ES2138054T3 - Procedimiento de sintesis de composiciones a base de oxidos mixtos de circonio y de cerio. - Google Patents
Procedimiento de sintesis de composiciones a base de oxidos mixtos de circonio y de cerio.Info
- Publication number
- ES2138054T3 ES2138054T3 ES94400235T ES94400235T ES2138054T3 ES 2138054 T3 ES2138054 T3 ES 2138054T3 ES 94400235 T ES94400235 T ES 94400235T ES 94400235 T ES94400235 T ES 94400235T ES 2138054 T3 ES2138054 T3 ES 2138054T3
- Authority
- ES
- Spain
- Prior art keywords
- sol
- pref
- compsn
- compositions based
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0242—Coating followed by impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20715—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/40—Mixed oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO PARA LA OBTENCION DE COMPOSICIONES A BASE DE OXIDOS MIXTOS DE ZIRCONIO Y DE CERIO QUE PRESENTAN SUPERFICIES ESPECIFICAS ELEVADAS Y TERMICAMENTE ESTABLES, CARACTERIZANDOSE DICHO PROCESO EN QUE COMPRENDE LAS SIGUIENTES ETAPAS: (I) SE MEZCLA, EN LAS PROPORCIONES ESTOQUIOMETRICAS QUE CORRESPONDEN A LAS DE LA COMPOSICION FINAL DESEADA, UN SOL DE ZIRCONIO POR UNA PARTE Y UN SOL DE CERIO POR OTRA PARTE, SIENDO LA RELACION R ENTRE EL DIAMETRO MEDIO R1 DE LAS PARTICULAS QUE CONSTITUYEN EL SOL DE ZIRCONIO Y EL DIAMETRO R2 DE LAS PARTICULAS QUE CONSTITUYEN EL SOL DE CERIO AL MENOS 5, (II) SE AÑADE UNA BASE EN LA MEZCLA ASI OBTENIDA, (III) SE RECUPERA EL PRECIPITADO ASI FORMADO Y POR FIN (IV) SE CALCINA EL PRECIPITADO ASI RECUPERADO. LA INVENCION SE REFIERE TAMBIEN A LAS COMPOSICIONES A BASE DE OXIDOS MIXTOS DE GRANDES SUPERFICIES ESPECIFICAS (> 10 M2/G) SUSCEPTIBLES DE SER OBTENIDAS, ASI COMO A SUS USOS EN TANTO QUE, O PARA LA FABRICACION DE CATALIZADORES Y/O SOPORTES DE CATALIZADORES, EN PARTICULAR EN EL CAMPO DE LA POSTCOMBUSTION AUTOMOVIL.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9301450A FR2701471B1 (fr) | 1993-02-10 | 1993-02-10 | Procédé de synthèse de compositions à base d'oxydes mixtes de zirconium et de cérium, compositions ainsi obtenues et utilisations de ces dernières. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2138054T3 true ES2138054T3 (es) | 2000-01-01 |
Family
ID=9443900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94400235T Expired - Lifetime ES2138054T3 (es) | 1993-02-10 | 1994-02-04 | Procedimiento de sintesis de composiciones a base de oxidos mixtos de circonio y de cerio. |
Country Status (13)
Country | Link |
---|---|
US (2) | US5607892A (es) |
EP (2) | EP0930271A3 (es) |
JP (1) | JP2787540B2 (es) |
KR (1) | KR100295168B1 (es) |
AT (1) | ATE183725T1 (es) |
AU (1) | AU668445B2 (es) |
BR (1) | BR9400472A (es) |
CA (1) | CA2115305C (es) |
DE (1) | DE69420163T2 (es) |
ES (1) | ES2138054T3 (es) |
FI (1) | FI107800B (es) |
FR (1) | FR2701471B1 (es) |
ZA (1) | ZA94837B (es) |
Families Citing this family (109)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2695574B1 (fr) * | 1992-09-15 | 1994-11-04 | Rhone Poulenc Chimie | Composition à base d'oxyde cérique, préparation et utilisation. |
ATE153987T1 (de) * | 1993-04-22 | 1997-06-15 | Mannesmann Ag | Verwendung eines katalysators zur herstellung von synthesegas |
FR2714370B1 (fr) * | 1993-12-24 | 1996-03-08 | Rhone Poulenc Chimie | Précurseur d'une composition et composition à base d'un oxyde mixte de cérium et de zirconium, procédé de préparation et utilisation. |
FR2720296B1 (fr) * | 1994-05-27 | 1996-07-12 | Rhone Poulenc Chimie | Composés à base d'alumine, d'oxyde de cérium et d'oxyde de zirconium à réductibilité élevée, leur procédé de préparation et leur utilisation dans la préparation de catalyseurs. |
EP0715879A1 (en) | 1994-12-09 | 1996-06-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Catalyst for purifying exhaust gases and process for producing the same |
FR2729309B1 (fr) * | 1995-01-13 | 1997-04-18 | Rhone Poulenc Chimie | Composition catalytique a base d'oxyde de cerium et d'oxyde de manganese, de fer ou de praseodyme, son procede de preparation et son utilisation en catalyse postcombustion automobile |
