ES2115953T5 - Producto acuoso de recubrimiento de poliuretano de dos componentes, procedimiento para su preparacion y su utilizacion en procedimientos para la elaboracion de un lacado multicapa. - Google Patents
Producto acuoso de recubrimiento de poliuretano de dos componentes, procedimiento para su preparacion y su utilizacion en procedimientos para la elaboracion de un lacado multicapa.Info
- Publication number
- ES2115953T5 ES2115953T5 ES94918882T ES94918882T ES2115953T5 ES 2115953 T5 ES2115953 T5 ES 2115953T5 ES 94918882 T ES94918882 T ES 94918882T ES 94918882 T ES94918882 T ES 94918882T ES 2115953 T5 ES2115953 T5 ES 2115953T5
- Authority
- ES
- Spain
- Prior art keywords
- pct
- water
- carboxyl groups
- monomer
- polyurethane coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6241—Polymers of esters containing hydroxy groups of alpha-beta ethylenically unsaturated carboxylic acids with epoxy compounds other than alkylene oxides and hydroxyglycidyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Abstract
EL OBJETIVO DE LA PRESENTE INVENCION ES UN MEDIO DE RECUBRIMIENTO DE POLIURETANO DE DOS COMPONENTES ACUOSOS, CONTENIENDO A) UNA RESINA DE POLIACRILATO SOLUBLE AL AGUA (A) CON UN INDICE OH DESDE 40 HASTA 200 MG COH/G, CON UN INDICE ACIDO DE 20 HASTA 100 MG COH/G Y UNA TEMPERATURA DE TRANSICION VITRIOSA DESDE 40 GENTE DE RETICULACION, CARACTERIZANDOSE DE TAL MODO QUE LA RESINA ACRILATO DILUIBLE EN AGUA ES OBTENIBLE MEDIANTE POLIMERIZACION DE SOLUCION EN PRESENCIA DE UN INICIADOR DE POLIMERIZACION A PARTIR AL MENOS DE UN MONOMERO LIBRE DE GRUPOS CARBOXILO, AL MENOS UN MONOMERO CONTENIENDO GRUPOS HIDROXILO, AL MENOS UN ESTERVINILICO DE ACIDOS MONOCARBOXILICOS RAMIFICADOS EN LA POSICION {AL} CON 5 HASTA 18 ATOMOS DE C POR MOLECULA Y/O AL MENOS UN PRODUCTO DE TRANSFORMACION A PARTIR DEL ACIDO ACRILICO Y/O ACIDO METACRILICO CON ESTERGRICIDILO DE ACIDOS CARBOXILICOS RAMIFICADOS EN LA POSICION {A} CON 5 HASTA 18 ATOMOS DE C POR MOLECULA, AL MENOS DE UN MONOMERO CONTENIENDO GRUPOS CARBOXILO Y EVENTUALMENTE OTROS MONOMEROS ESENCIALMENTE LIBRES DE GRUPOS CARBOXILO Y DONDE UNA VEZ TERMINADA LA POLIMERIZACION LA RESINA DE POLIACRILATO OBTENIDA SE NEUTRALIZA AL MENOS PARCIALMENTE Y SE DISPERSA EN AGUA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4322242A DE4322242A1 (de) | 1993-07-03 | 1993-07-03 | Wäßriges Zweikomponenten-Polyurethan-Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung in Verfahren zur Hestellung einer Mehrschichtlackierung |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2115953T3 ES2115953T3 (es) | 1998-07-01 |
ES2115953T5 true ES2115953T5 (es) | 2002-10-01 |
Family
ID=6491932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94918882T Expired - Lifetime ES2115953T5 (es) | 1993-07-03 | 1994-06-18 | Producto acuoso de recubrimiento de poliuretano de dos componentes, procedimiento para su preparacion y su utilizacion en procedimientos para la elaboracion de un lacado multicapa. |
Country Status (15)
Country | Link |
---|---|
US (1) | US5670600A (es) |
EP (1) | EP0707608B2 (es) |
JP (1) | JPH08512338A (es) |
AT (1) | ATE163437T1 (es) |
AU (1) | AU684292B2 (es) |
BR (1) | BR9406878A (es) |
CA (1) | CA2165088C (es) |
DE (2) | DE4322242A1 (es) |
DK (1) | DK0707608T3 (es) |
