ES2181728T3 - Complejos de metaloceno con grupos heterofuncionales en el sistema de ciclopentadienilo. - Google Patents

Complejos de metaloceno con grupos heterofuncionales en el sistema de ciclopentadienilo.

Info

Publication number
ES2181728T3
ES2181728T3 ES95102489T ES95102489T ES2181728T3 ES 2181728 T3 ES2181728 T3 ES 2181728T3 ES 95102489 T ES95102489 T ES 95102489T ES 95102489 T ES95102489 T ES 95102489T ES 2181728 T3 ES2181728 T3 ES 2181728T3
Authority
ES
Spain
Prior art keywords
rent
aril
brochure
horrow
arilalquil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95102489T
Other languages
English (en)
Inventor
Franz Dr Langhauser
David Dr Fischer
Jurgen Dr Kerth
Gunther Dr Schweier
Hans-Herbert Prof Brintzinger
Elke Barsties
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2181728T3 publication Critical patent/ES2181728T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30—Germanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION SE REFIERE A COMPLEJO METALOCENO DE LA FORMULA GENERAL I EN DONDE LOS SUSTITUYENTES TIENEN EL SIGUIENTE SIGNIFICADO: M SIGNIFICA TITANIO, ZIRCONIO, HAFNIO, VANADIO, NIOBIO O TANTALIO, X ES FLUOR, CLORO, BROMO, YODO, HIDROGENO, C1 - HASTA C10 ALQUIL, C6 - HASTA C15 - ARIL O - OR5, DONDE R5 SIGNIFICA C1 - HASTA C10 - ALQUIL, C6 - HASTA C15 - ARIL, ALQUILARIL, ARILALQUIL, FLUORALQUIL O FLUORARIL CON 1 HASTA 10 ATOMOS DE C EN RESTO ALQUIL Y 6 HASTA 20 ATOMOS EN RESTO ARIL, R1 HASTA R3 Y R6 HASTA R8 SIGNIFICAN HIDROGENO, C1 - HASTA C10 ALQUIL, CICLOALQUIL DE 5 HASTA 7 MIEMBROS, QUE PUEDE PORTAR POR SU PARTE C1 - HASTA C10 - ALQUIL COMO SUSTITUYENTES, C6 - HASTA C15 - ARIL O ARILALQUIL, DONDE EVENTUALMENTE PUEDEN SER TAMBIEN DOS RESTOS VECINOS DE FORMA CONJUNTA CON 4 HASTA 5 ATOMOS DE C MOSTRANDO GRUPOS CICLICOS O SI(R10)3 CON R10 SIGNIFICA C1 - HASTA C10 - ALQUIL, C6 - HASTA C15 - ARIL O C3 - HASTA C10 - CICLOALQUIL, R4 ES DONDE R9 ES HIDROGENO, C1 - HASTA C10 - ALQUIL, CICLOALQUILDE 5 HASTA 7 MIEMBROS, QUE POR SU PARTE PUEDE PORTAR C1 - HASTA C10 - ALQUIL COMO SUSTITUYENTE, C6 - HASTA C15 - ARIL O ARILALQUIL, DONDE EVENTUALMENTE PUEDEN SER TAMBIEN DOS RESTOS VECINOS DE FORMA CONJUNTA CON 4 HASTA 5 ATONOS DE C MOSTRANDO GRUPOS CICLICOS, SI(R13)3 O Y SISTEMA DE LIGANDURA DE LA FORMULA GENERAL II.
ES95102489T 1994-03-03 1995-02-22 Complejos de metaloceno con grupos heterofuncionales en el sistema de ciclopentadienilo. Expired - Lifetime ES2181728T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4406963A DE4406963A1 (de) 1994-03-03 1994-03-03 Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem

Publications (1)

Publication Number Publication Date
ES2181728T3 true ES2181728T3 (es) 2003-03-01

Family

ID=6511703

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95102489T Expired - Lifetime ES2181728T3 (es) 1994-03-03 1995-02-22 Complejos de metaloceno con grupos heterofuncionales en el sistema de ciclopentadienilo.

Country Status (7)

Country Link
US (2) US5585509A (es)
EP (1) EP0670325B1 (es)
JP (1) JP3723597B2 (es)
DE (2) DE4406963A1 (es)
ES (1) ES2181728T3 (es)
TW (1) TW429265B (es)
ZA (1) ZA951724B (es)

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IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
DE59600760D1 (de) * 1995-06-12 1998-12-10 Targor Gmbh Übergangsmetallverbindung
DE19618007A1 (de) * 1996-05-04 1997-11-06 Basf Ag Verfahren zur Wiedergewinnung von Metallocenkomplexen
TR199900589T2 (xx) * 1996-08-08 1999-07-21 The Dow Chemical Company 2 heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem.
JP3407074B2 (ja) * 1996-08-08 2003-05-19 ザ ダウ ケミカル カンパニー ３―ヘテロ原子置換シクロペンタジエニル含有金属錯体及びオレフィン重合方法
FI971565A (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
FI972230A (fi) 1997-01-28 1998-07-29 Borealis As Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US5866706A (en) * 1997-06-09 1999-02-02 Boulder Scientific Co. Preparation and separation of RAC and MESO compound mixtures
DE19728126A1 (de) * 1997-07-02 1999-01-07 Bayer Ag Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen
US6046346A (en) * 1997-12-26 2000-04-04 Honshu Chemical Industry Co., Ltd. Production of alkali metal cyclopentadienylide and production of dihalobis (η-substituted-cyclopentadienyl) zirconium from alkali metal cyclopentadienylide
DE19805329A1 (de) * 1998-02-11 1999-08-12 Basf Ag Spritzstreckgeblasene Behälter aus Olefinpolymerisaten
DE19813657A1 (de) 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE69940652D1 (de) * 1998-06-25 2009-05-07 Idemitsu Kosan Co Propylenpolymer und Zusammensetzung damit, Formobjekt und Laminat damit sowie Verfahren zur Herstellung von Propylenpolymer und einer Zusammensetzung damit
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US6326493B1 (en) 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
US6479646B1 (en) * 1999-10-22 2002-11-12 Chisso Corporation Metallocene compounds having indenyl ligand and catalysts for olefin polymerization containing the same
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
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US7807769B2 (en) * 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
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US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US7276567B2 (en) 2004-04-16 2007-10-02 Exxonmobil Chemical Patents Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
BRPI0513057A (pt) * 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
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US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
US7868197B2 (en) * 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
KR100936349B1 (ko) * 2006-11-23 2010-01-12 주식회사 엘지화학 새로운 금속 시클로펜타디엔나이드의 제조방법
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
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US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
EP2160419B1 (en) 2007-06-04 2013-11-13 ExxonMobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
EP2195349B1 (en) * 2007-09-13 2012-07-11 ExxonMobil Research and Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
US7910637B2 (en) * 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
WO2009082463A1 (en) * 2007-12-20 2009-07-02 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
CN103254514B (zh) * 2007-12-20 2015-11-18 埃克森美孚研究工程公司 全同立构聚丙烯和乙烯-丙烯共聚物的共混物
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
EP2103634A1 (en) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Production of propylene-based polymers
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
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EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105377905B (zh) 2013-07-17 2018-09-14 埃克森美孚化学专利公司 茂金属和由其衍生的催化剂组合物
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
KR101659540B1 (ko) * 2013-09-30 2016-09-23 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
EP3885373A1 (en) 2015-06-05 2021-09-29 ExxonMobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
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US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
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DE4406964A1 (de) * 1994-03-03 1995-09-07 Basf Ag Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme

Also Published As

Publication number Publication date
EP0670325A2 (de) 1995-09-06
TW429265B (en) 2001-04-11
DE4406963A1 (de) 1995-09-07
JP3723597B2 (ja) 2005-12-07
EP0670325A3 (de) 1997-05-28
US5756608A (en) 1998-05-26
DE59510314D1 (de) 2002-09-19
ZA951724B (en) 1996-09-02
JPH07258282A (ja) 1995-10-09
EP0670325B1 (de) 2002-08-14
US5585509A (en) 1996-12-17

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