ES2174605T3 - Procedimiento para la oxidacion selectiva de alcoholes primarios. - Google Patents
Procedimiento para la oxidacion selectiva de alcoholes primarios.Info
- Publication number
- ES2174605T3 ES2174605T3 ES99919713T ES99919713T ES2174605T3 ES 2174605 T3 ES2174605 T3 ES 2174605T3 ES 99919713 T ES99919713 T ES 99919713T ES 99919713 T ES99919713 T ES 99919713T ES 2174605 T3 ES2174605 T3 ES 2174605T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- selective oxidation
- primary alcohols
- oxidation
- oxidizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000003138 primary alcohols Chemical class 0.000 title abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000004965 peroxy acids Chemical group 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 125000000075 primary alcohol group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H7/00—Compounds containing non-saccharide radicals linked to saccharide radicals by a carbon-to-carbon bond
- C07H7/02—Acyclic radicals
- C07H7/033—Uronic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
Abstract
Procedimiento para la oxidación de un alcohol primario usando un agente oxidante en presencia de una cantidad catalítica de un di-terc-alquilnitroxilo, caracterizado porque el agente oxidante es un perácido o un precursor del mismo y porque la oxidación se efectúa en presencia de 0,1-40 moles % de haluro, con respecto al alcohol primario.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98201495 | 1998-05-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2174605T3 true ES2174605T3 (es) | 2002-11-01 |
Family
ID=8233692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99919713T Expired - Lifetime ES2174605T3 (es) | 1998-05-07 | 1999-05-04 | Procedimiento para la oxidacion selectiva de alcoholes primarios. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6518419B1 (es) |
| EP (1) | EP1093467B1 (es) |
| JP (1) | JP2002513809A (es) |
| KR (1) | KR20010071212A (es) |
| CN (1) | CN1141322C (es) |
| AT (1) | ATE215097T1 (es) |
| AU (1) | AU746462B2 (es) |
| BR (1) | BR9910274A (es) |
| CA (1) | CA2331701C (es) |
| DE (1) | DE69901117T2 (es) |
| DK (1) | DK1093467T3 (es) |
| ES (1) | ES2174605T3 (es) |
| HU (1) | HUP0101777A3 (es) |
| IL (1) | IL139346A (es) |
| NZ (1) | NZ507873A (es) |
| PL (1) | PL188781B1 (es) |
| WO (1) | WO1999057158A1 (es) |
| ZA (1) | ZA200006305B (es) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3180131B2 (ja) | 1996-03-28 | 2001-06-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | アルデヒドで官能化されたセルロース性繊維とポリマーから作られた湿潤強度を有する紙製品 |
| US6524348B1 (en) | 1999-03-19 | 2003-02-25 | Weyerhaeuser Company | Method of making carboxylated cellulose fibers and products of the method |
| WO2002048197A1 (en) * | 2000-12-13 | 2002-06-20 | Sca Hygiene Products Zeist B.V. | Process for oxidising primary alcohols |
| US6919447B2 (en) | 2001-06-06 | 2005-07-19 | Weyerhaeuser Company | Hypochlorite free method for preparation of stable carboxylated carbohydrate products |
| US20030051834A1 (en) * | 2001-06-06 | 2003-03-20 | Weerawarna S. Ananda | Method for preparation of stabilized carboxylated cellulose |
| US6916466B2 (en) | 2001-07-11 | 2005-07-12 | Sca Hygiene Products Ab | Coupling of modified cyclodextrins to fibers |
| EP1329498A1 (en) * | 2002-01-18 | 2003-07-23 | Nederlandse Organisatie voor Toegepast-Natuuurwetenschappelijk Onderzoek TNO | Process for cleaning filters |
