ES2176006T3 - Procedimiento para la obtencion de polimeros de estireno explandibles,que contienen particulas de grafito expansivo. - Google Patents

Procedimiento para la obtencion de polimeros de estireno explandibles,que contienen particulas de grafito expansivo.

Info

Publication number
ES2176006T3
ES2176006T3 ES99936512T ES99936512T ES2176006T3 ES 2176006 T3 ES2176006 T3 ES 2176006T3 ES 99936512 T ES99936512 T ES 99936512T ES 99936512 T ES99936512 T ES 99936512T ES 2176006 T3 ES2176006 T3 ES 2176006T3
Authority
ES
Spain
Prior art keywords
procedure
styrene polymers
graphite particles
expandable styrene
expansive graphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99936512T
Other languages
English (en)
Inventor
Guiscard Gluck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2176006T3 publication Critical patent/ES2176006T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/09—Pre-expansion of foamed polystyrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Procedimiento para la obtención de polímeros de estireno (EPS) expandibles mediante polimerización de estireno, en caso dado conjuntamente con un 20% de su peso de comonómeros, en suspensión acuosa en presencia de partículas de grafito y con adición de un propulsante antes, durante o después de la polimerización, caracterizado porque se emplea, como partículas de grafito, grafito expansivo expandido con una densidad menor que 1,5 g/cm3.
ES99936512T 1998-07-27 1999-07-12 Procedimiento para la obtencion de polimeros de estireno explandibles,que contienen particulas de grafito expansivo. Expired - Lifetime ES2176006T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19833664 1998-07-27

Publications (1)

Publication Number Publication Date
ES2176006T3 true ES2176006T3 (es) 2002-11-16

Family

ID=7875394

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99936512T Expired - Lifetime ES2176006T3 (es) 1998-07-27 1999-07-12 Procedimiento para la obtencion de polimeros de estireno explandibles,que contienen particulas de grafito expansivo.

Country Status (15)

Country Link
US (1) US6384094B1 (es)
EP (1) EP1102807B1 (es)
JP (1) JP2002521543A (es)
KR (1) KR100573636B1 (es)
CN (1) CN1114649C (es)
AT (1) ATE215582T1 (es)
AU (1) AU5158499A (es)
BR (1) BR9912446A (es)
CZ (1) CZ292351B6 (es)
DE (1) DE59901144D1 (es)
ES (1) ES2176006T3 (es)
NO (1) NO325667B1 (es)
PL (1) PL194984B1 (es)
RU (1) RU2223984C2 (es)
WO (1) WO2000006635A1 (es)

Families Citing this family (37)

