-01
CA2053856A1 (en) 1990-10-27
JPH04504873A (ja) 1992-08-27
US5310826A (en) 1994-05-10

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee