ES2128546T3 - Composicion para pasivar vanadio en craqueo catalitico y su preparacion. - Google Patents
Composicion para pasivar vanadio en craqueo catalitico y su preparacion.Info
- Publication number
- ES2128546T3 ES2128546T3 ES94902504T ES94902504T ES2128546T3 ES 2128546 T3 ES2128546 T3 ES 2128546T3 ES 94902504 T ES94902504 T ES 94902504T ES 94902504 T ES94902504 T ES 94902504T ES 2128546 T3 ES2128546 T3 ES 2128546T3
- Authority
- ES
- Spain
- Prior art keywords
- magnesium
- vanadium
- preparation
- caolin
- craquing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002360 preparation method Methods 0.000 title abstract 2
- 229910052720 vanadium Inorganic materials 0.000 title abstract 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 239000004927 clay Substances 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 abstract 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract 1
- 239000000347 magnesium hydroxide Substances 0.000 abstract 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 235000012243 magnesium silicates Nutrition 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000003469 silicate cement Substances 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/521—Metal contaminant passivation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
SE EXPONE UN NEUTRALIZADOR DE VANADIO PARA USAR EN FCC QUE CONTIENE UNA CANTIDAD IMPORTANTE DE ARCILLA DE CAOLIN CALCINADA, OXIDO LIBRE DE MAGNESIO Y UN AGLOMERANTE DE CEMENTO DE SILICATO DE MAGNESIO FORMADO IN SITU. TAMBIEN SE EXPONEN PROCEDIMIENTOS PARA LA PREPARACION DEL MISMO, FORMANDO UN LODO EN AGUA DE ARCILLA DE CAOLIN HIDRIO, OXIDO DE MAGNESIO O HIDROXIDO DE MAGNESIO Y SILICATO DE SODIO, ENVEJECIENDO EL LODO PARA FORMAR SILICATO DE MAGNESIO IN SITU, OPCIONALMENTE AÑADIENDO ARCILLA ADICIONAL, SILICE COLOIDAL O AMBOS, PULVERIZADOR SECANTE, Y CALCINANDO LAS RESULTANTES MICROESFERAS SECAS ATOMIZADAS SIN FORMAR CANTIDADES APRECIABLES DE SILICATOS DE MAGNESIO CRISTALINOS DE ALUMINATOS DE MAGNESIO CRISTALINOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/987,519 US5300469A (en) | 1992-12-08 | 1992-12-08 | Composition for passivating vanadium in catalytic cracking and preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2128546T3 true ES2128546T3 (es) | 1999-05-16 |
Family
ID=25533339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94902504T Expired - Lifetime ES2128546T3 (es) | 1992-12-08 | 1993-12-07 | Composicion para pasivar vanadio en craqueo catalitico y su preparacion. |
Country Status (11)
Country | Link |
---|---|
US (2) | US5300469A (es) |
EP (1) | EP0673404B1 (es) |
JP (1) | JP3775749B2 (es) |
KR (1) | KR100278957B1 (es) |
CN (1) | CN1043966C (es) |
AT (1) | ATE177466T1 (es) |
CA (1) | CA2144544C (es) |
DE (1) | DE69323896T2 (es) |
ES (1) | ES2128546T3 (es) |
MY (1) | MY131635A (es) |
WO (1) | WO1994013755A1 (es) |
Families Citing this family (33)
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FR2726486B1 (fr) * | 1994-11-07 | 1997-01-24 | Eurecat Europ Retrait Catalys | Procede de regeneration hors site de catalyseur comprenant au moins un metal precieux |
