ES2174476T3 - Purificacion de oxido de propileno. - Google Patents
Purificacion de oxido de propileno.Info
- Publication number
- ES2174476T3 ES2174476T3 ES98942636T ES98942636T ES2174476T3 ES 2174476 T3 ES2174476 T3 ES 2174476T3 ES 98942636 T ES98942636 T ES 98942636T ES 98942636 T ES98942636 T ES 98942636T ES 2174476 T3 ES2174476 T3 ES 2174476T3
- Authority
- ES
- Spain
- Prior art keywords
- propylene oxide
- acetaldehyde
- allows
- purification
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/32—Separation; Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
Abstract
La invención se refiere a un tratamiento eficaz de óxido de propileno que resulta de un proceso de epoxidación que utiliza metanol como solvente. Este tratamiento permite eliminar el acetaldehído por destilación fraccionada del producto de reacción bruto de epoxidación. En este tipo de destilación se utiliza el solvente metanol para reducir la volatilidad relativa de las impurezas acetaldehído, lo que permite obtener una fracción de residuo que contiene sensiblemente cualquier acetaldehído. Se retira el óxido de propileno purificado que presenta una concentración de acetaldehído en forma de un flujo de cabeza. Este procedimiento permite también separar eficazmente el agua del óxido de propileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/908,604 US6024840A (en) | 1997-08-08 | 1997-08-08 | Propylene oxide purification |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2174476T3 true ES2174476T3 (es) | 2002-11-01 |
Family
ID=25426028
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98942636T Expired - Lifetime ES2174476T3 (es) | 1997-08-08 | 1998-07-27 | Purificacion de oxido de propileno. |
Country Status (11)
Country | Link |
---|---|
US (1) | US6024840A (es) |
EP (1) | EP1003733B1 (es) |
JP (1) | JP4301727B2 (es) |
KR (1) | KR100559159B1 (es) |
CN (1) | CN100400526C (es) |
AU (1) | AU9069798A (es) |
BR (1) | BR9811144A (es) |
CA (1) | CA2300083C (es) |
DE (1) | DE69804630T2 (es) |
ES (1) | ES2174476T3 (es) |
WO (1) | WO1999007690A1 (es) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1122248A1 (de) | 2000-02-07 | 2001-08-08 | Degussa AG | Verfahren zur Epoxidierung von Olefinen |
EP1122247A1 (de) | 2000-02-07 | 2001-08-08 | Degussa AG | Verfahren zur Epoxidierung von Olefinen |
EP1122246A1 (de) | 2000-02-07 | 2001-08-08 | Degussa AG | Verfahren zur Epoxidierung von Olefinen |
DE50115570D1 (de) | 2001-01-08 | 2010-09-09 | Evonik Degussa Gmbh | Verfahren zur Epoxidierung von Olefinen |
DE10105527A1 (de) * | 2001-02-07 | 2002-08-08 | Basf Ag | Verfahren zur Herstellung eines Epoxids |
US6608219B2 (en) | 2001-06-13 | 2003-08-19 | Degussa Ag | Process for the epoxidation of olefins |
US6596881B2 (en) | 2001-06-13 | 2003-07-22 | Degussa Ag | Process for the epoxidation of olefins |
US6600055B2 (en) | 2001-06-13 | 2003-07-29 | Degussa Ag | Process for the epoxidation of olefins |
US6749668B2 (en) | 2001-06-18 | 2004-06-15 | Degussa Ag | Process for the recovery of combustible components of a gas stream |
US6610865B2 (en) | 2001-08-15 | 2003-08-26 | Degussa Ag | Process for the epoxidation of olefins |
US6596883B2 (en) | 2001-08-23 | 2003-07-22 | Degussa Ag | Process for the epoxidation of olefins |
US6500311B1 (en) * | 2001-09-21 | 2002-12-31 | Arco Chemical Technology, L.P. | Propylene oxide purification |
US6720436B2 (en) | 2002-03-18 | 2004-04-13 | Degussa Ag | Process for the epoxidation of olefins |