ES (1) | ES2115953T5 (es) |
HU (1) | HU215779B (es) |
RU (1) | RU2136713C1 (es) |
SK (1) | SK281260B6 (es) |
WO (1) | WO1995002005A1 (es) |
ZA (1) | ZA944635B (es) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
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DE4410557A1 (de) * | 1994-03-26 | 1995-09-28 | Basf Lacke & Farben | Wäßriges Mehrkomponenten-Polyurethan-Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung in Verfahren zur Herstellung einer Mehrschichtlackierung |
DE4439669A1 (de) * | 1994-11-07 | 1996-05-09 | Basf Lacke & Farben | Wäßriges Zweikomponenten-Polyurethan-Beschichtungsmittel, Verfahren zu seiner Herstellung und seine Verwendung in Verfahren zur Herstellung einer Mehrschichtlackierung |
DE19519807A1 (de) * | 1995-05-31 | 1997-02-13 | Basf Lacke & Farben | Beschichtungsmittel auf der Basis eines hydroxylgruppenhaltigen Polyacrylatharzes und seine Verwendung in Verfahren zur Herstellung einer Mehrschichtlackierung |
DE19542119C1 (de) * | 1995-11-11 | 1997-02-13 | Herberts Gmbh | Überzugsmittel und Verfahren zur Herstellung von Mehrschichtüberzügen |
DE19709465C2 (de) * | 1997-03-07 | 2001-07-12 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zur Herstellung von Mehrschichtlackierungen und Verwendung der Beschichtungsmittel hierfür |
US6017989A (en) * | 1997-04-01 | 2000-01-25 | The Standard Products Company | Exterior automotive component of an elastomeric modified polyolefin material having pleasing appearance |
DE19730889A1 (de) | 1997-07-18 | 1999-01-21 | Basf Coatings Ag | Wäßriger Lack, enthaltend eine mehrkomponentige wäßrige Dispersion |
DE19805004C2 (de) * | 1998-02-07 | 2000-05-31 | Herberts Gmbh | Wäßrige Überzugsmittel, ihre Herstellung und Verwendung bei der Herstellung von Mehrschichtlackierungen |
FR2775482A1 (fr) * | 1998-03-02 | 1999-09-03 | Rhodia Chimie Sa | Revetement a deux polyols, composition utile pour ces revetements et procede d'obtention de ces revetements |
DE19814061A1 (de) | 1998-03-30 | 1999-10-07 | Bayer Ag | Copolymerisatdispersionen, Bindemittelkombinationen auf Basis der Copolymerisatdispersionen, ein Verfahren zu deren Herstellung und deren Verwendung |
US5973073A (en) * | 1998-04-06 | 1999-10-26 | Arco Chemical Technology, L.P. | Two-component aqueous polyurethane coatings |
US6458885B1 (en) * | 1998-05-29 | 2002-10-01 | Ppg Industries Ohio, Inc. | Fast drying clear coat composition |
US6277953B1 (en) * | 1998-09-25 | 2001-08-21 | Mcwhorter Technologies, Inc. | Stable aqueous polymer dispersions and a process for their preparation |
DE19858732A1 (de) | 1998-12-18 | 2000-06-21 | Bayer Ag | Wäßrige 2 K-PUR-Systeme mit erhöhter Schlagzähigkeit, hohen Beständigkeitseigenschaften und guten optischen Eigenschaften, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
DE19858733A1 (de) * | 1998-12-18 | 2000-06-21 | Bayer Ag | Wäßrige 2 K-PUR-Systeme mit erhöhter Schlagzähigkeit und guten Beständigkeitseigenschaften, ein Verfahren zu deren Herstellung und deren Verwendung |
DE19903391A1 (de) * | 1999-01-29 | 2000-08-03 | Bayer Ag | Wäßriges Überzugsmittel, Verfahren zu seiner Herstellung und seine Verwendung |
US6342558B1 (en) * | 1999-11-17 | 2002-01-29 | Basf Corporation | Waterborne primer with improved chip resistance |