FR2753984B1 (fr) * | 1996-10-02 | 1999-05-28 | Inst Francais Du Petrole | Procede de conversion d'une fraction lourde d'hydrocarbures impliquant une hydrodemetallisation en lit bouillonnant de catalyseur |
CA2217145A1 (en) * | 1996-11-12 | 1998-05-12 | Phillips Petroleum Company | An improved zeolite material and the use thereof in the conversion of non-aromatic hydrocarbons to aromatics and light olefins |
US5800696A (en) * | 1996-11-12 | 1998-09-01 | Phillips Petroleum Company | Method for inhibiting the rate of coke formation during the zeolite catalyzed aromatization of hydrocarbons |
CO4890864A1 (es) * | 1997-10-02 | 2000-02-28 | Colombiana De Petroleos Ecopet | Trampas de vanadio para catalizadores de ruptura catalitica |
CN1074688C (zh) * | 1998-02-20 | 2001-11-14 | 中国石化兰州炼油化工总厂 | 对重金属钒进行捕集的烃类裂化沸石催化剂及制备方法 |
CN1065902C (zh) * | 1998-09-03 | 2001-05-16 | 中国石油化工集团公司 | 一种重整催化剂上硫酸根的脱除方法 |
ATE290925T1 (de) | 1999-08-11 | 2005-04-15 | Akzo Nobel Nv | Abriebfester kristaline mg-al-si haltende, tonhaltende formkörper |
US6656347B2 (en) | 2000-09-22 | 2003-12-02 | Engelhard Corporation | Structurally enhanced cracking catalysts |
US6673235B2 (en) | 2000-09-22 | 2004-01-06 | Engelhard Corporation | FCC catalysts for feeds containing nickel and vanadium |
US6696378B2 (en) | 2001-08-31 | 2004-02-24 | Engelhard Corporation | Fluid catalytic cracking catalyst manufacturing process |
US7101473B2 (en) | 2002-05-31 | 2006-09-05 | Engelhard Corporation | Method of enhancing the activity of FCC catalysts |
US6942783B2 (en) * | 2003-05-19 | 2005-09-13 | Engelhard Corporation | Enhanced FCC catalysts for gas oil and resid applications |
US7431825B2 (en) * | 2003-12-05 | 2008-10-07 | Intercat, Inc. | Gasoline sulfur reduction using hydrotalcite like compounds |
US7375048B2 (en) * | 2004-04-29 | 2008-05-20 | Basf Catalysts Llc | ZSM-5 additive |
US20060060504A1 (en) * | 2004-09-08 | 2006-03-23 | Vierheilig Albert A | Additives for metal contaminant removal |
CN100429149C (zh) * | 2004-11-26 | 2008-10-29 | 中国石油天然气股份有限公司 | 一种高岭土喷雾微球合成高含量NaY分子筛的制备方法 |
CN100450608C (zh) * | 2005-06-15 | 2009-01-14 | 中国石油天然气股份有限公司 | 一种抗重金属的催化裂化助剂及其制备方法 |
US7993623B2 (en) | 2007-06-29 | 2011-08-09 | Albemarle Netherlands B.V. | Additives for removal of metals poisonous to catalysts during fluidized catalytic cracking of hydrocarbons |
CO5930068A1 (es) * | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso |
US8372269B2 (en) * | 2009-10-02 | 2013-02-12 | Basf Corporation | Heavy metals trapping co-catalyst for FCC processes |
CN103037966B (zh) | 2010-06-07 | 2015-12-02 | 印度石油有限公司 | 金属钝化添加剂和制备方法 |
US9029291B2 (en) | 2011-01-12 | 2015-05-12 | Basf Corporation | Rare earth-containing attrition resistant vanadium trap for catalytic cracking catalyst |
CN103172030B (zh) * | 2013-03-22 | 2015-04-15 | 清华大学深圳研究生院 | 氧化物粉体及其制备方法、催化剂、以及催化剂载体 |
DE102014019393A1 (de) * | 2014-12-30 | 2016-06-30 | Georg Dohmen | Additiv und Verfahren zur Behandlung saurer Lösungen, Gase oder Schadstoffe |
CN105498684A (zh) * | 2015-11-30 | 2016-04-20 | 马鞍山泓宇材料科技有限公司 | 一种中空玻璃干燥剂 |
CN106378205A (zh) * | 2016-08-12 | 2017-02-08 | 青岛惠城环保科技股份有限公司 | 一种金属捕集剂的制备方法 |
WO2019094603A1 (en) | 2017-11-10 | 2019-05-16 | Basf Corporation | A metal trap for use in fluid catalytic cracking (fcc) |