US7141683B2 (en) | 2002-05-02 | 2006-11-28 | Degussa Ag | Process for the epoxidation of olefins |
US7722847B2 (en) | 2002-09-30 | 2010-05-25 | Evonik Degussa Gmbh | Aqueous hydrogen peroxide solutions and method of making same |
US6838572B2 (en) | 2002-09-30 | 2005-01-04 | Degussa Ag | Process for the epoxidation of olefins |
US7169945B2 (en) | 2002-11-26 | 2007-01-30 | Degussa Ag | Process for the epoxidation of olefins |
EP1601708B1 (en) * | 2003-02-26 | 2006-12-27 | Shell Internationale Researchmaatschappij B.V. | Process for preparation of polyether polyols |
JP4673297B2 (ja) * | 2003-03-18 | 2011-04-20 | ダウ グローバル テクノロジーズ エルエルシー | プロピレンの過酸化水素とのエポキシ化反応により得られるプロピレンオキシドの精製 |
DE10317519A1 (de) * | 2003-04-16 | 2004-11-04 | Basf Ag | Verfahren zur Herstellung von Propylenoxid |
JP2007508406A (ja) * | 2003-10-10 | 2007-04-05 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | ポリエーテルポリオールの製造方法 |
JP4963022B2 (ja) * | 2005-11-25 | 2012-06-27 | 株式会社日本触媒 | エポキシ化合物の製造方法 |
US7105687B1 (en) | 2005-12-22 | 2006-09-12 | Lyondell Chemical Technology, L.P. | Propylene oxide purification and recovery |
US7718040B2 (en) * | 2007-03-23 | 2010-05-18 | Lyondell Chemical Technology, L.P. | Propylene oxide recovery process |
US8080678B2 (en) * | 2010-04-01 | 2011-12-20 | Lyondell Chemical Technology, L.P. | Purification of propylene oxide |
US8389750B2 (en) * | 2010-09-28 | 2013-03-05 | Lyondell Chemical Technology, L.P. | Purification of propylene oxide |
CN102093316B (zh) * | 2010-12-17 | 2013-06-12 | 中国海洋石油总公司 | 一种分离提纯环氧丙烷与甲醇的方法 |
US8981133B2 (en) | 2011-06-07 | 2015-03-17 | Lyondell Chemical Technology, L.P. | Alkylene oxide separation systems, methods, and apparatuses |
MY184844A (en) | 2015-11-26 | 2021-04-26 | Evonik Operations Gmbh | Process for the epoxidation of propene |
CN105712953A (zh) * | 2016-01-26 | 2016-06-29 | 江苏怡达化学股份有限公司 | 一种预纯化环氧丙烷的方法 |
CN105906584B (zh) * | 2016-03-01 | 2018-07-06 | 江苏怡达化学股份有限公司 | 脱除环氧丙烷反应混合物中的醛类的方法 |
BR112018075464B1 (pt) * | 2016-07-20 | 2022-11-22 | Basf Se | Processo para purificação de óxido de propileno |
BR112019000496B1 (pt) * | 2016-07-20 | 2022-12-06 | Dow Global Technologies Llc | Processo para preparar óxido de propileno |
CN106268688A (zh) * | 2016-08-21 | 2017-01-04 | 王琪宇 | 一种环氧丙烷提纯用吸附剂的制备方法 |
WO2018205244A1 (en) * | 2017-05-12 | 2018-11-15 | Evonik Degussa Gmbh | Process for the epoxidation of propene |
EP3406603A1 (en) | 2017-05-22 | 2018-11-28 | Evonik Degussa GmbH | Process for the epoxidation of propene |
CN113968830B (zh) * | 2020-07-24 | 2024-01-09 | 中国石油化工股份有限公司 | 环氧丙烷物流的分离方法和环氧化反应产物分离方法以及丙烯环氧化方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3715284A (en) * | 1970-09-16 | 1973-02-06 | Jefferson Chem Co Inc | Recovery of propylene oxide from contaminants by distillation in the presence of acetone or acetone-methanol mixtures |
US3881996A (en) * | 1973-11-21 | 1975-05-06 | Oxirane Corp | Recovery of propylene oxide by plural stage distillation |
US4140588A (en) * | 1977-08-05 | 1979-02-20 | Halcon Research And Development Corporation | Purification of propylene oxide by extractive distillation |
DE3038497C2 (de) * | 1980-10-11 | 1983-11-10 | Bayer Ag, 5090 Leverkusen | Verfahren und Vorrichtung zur Trennung von ein Azeotrop bildenden Gemischen |
US4584063A (en) * | 1982-06-28 | 1986-04-22 | Lloyd Berg | Separation of acetone from methanol by extractive distillation |
IT1152299B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