| US6789744B2 (en) * | 2002-01-29 | 2004-09-14 | Valeo Electrical Systems, Inc. | Fluid heater with a variable mass flow path |
| JP4820284B2 (ja) * | 2003-01-30 | 2011-11-24 | ニュートラスウィート プロパティ ホールディングス,インコーポレイテッド | 酸化剤としてNaOClを用いて第1級及び第2級アルコールを酸化する無臭素TEMPO系触媒システム |
| US7001483B2 (en) | 2003-08-05 | 2006-02-21 | Weyerhaeuser Company | Apparatus for making carboxylated pulp fibers |
| US7125469B2 (en) * | 2003-10-16 | 2006-10-24 | The Procter & Gamble Company | Temporary wet strength resins |
| DE10354259A1 (de) | 2003-11-20 | 2005-06-09 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von Carbonylreste-aufweisenden Organosiliciumverbindungen |
| BRPI0415764A (pt) | 2003-11-28 | 2006-12-26 | Eastman Chem Co | interpolìmero, produto de reação, métodos para converter uma hidroxila, para preparar uma forma estável de um interpolìmero, para converter um álcool primário, e para tratar um mamìfero necessitado do mesmo, composições para revestimento e farmacêutica oral, dispersão de pigmento, e, artigo |
| US6825384B1 (en) * | 2004-01-29 | 2004-11-30 | The Nutrasweet Company | Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant |
| EP1580228A1 (en) * | 2004-03-24 | 2005-09-28 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO | Process for gelatinising starch using a biodegradable polymer material bearing aldehyde groups |
| US7799485B2 (en) * | 2004-07-09 | 2010-09-21 | Nissan Motor Co., Ltd. | Fuel cell system and composition for electrode |
| WO2006006502A1 (ja) * | 2004-07-09 | 2006-01-19 | Nissan Motor Co., Ltd. | 燃料電池システム及び固体高分子電解質膜 |
| EP1666441A1 (en) * | 2004-12-03 | 2006-06-07 | Daiso Co., Ltd. | Oxidation method for primary or secondary alcohols |
| JP2006182764A (ja) * | 2004-12-03 | 2006-07-13 | Daiso Co Ltd | 第1級または第2級アルコールの新規酸化方法 |
| US7923231B2 (en) * | 2004-12-17 | 2011-04-12 | Cargill, Incorporated | Production of glucuronic acid using myo-inositol oxygenase from cryptococcus neoformans |
| US7259218B2 (en) * | 2005-02-17 | 2007-08-21 | The Procter + Gamble Company | Processes for making temporary wet strength additives |
| JP5205694B2 (ja) * | 2005-12-15 | 2013-06-05 | 日産自動車株式会社 | 燃料、燃料電池システム及び燃料電池車輌 |
| CN101069495B (zh) * | 2006-05-11 | 2011-12-07 | 广州神阳高新技术有限公司 | 过滤盒 |
| CN100463914C (zh) * | 2006-06-26 | 2009-02-25 | 重庆华邦制药股份有限公司 | 一种单糖苷酸纯化方法 |
| EP2108676B1 (en) * | 2008-04-03 | 2017-12-27 | OrganoClick AB | Crosslinked paper based material |
| US9512563B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Surface treated modified cellulose from chemical kraft fiber and methods of making and using same |
| US9512237B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Method for inhibiting the growth of microbes with a modified cellulose fiber |
| US9511167B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
| KR101805048B1 (ko) | 2009-05-28 | 2017-12-05 | 게페 첼루로제 게엠베하 | 화학적 크래프트 섬유로부터의 변형된 셀룰로즈 및 이들을 제조 및 사용하는 방법 |
| EP2309059A1 (en) | 2009-10-02 | 2011-04-13 | Organoclick Aktiebolag | Method of improving properties of cellulose-based fibrous sheet-formed materials |
| GB0918616D0 (en) * | 2009-10-23 | 2009-12-09 | 3M Innovative Properties Co | Method of preparing highly fluorinated carboxylic acids and their salts |
| CZ302503B6 (cs) * | 2009-12-11 | 2011-06-22 | Contipro C A.S. | Zpusob prípravy derivátu kyseliny hyaluronové oxidovaného v poloze 6 glukosaminové cásti polysacharidu selektivne na aldehyd a zpusob jeho modifikace |