FR2736343B1 (fr) * | 1995-07-03 | 1997-09-19 | Rhone Poulenc Chimie | Composition a base d'oxyde de zirconium et d'oxyde de cerium, procede de preparation et utilisation |
FR2741869B1 (fr) * | 1995-12-04 | 1998-02-06 | Rhone Poulenc Chimie | Oxyde de cerium a pores de structure lamellaire, procede de preparation et utilisation en catalyse |
JP2840054B2 (ja) * | 1995-12-26 | 1998-12-24 | ダイハツ工業株式会社 | 耐熱性酸化物 |
US5977017A (en) * | 1996-04-10 | 1999-11-02 | Catalytic Solutions, Inc. | Perovskite-type metal oxide compounds |
US5898014A (en) * | 1996-09-27 | 1999-04-27 | Engelhard Corporation | Catalyst composition containing oxygen storage components |
EP0834348B1 (en) * | 1996-10-07 | 2004-03-31 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Composite oxide, composite oxide carrier and catalyst |
US5723101A (en) * | 1996-10-15 | 1998-03-03 | Rhone-Poulenc Inc. | Method for producing cerium and zirconium oxides, mixed oxides and solid solutions having improved thermal stability |
US5747401A (en) * | 1996-10-15 | 1998-05-05 | Rhone-Poulenc Inc. | Cerium and zirconium oxides, mixed oxides and solid solutions having improved thermal stability |
US5919727A (en) * | 1996-11-14 | 1999-07-06 | W. R. Grace & Co.-Conn. | Ceric oxide washcoat |
US6506705B2 (en) | 1996-12-06 | 2003-01-14 | Rhodia Chimie | Composition based on cerium oxide or on cerium and zirconium oxides, in the extruded form, process for the preparation thereof and use thereof as catalyst |
JP4053623B2 (ja) * | 1996-12-27 | 2008-02-27 | 阿南化成株式会社 | ジルコニウム−セリウム系複合酸化物及びその製造方法 |
JP3429967B2 (ja) * | 1997-02-10 | 2003-07-28 | ダイハツ工業株式会社 | 酸素吸蔵性セリウム系複合酸化物 |
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US6210649B1 (en) * | 1997-04-15 | 2001-04-03 | Massachusetts Institute Of Technology | Metal oxide catalysts for nitric oxide reduction |
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-
1993
- 1993-02-10 FR FR9301450A patent/FR2701471B1/fr not_active Expired - Fee Related
-
1994
- 1994-01-21 AU AU53924/94A patent/AU668445B2/en not_active Expired
- 1994-02-04 AT AT94400235T patent/ATE183725T1/de active
- 1994-02-04 EP EP99102077A patent/EP0930271A3/fr not_active Ceased
- 1994-02-04 DE DE69420163T patent/DE69420163T2/de not_active Expired - Lifetime
- 1994-02-04 EP EP94400235A patent/EP0614854B1/fr not_active Expired - Lifetime
- 1994-02-04 ES ES94400235T patent/ES2138054T3/es not_active Expired - Lifetime
- 1994-02-08 ZA ZA94837A patent/ZA94837B/xx unknown
- 1994-02-08 KR KR1019940002426A patent/KR100295168B1/ko not_active IP Right Cessation
- 1994-02-09 BR BR9400472A patent/BR9400472A/pt not_active IP Right Cessation
- 1994-02-09 FI FI940595A patent/FI107800B/fi not_active IP Right Cessation
- 1994-02-09 CA CA002115305A patent/CA2115305C/fr not_active Expired - Lifetime
- 1994-02-09 JP JP6035177A patent/JP2787540B2/ja not_active Expired - Lifetime
- 1994-02-10 US US08/194,529 patent/US5607892A/en not_active Expired - Lifetime
-
1995
- 1995-05-25 US US08/450,999 patent/US5626826A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR100295168B1 (ko) | 2001-09-17 |
ZA94837B (en) | 1994-09-05 |
EP0930271A2 (fr) | 1999-07-21 |
FI940595A0 (fi) | 1994-02-09 |
KR940019602A (ko) | 1994-09-14 |
US5607892A (en) | 1997-03-04 |
CA2115305A1 (fr) | 1994-08-11 |
US5626826A (en) | 1997-05-06 |
BR9400472A (pt) | 1994-09-27 |
CA2115305C (fr) | 1999-08-10 |
AU5392494A (en) | 1994-09-08 |
EP0930271A3 (fr) | 1999-07-28 |
EP0614854A1 (fr) | 1994-09-14 |
FR2701471A1 (fr) | 1994-08-19 |
FR2701471B1 (fr) | 1995-05-24 |
JP2787540B2 (ja) | 1998-08-20 |
JPH06279027A (ja) | 1994-10-04 |
AU668445B2 (en) | 1996-05-02 |
DE69420163D1 (de) | 1999-09-30 |
EP0614854B1 (fr) | 1999-08-25 |
DE69420163T2 (de) | 2000-04-20 |
FI940595A (fi) | 1994-08-11 |
ATE183725T1 (de) | 1999-09-15 |
FI107800B (fi) | 2001-10-15 |
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