US6437036B1 (en) | 1999-11-17 | 2002-08-20 | Basf Corporation | Waterborne primer with improved chip resistance |
US6875834B2 (en) * | 2001-01-30 | 2005-04-05 | Rohm And Haas Company | Two-component coating composition and method of preparation |
JP3984488B2 (ja) * | 2001-03-27 | 2007-10-03 | 日本ペイント株式会社 | 硬化性塗料組成物および塗膜形成方法 |
US20030134970A1 (en) * | 2002-01-17 | 2003-07-17 | Basf Corporation | Basecoat coating composition having low volatile organic content and composite coating prepared therefrom |
EP1366828A1 (en) * | 2002-05-31 | 2003-12-03 | Rohm And Haas Company | Multi-layer coating composition and method of preparation |
US7091278B2 (en) * | 2003-12-10 | 2006-08-15 | E. I. Dupont De Nemours And Company | Aqueous two-component coating compositions |
US20060047065A1 (en) * | 2004-08-30 | 2006-03-02 | Wiebke Becker | Aqueous coating compositions based on acrylate copolymers |
EP1634900B1 (en) * | 2004-09-10 | 2007-10-31 | Rohm and Haas Company | Durable two-part polyurethane floor coating |
US20070015873A1 (en) * | 2005-07-13 | 2007-01-18 | Fenn David R | Electrodepositable aqueous resinous dispersions and methods for their preparation |
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US9777190B2 (en) | 2011-01-20 | 2017-10-03 | Basf Coatings Gmbh | Aqueous polyurethane coating material and coatings produced therefrom and having high scratch resistance and good chemicals resistance |
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US9505937B2 (en) | 2012-05-16 | 2016-11-29 | Ppg Industries Ohio, Inc. | Anionic electrodepositable coating compositions capable of forming low gloss coatings |
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CN111886273A (zh) * | 2018-03-23 | 2020-11-03 | 科思创有限公司 | 含聚脲二酮的树脂共混组合物 |
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DE2814128A1 (de) † | 1978-04-01 | 1979-10-18 | Hoechst Ag | Verfahren zur herstellung von loeslichen, hydroxylgruppenhaltigen, mit organischen polyisocyanaten vernetzbaren mischpolymerisaten |
DE2858105C2 (de) † | 1978-11-29 | 1985-03-28 | Synthopol Chemie Dr. rer. pol. Koch & Co, 2150 Buxtehude | Reaktionslacke und Einbrennlacke auf der Basis von hydroxylgruppentragenden Copolymerisaten sowie Verfahren zur Herstellung von Überzügen |
DE2851615C2 (de) † | 1978-11-29 | 1990-05-31 | Synthopol Chemie Dr. rer. pol. Koch & Co, 2150 Buxtehude | Verfahren zur Herstellung von in organischen Lösungsmitteln löslichen hydroxylgruppentragenden Copolymerisaten und deren Verwendung |
DE2858097C2 (de) † | 1978-11-29 | 1985-03-28 | Synthopol Chemie Dr. rer. pol. Koch & Co, 2150 Buxtehude | Reaktionslacke und Einbrennlacke auf der Basis von hydroxylgruppentragenden Copolymerisaten sowie Verfahren zur Herstellung von Überzügen |
DE2851616A1 (de) † | 1978-11-29 | 1980-06-12 | Synthopol Chemie Dr Koch | Zwischenproduktloesung eines additionsproduktes einer alpha , beta - ungesaettigten monocarbonsaeure mit einer monoglycidylverbindung, verfahren zu ihrer herstellung sowie ihre verwendung |
US4919178A (en) * | 1986-11-14 | 1990-04-24 | The Lubrizol Corporation | Explosive emulsion |
DE3800389A1 (de) * | 1988-01-09 | 1989-07-20 | Bayer Ag | Wasserverduennbare bindemittel, ein verfahren zu ihrer herstellung und ihre verwendung |