| CZ2009836A3 (cs) * | 2009-12-11 | 2011-06-22 | Contipro C A.S. | Derivát kyseliny hyaluronové oxidovaný v poloze 6 glukosaminové cásti polysacharidu selektivne na aldehyd, zpusob jeho prípravy a zpusob jeho modifikace |
| AU2012268700B2 (en) | 2011-05-23 | 2017-02-02 | Gp Cellulose Gmbh | Softwood kraft fiber having improved whiteness and brightness and methods of making and using the same |
| WO2013106703A1 (en) | 2012-01-12 | 2013-07-18 | Georgia-Pacific Consumer Products Lp | A low viscosity kraft fiber having reduced yellowing properties and methods of making and using the same |
| CZ2012136A3 (cs) | 2012-02-28 | 2013-06-05 | Contipro Biotech S.R.O. | Deriváty na bázi kyseliny hyaluronové schopné tvorit hydrogely, zpusob jejich prípravy, hydrogely na bázi techto derivátu, zpusob jejich prípravy a pouzití |
| CA2869649C (en) | 2012-04-04 | 2019-01-29 | Stichting Dienst Landbouwkundig Onderzoek | Catalytic oxidation of uronic acids to aldaric acids |
| WO2013158384A1 (en) | 2012-04-18 | 2013-10-24 | Georgia-Pacific Consumer Products Lp | The use of surfactant to treat pulp and improve the incorporation of kraft pulp into fiber for the production of viscose and other secondary fiber products |
| CZ304512B6 (cs) | 2012-08-08 | 2014-06-11 | Contipro Biotech S.R.O. | Derivát kyseliny hyaluronové, způsob jeho přípravy, způsob jeho modifikace a použití |
| CZ2012842A3 (cs) | 2012-11-27 | 2014-08-20 | Contipro Biotech S.R.O. | Nanomicelární kompozice na bázi C6-C18-acylovaného hyaluronanu, způsob přípravy C6-C18-acylovaného hyaluronanu, způsob přípravy nanomicelární kompozice a stabilizované nanomicelární kompozice a použití |
| KR101980989B1 (ko) * | 2012-12-20 | 2019-05-21 | 화이자 인코포레이티드 | 당접합 방법 |
| KR101475136B1 (ko) * | 2013-02-07 | 2014-12-22 | 한양대학교 에리카산학협력단 | 수용액 상에서의 2-(4-포르밀페닐)프로피온산의 친환경적인 제조방법 |
| KR102180512B1 (ko) | 2013-02-08 | 2020-11-19 | 게페 첼루로제 게엠베하 | 개선된 알파 셀룰로스 함량을 갖는 연재 크래프트 섬유 및 화학적 셀룰로스 제품의 생산에서의 그의 용도 |
| US10138598B2 (en) | 2013-03-14 | 2018-11-27 | Gp Cellulose Gmbh | Method of making a highly functional, low viscosity kraft fiber using an acidic bleaching sequence and a fiber made by the process |
| EP2971338A2 (en) | 2013-03-15 | 2016-01-20 | GP Cellulose GmbH | A low viscosity kraft fiber having an enhanced carboxyl content and methods of making and using the same |
| ES2734726T3 (es) * | 2014-03-11 | 2019-12-11 | Du Pont | Poli alfa-1,2-glucano oxidado como reforzante de detergente |
| CZ2014150A3 (cs) | 2014-03-11 | 2015-05-20 | Contipro Biotech S.R.O. | Konjugáty oligomeru kyseliny hyaluronové nebo její soli, způsob jejich přípravy a použití |
| CZ2014451A3 (cs) | 2014-06-30 | 2016-01-13 | Contipro Pharma A.S. | Protinádorová kompozice na bázi kyseliny hyaluronové a anorganických nanočástic, způsob její přípravy a použití |
| CZ309295B6 (cs) | 2015-03-09 | 2022-08-10 | Contipro A.S. | Samonosný, biodegradabilní film na bázi hydrofobizované kyseliny hyaluronové, způsob jeho přípravy a použití |
| CZ2015398A3 (cs) | 2015-06-15 | 2017-02-08 | Contipro A.S. | Způsob síťování polysacharidů s využitím fotolabilních chránicích skupin |
| CZ306662B6 (cs) | 2015-06-26 | 2017-04-26 | Contipro A.S. | Deriváty sulfatovaných polysacharidů, způsob jejich přípravy, způsob jejich modifikace a použití |
| US9956536B2 (en) | 2015-08-04 | 2018-05-01 | Jiangnan University | Triple-responsive starch-based microgel and preparation method thereof |
| US12064732B2 (en) | 2016-02-17 | 2024-08-20 | Zeco, Llc | Methods and related apparatus for providing a processing solution for a food processing application |