CA3084820A1 (en) | 2017-12-15 | 2019-06-20 | Basf Corporation | Vanadium traps for catalytic cracking processes |
CN110180495B (zh) * | 2019-05-29 | 2022-04-12 | 北京化工大学常州先进材料研究院 | 一种多元共沉淀法制备硅酸镁基复合吸附材料的方法 |
CN110170298B (zh) * | 2019-05-29 | 2022-03-18 | 北京化工大学常州先进材料研究院 | 一种浆态复合法制备硅酸镁碳酸镁复合吸附材料的方法 |
JP7208125B2 (ja) * | 2019-09-30 | 2023-01-18 | 日揮触媒化成株式会社 | 流動接触分解触媒用添加剤および流動接触分解触媒用添加剤の製造方法、ならびに触媒組成物 |
CN115430413A (zh) * | 2022-08-30 | 2022-12-06 | 青岛惠城环保科技集团股份有限公司 | 一种高岭土基金属捕集剂的制备方法 |
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DE1768460C2 (de) * | 1968-05-16 | 1973-01-04 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Verfahren zur Gewinnung von Acetylen, Äthylen und höhere Kohlenwasserstoffe enthaltenden Gemischen aus Spaltgasen |
SU271496A1 (ru) * | 1969-05-07 | 1970-05-26 | Садовска Л. А. Иванова, М. А. Юревич , А. И. Хром | КАТАЛИЗАТОР ДЛЯ ВОССТАНОВЛЕНИЯ а-НЕПРЕДЕЛЬНЫХ КАРБОНИЛЬНЫХ СОЕДИНЕНИЙ |
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US4988654A (en) * | 1989-12-29 | 1991-01-29 | Chevron Research Company | Dual component cracking catalyst with vanadium passivation and improved sulfur tolerance |
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US5128027A (en) * | 1990-06-07 | 1992-07-07 | Naguib Halaka | Method for removing mineral slimes from kaolin clay |
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TW200413725A (en) * | 2002-09-30 | 2004-08-01 | Oncotherapy Science Inc | Method for diagnosing non-small cell lung cancers |
-
1992
- 1992-12-08 US US07/987,519 patent/US5300469A/en not_active Expired - Lifetime
-
1993
- 1993-12-07 KR KR1019950702299A patent/KR100278957B1/ko not_active IP Right Cessation
- 1993-12-07 JP JP51430094A patent/JP3775749B2/ja not_active Expired - Fee Related
- 1993-12-07 WO PCT/US1993/011812 patent/WO1994013755A1/en active IP Right Grant
- 1993-12-07 ES ES94902504T patent/ES2128546T3/es not_active Expired - Lifetime
- 1993-12-07 MY MYPI93002614A patent/MY131635A/en unknown
- 1993-12-07 CN CN93120865A patent/CN1043966C/zh not_active Expired - Fee Related
- 1993-12-07 CA CA002144544A patent/CA2144544C/en not_active Expired - Fee Related
- 1993-12-07 DE DE69323896T patent/DE69323896T2/de not_active Expired - Fee Related
- 1993-12-07 AT AT94902504T patent/ATE177466T1/de not_active IP Right Cessation
- 1993-12-07 EP EP94902504A patent/EP0673404B1/en not_active Expired - Lifetime
-
1994
- 1994-03-04 US US08/179,843 patent/US5384041A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN1093951A (zh) | 1994-10-26 |
CN1043966C (zh) | 1999-07-07 |
JP3775749B2 (ja) | 2006-05-17 |
EP0673404A1 (en) | 1995-09-27 |
EP0673404B1 (en) | 1999-03-10 |
KR950704445A (ko) | 1995-11-20 |
JPH08504397A (ja) | 1996-05-14 |
CA2144544A1 (en) | 1994-06-23 |
ATE177466T1 (de) | 1999-03-15 |
AU664009B2 (en) | 1995-10-26 |
WO1994013755A1 (en) | 1994-06-23 |
MY131635A (en) | 2007-08-30 |
KR100278957B1 (ko) | 2001-03-02 |
US5384041A (en) | 1995-01-24 |
AU5685794A (en) | 1994-07-04 |
DE69323896D1 (de) | 1999-04-15 |
US5300469A (en) | 1994-04-05 |
DE69323896T2 (de) | 1999-09-16 |
CA2144544C (en) | 2004-06-29 |
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