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US20050282952A1 (en) * 2000-01-21 2005-12-22 Cyclics Corporation Graphite-polyester composites made from macrocyclic polyester oligomers
MXPA02009492A (es) * 2000-03-27 2003-02-12 Apache Prod Co Espuma pirorresistente y productos de espuma, metodos y dispersiones para su elaboracion.
ITMI20021711A1 (it) * 2002-07-31 2004-02-01 Polimeri Europa Spa Polimeri vinilaromatici espandibili in perle e procedimento per la loro preparazione.
US7105108B2 (en) * 2002-08-15 2006-09-12 Advanced Energy Technology Inc. Graphite intercalation and exfoliation process
ES2379460T3 (es) * 2002-12-18 2012-04-26 Synbra Technology B.V. Materiales resistentes al fuego
US8568632B2 (en) 2003-11-26 2013-10-29 Owens Corning Intellectual Capital, Llc Method of forming thermoplastic foams using nano-particles to control cell morphology
US7605188B2 (en) * 2004-12-31 2009-10-20 Owens Corning Intellectual Capital, Llc Polymer foams containing multi-functional layered nano-graphite
US9359481B2 (en) 2003-11-26 2016-06-07 Owens Corning Intellectual Capital, Llc Thermoplastic foams and method of forming them using nano-graphite
EP1709110B1 (en) * 2004-01-30 2020-03-18 Synbra Propor B.V. Expanded polystyrene bead having functional skin layer, manufacturing process thereof, and functional eps product and manufacturing process thereof using the same
DE102004028768A1 (de) * 2004-06-16 2005-12-29 Basf Ag Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit
DE102004049912A1 (de) * 2004-10-13 2006-04-20 Bosch Rexroth Aktiengesellschaft Gliederkette
KR100602205B1 (ko) * 2004-12-18 2006-07-19 금호석유화학 주식회사 팽창흑연을 함유한 불연성 난연 폴리스티렌 발포체수지입자의 제조방법
US9187608B2 (en) 2005-09-08 2015-11-17 Owens Corning Intellectual Capital, Llc Polystyrene foam containing a modifier-free nanoclay and having improved fire protection performance
KR100782311B1 (ko) * 2005-11-22 2007-12-06 금호석유화학 주식회사 단열 특성이 우수한 발포성 폴리스티렌 입자의 제조 방법
US20070173630A1 (en) * 2005-12-02 2007-07-26 Cyclics Corporation Macrocyclic polyester oligomers as flow modifier additives for thermoplastics
FR2924263B1 (fr) * 2007-11-22 2012-10-12 Univ Toulouse 3 Paul Sabatier Procede de fabrication d'un solide conducteur thermique et/ou electrique.
IT1392391B1 (it) * 2008-12-19 2012-03-02 Polimeri Europa Spa Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti
EP2387595B1 (en) * 2009-01-15 2019-06-26 Dow Global Technologies LLC Polymer foam with low bromine content
EA016792B1 (ru) * 2009-04-10 2012-07-30 Сергей Валерьевич Кажуро Способ получения пенопласта с графитовым наполнителем и теплоизоляционное изделие на его основе
NL2004587C2 (nl) * 2010-04-21 2011-10-24 Synbra Tech Bv Isolerend geschuimd vormdeel.
RU2448130C2 (ru) * 2010-07-23 2012-04-20 Общество с ограниченной ответственностью "ПОЛИСТИРОЛ" (ООО "ПОЛИСТИРОЛ") Способ получения способного вспениваться полистирольного гранулята
CN103298867B (zh) * 2010-12-30 2015-01-07 第一毛织株式会社 泡沫聚苯乙烯基珠粒及其制造方法
CN102492232B (zh) * 2011-12-08 2013-09-25 山西中环绿科环境工程项目管理有限公司 一种膨胀石墨聚苯板的制备方法
KR101886435B1 (ko) 2012-03-08 2018-08-07 현대자동차주식회사 팽창 그라파이트에 팽창 고분자 비드가 충전된 하이브리드 필러를 함유한 고방열 복합재 및 그 제조방법
US9120905B2 (en) 2012-07-10 2015-09-01 Ineos Europe Ag Process for the preparation of expandable polystyrene
EA029816B1 (ru) 2012-12-28 2018-05-31 Тотал Ресерч & Технолоджи Фелай Улучшенные вспениваемые виниловые ароматические полимеры
CN103333422B (zh) * 2013-03-22 2015-09-02 李春光 一种掺有低硫膨胀石墨的阻燃型可发性聚苯乙烯颗粒及其制备方法
ITMI20130834A1 (it) * 2013-05-22 2014-11-23 Versalis Spa Procedimento di polimerizzazione cationica per la sintesi di polimeri nano-strutturati contenenti grafene
CN104292680B (zh) * 2014-09-15 2017-02-15 刘崴崴 一种聚苯乙烯泡沫保温材料及其制备方法
KR20160072411A (ko) 2014-12-15 2016-06-23 금호석유화학 주식회사 성형성이 우수하고 단열성능과 난연성능이 우수한 발포성 폴리스티렌 입자 및 이의 제조방법
CN105860305A (zh) * 2015-01-23 2016-08-17 江苏业达鑫化工有限公司 一种功能性石墨母粒的制备方法及其应用
WO2018069186A1 (en) 2016-10-10 2018-04-19 Total Research & Technology Feluy Improved expandable vinyl aromatic polymers
PL3523363T3 (pl) 2016-10-10 2021-02-08 Total Research & Technology Feluy Ulepszone spienialne polimery winyloaromatyczne
US11834563B2 (en) 2016-10-10 2023-12-05 Totalenergies Onetech Belgium Expandable vinyl aromatic polymers
KR20190057841A (ko) 2017-11-21 2019-05-29 금호석유화학 주식회사 발포 폴리 스티렌 입자의 제조 방법
KR101992628B1 (ko) 2017-11-21 2019-06-25 금호석유화학 주식회사 발포 폴리 스티렌 입자의 제조 방법 및 발포 폴리 스티렌 입자
CN114341256A (zh) 2019-09-04 2022-04-12 道达尔能源一技术比利时公司 具有改进的阻燃性的可膨胀乙烯基芳族聚合物

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8611671D0 (en) * 1986-05-13 1986-06-18 Dunlop Ltd Flame-retardent latex foams
DE19629791A1 (de) * 1996-07-24 1998-01-29 Basf Ag Expandierbare Styrolpolymerisate
DE29616362U1 (de) * 1996-09-20 1996-11-07 Basf Ag, 67063 Ludwigshafen Fußbodendämmung
DE19716572A1 (de) * 1997-04-19 1998-10-22 Basf Ag Expandierbare Styrolpolymerisate

Also Published As

Publication number Publication date
KR100573636B1 (ko) 2006-04-26
NO20010445L (no) 2001-01-29
CN1310740A (zh) 2001-08-29
BR9912446A (pt) 2001-04-17
CZ2001305A3 (cs) 2001-10-17
WO2000006635A1 (de) 2000-02-10
JP2002521543A (ja) 2002-07-16
NO325667B1 (no) 2008-07-07
NO20010445D0 (no) 2001-01-26
AU5158499A (en) 2000-02-21
DE59901144D1 (de) 2002-05-08
US6384094B1 (en) 2002-05-07
CN1114649C (zh) 2003-07-16
PL345699A1 (en) 2002-01-02
RU2223984C2 (ru) 2004-02-20
EP1102807B1 (de) 2002-04-03
CZ292351B6 (cs) 2003-09-17
ATE215582T1 (de) 2002-04-15
EP1102807A1 (de) 2001-05-30
KR20010071028A (ko) 2001-07-28
PL194984B1 (pl) 2007-07-31

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