| US11350640B1 (en) | 2016-08-12 | 2022-06-07 | Zee Company I, Llc | Methods and related apparatus for increasing antimicrobial efficacy in a poultry chiller tank |
| US10974211B1 (en) | 2016-02-17 | 2021-04-13 | Zee Company, Inc. | Peracetic acid concentration and monitoring and concentration-based dosing system |
| CZ308106B6 (cs) | 2016-06-27 | 2020-01-08 | Contipro A.S. | Nenasycené deriváty polysacharidů, způsob jejich přípravy a jejich použití |
| CA3040734A1 (en) | 2016-11-16 | 2018-05-24 | Gp Cellulose Gmbh | Modified cellulose from chemical fiber and methods of making and using the same |
| CN106832018A (zh) * | 2017-01-20 | 2017-06-13 | 青岛大学 | 一种高羧基含量氧化淀粉的制备方法 |
| CN115677480B (zh) * | 2022-10-19 | 2025-09-23 | 东南大学 | 一种温和条件下选择性氧化伯醇以制备酸的TiO2/NaBr光催化体系的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5334756A (en) * | 1991-03-26 | 1994-08-02 | Sandoz Ltd. | Carboxylate of certain polyoxyalkylene amines |
| US5362868A (en) * | 1993-06-18 | 1994-11-08 | Degussa Aktiengesellshaft | Thinning of granular starch |
| US5739352A (en) * | 1995-10-19 | 1998-04-14 | United Carbide Chemicals & Plastics Technology Corporation | Process for preparing carboxylic acids |
-
1999
- 1999-05-04 KR KR1020007012356A patent/KR20010071212A/ko not_active Abandoned
- 1999-05-04 JP JP2000547126A patent/JP2002513809A/ja active Pending
- 1999-05-04 CA CA002331701A patent/CA2331701C/en not_active Expired - Fee Related
- 1999-05-04 HU HU0101777A patent/HUP0101777A3/hu unknown
- 1999-05-04 ES ES99919713T patent/ES2174605T3/es not_active Expired - Lifetime
- 1999-05-04 WO PCT/NL1999/000272 patent/WO1999057158A1/en not_active Ceased
- 1999-05-04 NZ NZ507873A patent/NZ507873A/en not_active IP Right Cessation
- 1999-05-04 CN CNB998058637A patent/CN1141322C/zh not_active Expired - Fee Related
- 1999-05-04 AT AT99919713T patent/ATE215097T1/de active
- 1999-05-04 IL IL13934699A patent/IL139346A/en not_active IP Right Cessation
- 1999-05-04 EP EP99919713A patent/EP1093467B1/en not_active Expired - Lifetime
- 1999-05-04 DE DE69901117T patent/DE69901117T2/de not_active Expired - Lifetime
- 1999-05-04 BR BR9910274-9A patent/BR9910274A/pt not_active IP Right Cessation
- 1999-05-04 PL PL99343940A patent/PL188781B1/pl not_active IP Right Cessation
- 1999-05-04 AU AU37369/99A patent/AU746462B2/en not_active Ceased
- 1999-05-04 DK DK99919713T patent/DK1093467T3/da active
-
2000
- 2000-11-03 ZA ZA200006305A patent/ZA200006305B/en unknown
- 2000-11-07 US US09/706,767 patent/US6518419B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010071212A (ko) | 2001-07-28 |
| NZ507873A (en) | 2002-05-31 |
| WO1999057158A1 (en) | 1999-11-11 |
| CN1299373A (zh) | 2001-06-13 |
| IL139346A (en) | 2004-06-20 |
| HUP0101777A2 (hu) | 2001-12-28 |
| CA2331701A1 (en) | 1999-11-11 |
| CA2331701C (en) | 2008-11-18 |
| ATE215097T1 (de) | 2002-04-15 |
| AU746462B2 (en) | 2002-05-02 |
| PL343940A1 (en) | 2001-09-10 |
| DE69901117T2 (de) | 2002-09-05 |
| DK1093467T3 (da) | 2002-04-29 |
| US6518419B1 (en) | 2003-02-11 |
| EP1093467A1 (en) | 2001-04-25 |
| AU3736999A (en) | 1999-11-23 |
| BR9910274A (pt) | 2001-01-02 |
| DE69901117D1 (de) | 2002-05-02 |
| JP2002513809A (ja) | 2002-05-14 |
| PL188781B1 (pl) | 2005-04-29 |
| EP1093467B1 (en) | 2002-03-27 |
| ZA200006305B (en) | 2001-11-05 |
| CN1141322C (zh) | 2004-03-10 |
| HUP0101777A3 (en) | 2003-04-28 |
| IL139346A0 (en) | 2001-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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