US4597834A (en) * | 1983-04-14 | 1986-07-01 | Lloyd Berg | Separation of methyl acetate from methanol by extractive distillation |
US4620901A (en) * | 1985-11-04 | 1986-11-04 | Lloyd Berg | Separation of acetone from methanol by extractive distillation |
ES2033693T3 (es) * | 1986-01-28 | 1993-04-01 | Eniricerche S.P.A. | Un procedimiento para la exposidacion de compuestos olefinicos. |
US5000825A (en) * | 1989-03-23 | 1991-03-19 | Arco Chemical Technology, Inc. | Monoepoxide purification |
US4971661A (en) * | 1989-10-20 | 1990-11-20 | Texaco Chemical Company | Purification of propylene oxide using an aqueous acetone extractive distillatin agent |
US5133839A (en) * | 1991-07-25 | 1992-07-28 | Arco Chemical Technology, L.P. | Lower alkylene oxide purification |
US5139622A (en) * | 1991-10-03 | 1992-08-18 | Texaco Chemical Company | Purification of propylene oxide by extractive distillation |
US5274138A (en) * | 1993-01-21 | 1993-12-28 | Texaco Chemical Company | Epoxidation process for manufacture of olefin oxide and alcohol |
US5453511A (en) * | 1993-12-23 | 1995-09-26 | Arco Chemical Technology, L.P. | Bis-piperidinium compounds |
US5489366A (en) * | 1994-03-28 | 1996-02-06 | Texaco Chemical Inc. | Recovery of purified and substantially anhydrous propylene oxide |
US5453160A (en) * | 1994-05-31 | 1995-09-26 | Texaco Chemical Inc. | Use of mixed polyoxypropylene glycols in the extractive distillation of propylene oxide |
US5646314A (en) * | 1994-11-16 | 1997-07-08 | Arco Chemical Technology, L.P. | Process for titanium silicalite-catalyzed epoxidation |
US5523426A (en) * | 1995-01-04 | 1996-06-04 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
US5693834A (en) * | 1995-03-15 | 1997-12-02 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
US5591875A (en) * | 1995-08-02 | 1997-01-07 | Chang; Te | Epoxidation Process |
-
1997
- 1997-08-08 US US08/908,604 patent/US6024840A/en not_active Expired - Fee Related
-
1998
- 1998-07-27 KR KR1020007001322A patent/KR100559159B1/ko not_active IP Right Cessation
- 1998-07-27 AU AU90697/98A patent/AU9069798A/en not_active Abandoned
- 1998-07-27 EP EP98942636A patent/EP1003733B1/en not_active Expired - Lifetime
- 1998-07-27 DE DE69804630T patent/DE69804630T2/de not_active Expired - Fee Related
- 1998-07-27 CA CA002300083A patent/CA2300083C/en not_active Expired - Fee Related
- 1998-07-27 JP JP2000506194A patent/JP4301727B2/ja not_active Expired - Lifetime
- 1998-07-27 BR BR9811144-2A patent/BR9811144A/pt not_active IP Right Cessation
- 1998-07-27 CN CNB988098032A patent/CN100400526C/zh not_active Expired - Fee Related
- 1998-07-27 ES ES98942636T patent/ES2174476T3/es not_active Expired - Lifetime
- 1998-07-27 WO PCT/EP1998/004693 patent/WO1999007690A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
BR9811144A (pt) | 2000-07-18 |
JP4301727B2 (ja) | 2009-07-22 |
AU9069798A (en) | 1999-03-01 |
KR100559159B1 (ko) | 2006-03-10 |
CA2300083C (en) | 2008-04-22 |
KR20010022725A (ko) | 2001-03-26 |
DE69804630T2 (de) | 2002-10-17 |
CN100400526C (zh) | 2008-07-09 |
DE69804630D1 (de) | 2002-05-08 |
WO1999007690A1 (en) | 1999-02-18 |
EP1003733A1 (en) | 2000-05-31 |
CN1273583A (zh) | 2000-11-15 |
CA2300083A1 (en) | 1999-02-18 |
JP2001512721A (ja) | 2001-08-28 |
EP1003733B1 (en) | 2002-04-03 |
US6024840A (en) | 2000-02-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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