DE3823005A1 (de) * | 1988-07-07 | 1990-01-11 | Basf Lacke & Farben | Hydroxylgruppenhaltie copolymerisate auf der basis von vinylester-,vinylaromat- und hydroxylalkylester-monomeren, verfahren zur ihrer herstellung sowie ihre verwendung in beschichtungsmitteln |
DE3829587A1 (de) * | 1988-09-01 | 1990-03-15 | Bayer Ag | Beschichtungsmittel, ein verfahren zu ihrer herstellung und die verwendung von ausgewaehlten zweikomponenten-polyurethansystemen als bindemittel fuer derartige beschichtungsmittel |
US5275847A (en) * | 1988-09-28 | 1994-01-04 | Basf Lacke+Farben Aktiengesellschaft | Process for producing a multi-layer coating using aqueous coating compound aqueous coating compounds |
DE69005215T2 (de) * | 1989-05-19 | 1994-06-16 | Basf Corp | Copolymere zur Verwendung für Beschichtungen mit gering flüchtigen organischen Anteilen und hohen Feststoffgehalten. |
DE4100430A1 (de) † | 1990-01-20 | 1991-07-25 | Synthopol Chemie Dr Koch | Copolymerisatloesungen auf der basis von additionsprodukten (alpha),(beta)-ungesaettigter carbonsaeure mit glycidylestern und damit mischpolymerisierbarer (alpha),(beta)-ungesaettigter monomerer |
DE4132430A1 (de) * | 1991-09-28 | 1993-04-01 | Basf Lacke & Farben | Waessrige lacke und verfahren zur herstellung von automobildecklackierungen |
-
1993
- 1993-07-03 DE DE4322242A patent/DE4322242A1/de not_active Withdrawn
-
1994
- 1994-06-18 AU AU70010/94A patent/AU684292B2/en not_active Ceased
- 1994-06-18 HU HU9503765A patent/HU215779B/hu not_active IP Right Cessation
- 1994-06-18 DE DE59405319T patent/DE59405319D1/de not_active Expired - Fee Related
- 1994-06-18 DK DK94918882T patent/DK0707608T3/da active
- 1994-06-18 ES ES94918882T patent/ES2115953T5/es not_active Expired - Lifetime
- 1994-06-18 WO PCT/EP1994/001991 patent/WO1995002005A1/de active IP Right Grant
- 1994-06-18 US US08/564,145 patent/US5670600A/en not_active Expired - Lifetime
- 1994-06-18 CA CA002165088A patent/CA2165088C/en not_active Expired - Fee Related
- 1994-06-18 EP EP94918882A patent/EP0707608B2/de not_active Expired - Lifetime
- 1994-06-18 SK SK1605-95A patent/SK281260B6/sk unknown
- 1994-06-18 BR BR9406878A patent/BR9406878A/pt not_active IP Right Cessation
- 1994-06-18 RU RU96102130/04A patent/RU2136713C1/ru not_active IP Right Cessation
- 1994-06-18 AT AT94918882T patent/ATE163437T1/de not_active IP Right Cessation
- 1994-06-18 JP JP7503782A patent/JPH08512338A/ja active Pending
- 1994-06-28 ZA ZA944635A patent/ZA944635B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
AU7001094A (en) | 1995-02-06 |
DE4322242A1 (de) | 1995-01-12 |
AU684292B2 (en) | 1997-12-11 |
SK160595A3 (en) | 1997-01-08 |
CA2165088C (en) | 2006-04-11 |
ZA944635B (en) | 1995-02-17 |
HUT73866A (en) | 1996-10-28 |
EP0707608B1 (de) | 1998-02-25 |
BR9406878A (pt) | 1996-04-02 |
WO1995002005A1 (de) | 1995-01-19 |
US5670600A (en) | 1997-09-23 |
DE59405319D1 (de) | 1998-04-02 |
JPH08512338A (ja) | 1996-12-24 |
RU2136713C1 (ru) | 1999-09-10 |
ATE163437T1 (de) | 1998-03-15 |
HU9503765D0 (en) | 1996-02-28 |
CA2165088A1 (en) | 1995-01-19 |
EP0707608B2 (de) | 2002-02-13 |
ES2115953T3 (es) | 1998-07-01 |
EP0707608A1 (de) | 1996-04-24 |
DK0707608T3 (da) | 1998-09-23 |
SK281260B6 (sk) | 2001-01-18 |
HU215779B (hu) | 1999-02-01 |
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